PET color master batch for water-based superfine fibers and preparation method thereof

A technology of superfine fiber and color masterbatch, applied in the direction of adding pigments to spinning solution, adding dyes to spinning solution, single-component polyester artificial filament, etc., can solve compatibility, dispersion and uniformity Poor performance, easy color migration of the final product, and the color cannot meet the requirements, etc., to achieve stable hue, save manpower and equipment costs, and good coloring effect

Inactive Publication Date: 2020-03-24
明新梅诺卡(江苏)新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

On the one hand, traditional water-soluble dyes cannot be effectively adsorbed on PET molecules, and disperse dyes have a certain dyeing ability. Although they can form intermolecular forces (Van der Waals forces) with fibers and polyurethane, the final product is also prone to color migration. And other issues
On the other hand, since the application of water-based superfiber started later than that of oil-based superfiber, there is currently a lack of PET masterbatches for water-based superfiber systems, and the use of general-purpose PET masterbatches is aimed at ordinary polyester fibers. During the spinning process of the water-based superfiber of the components, problems such as poor compatibility, dispersion and uniformity, broken filaments, and failure of the color to meet the requirements after fiber reduction and opening are prone to occur.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] A kind of PET color masterbatch for water-based superfine fiber, its raw material comprises by mass percentage:

[0035] Carrier 30-80%, colorant 10-50%, dispersant 3-15%, compatibilizer 3-15%, slip agent 3-10%, antistatic agent 3-20%, modified inorganic filler 0.5- 20%, antioxidant 0.1-1%.

[0036] Preferably, the raw material of PET color master batch for described water-based microfiber comprises by mass percent:

[0037] Carrier 45-65%, colorant 20-40%, dispersant 7-11%, compatibilizer 7-11%, slip agent 5-8%, antistatic agent 8-15%, modified inorganic filler 6.5- 14%, antioxidant 0.35-0.75%.

[0038] Preferably, the carrier is polyethylene terephthalate, polybutylene terephthalate, polytrimethylene terephthalate, sulfonated polyester, and polyethylene terephthalate-isophthalate Any one or more of the glycol diformate-polyol terephthalate copolymers, and the polyethylene terephthalate, polybutylene terephthalate, polyethylene terephthalate The melting points of p...

Embodiment 2

[0052] 20% of carbon black, 10% of ultramarine blue, 5% of polyethylene low molecular weight wax, and 2.5% of pentaerythritol tetrastearate are mixed, and ground with a grinder until the particle size of the colorant is about 1.0 μm. 50% carrier resin, 5% maleic anhydride grafted polyolefin elastomer, 4% fatty alcohol polyoxyethylene ether, 3% modified diatomite, 0.5% hindered phenol antioxidant 1010 or 1076 Mix with the compound of phosphite antioxidant 168 for 30-60 minutes, then add the treated colorant for mixing, send it into a high-speed mixer for 30-60 minutes, and send the prepared mixture into a twin-screw extruder The machine is melted and extruded. The temperature inside the twin-screw extruder is controlled at 230-260°C, and the screw speed is 100-400r / min. Multiple colored threads are extruded, and the colored threads are put into a water tank to cool. After cooling, The color masterbatch is transported to the dryer for drying treatment. The drying temperature is ...

Embodiment 3

[0055] Mix 20% carbon black, 5% iron oxide red, 5% cobalt blue, 2% polyethylene low molecular weight wax, and 4.5% polar modified wax, and use a grinder to grind until the particle size of the colorant is about 1.0 μm. A compound of 57% carrier resin, 5% maleic anhydride grafted polyolefin elastomer, 1% fumed silica, 0.5% hindered phenol antioxidant 1010 or 1076 and phosphite antioxidant 168 The mixture is mixed and stirred for 30-60 minutes, then the treated colorant is added and mixed, and sent to a high-speed mixer for 30-60 minutes, and the prepared mixture is sent to a twin-screw extruder for melt extrusion, twin-screw extrusion The temperature inside the machine is controlled at 250-260°C, the screw speed is 100-400r / min, extrude multiple colored threads, put the colored threads into the water tank to cool, and the cooled color masterbatch is transported to the dryer for drying treatment , the drying temperature is controlled at 100-120°C, dried for 30-60 minutes, after...

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Abstract

The invention discloses a PET color master batch for water-based superfine fibers. The PET color master batch comprises the following raw materials in percentage by mass: 30-80% of a carrier, 10-50% of a coloring agent, 3-15% of a dispersing agent, 3-15% of a compatibilizer, 3-10% of a slip agent, 3-20% of an antistatic agent, 0.5-20% of modified inorganic filler and 0.1-1% of an antioxidant. By adopting the PET color master batch for water-based superfine fibers, the performances of superfine fiber spinning, non-woven fabric processing and the like are guaranteed, and the problems of coloringand color migration of a final product are solved. The PET color master batch for water-based superfine fibers is low in cost, strong in coloring agent and carrier effect, good in coloring effect, simple in production and preparation process, small in environmental pollution, good in compatibility and liquidity in the spinning process and not prone to yarn breakage, and the final product is stable in hue and free of color migration.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a PET color masterbatch for water-based superfine fibers and a preparation method thereof. Background technique [0002] Microfiber synthetic leather is considered to be the third generation of synthetic leather technology, and it is a typical representative of the development of synthetic fibers towards high simulation. Because it can simulate the structure of dermal fibers, related research and development and industrial application work have attracted wide attention. The preparation of microfiber synthetic leather needs to go through processes such as impregnation, drying, weight reduction, dyeing, washing, etc., to finally obtain a structure similar to the collagen fiber structure of dermis, and then to obtain highly simulated microfiber leather products. Generally, according to the different methods of weight reduction, ultrafine fibers can be divided into two typ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/02C08K13/06C08K13/02C08K7/26C08K3/26C08J3/22D01F1/04D01F1/06D01F6/92
CPCC08J3/226D01F1/04D01F1/06D01F6/92C08J2467/02C08J2367/02C08K13/06C08K13/02C08K7/26C08K2003/265
Inventor 庄君新宋兵严思佳吴儒伟余嵘
Owner 明新梅诺卡(江苏)新材料有限公司
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