Preparation method of efficient scale inhibitor for circulating cooling water system

A technology of circulating cooling water and scale inhibitor, which is applied in the field of scale inhibitor, can solve the problems of industrial circulating cooling water, long synthesis time, simple function, etc. , good scale inhibition and dispersion performance, the effect of preventing the formation of calcium gel

Inactive Publication Date: 2020-04-24
安徽遨信网络科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the nutrient enrichment of water quality caused by the extensive use of phosphate scale inhibitors promotes the growth of a large number of bacteria and algae, resulting in large-scale red tides and seriously affecting the ecological environment.
Therefore, phosphate scale inhibitors have been gradually replaced by low-phosphorus and phosphorus-free scale inhibitors such as polymaleic anhydride, polyacrylic acid, polyaspartic acid, and polyepoxysuccinic acid. It has good performance in terms of scale performance, but there are still deficiencies: such as long synthesis time; the product has simple functions, relatively single performance, long use time, and poor reproducibility; some antiscalant agents can’t well meet the environment of industrial circulating cooling water, etc.

Method used

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  • Preparation method of efficient scale inhibitor for circulating cooling water system
  • Preparation method of efficient scale inhibitor for circulating cooling water system

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] A preparation method of high-efficiency scale inhibitor for circulating cooling water system:

[0030] Add succinic anhydride and diethanolamine to dimethylacetamide according to the mass ratio of 1:1, stir and react for 2 hours, add p-toluenesulfonic acid and toluene, gradually heat up to reflux and separate the water generated by the reaction. After anhydrous generation, add benzoic acid in the system, continue stirring reaction until anhydrous generation, underpressure distillation removes solvent and small molecule, obtains hyperbranched polyamide ester, hyperbranched polyamide ester and 2-acrylamide-2- Add methylpropanesulfonic acid into deionized water at a mass ratio of 1:5.5. After ultrasonic vibration and dissolution, add ammonium persulfate solution with a mass concentration of 12% dropwise under microwave radiation heating. After the dropwise addition, react for 3 hours and cool naturally to room temperature , the viscous obtained after vacuum distillation is...

Embodiment 2

[0032] A preparation method of high-efficiency scale inhibitor for circulating cooling water system:

[0033]Add succinic anhydride and diethanolamine to dimethylacetamide according to the mass ratio of 1:1, stir and react for 1 hour, add p-toluenesulfonic acid and toluene, gradually heat up to reflux and separate the water generated by the reaction. After anhydrous generation, add α-methacrylic acid to the system, continue to stir the reaction until anhydrous generation, remove solvent and small molecule by distillation under reduced pressure, obtain hyperbranched polyamide ester, hyperbranched polyamide ester and 2-acrylamide -2-Methylpropanesulfonic acid was added to deionized water at a mass ratio of 1:5, and after being dissolved by ultrasonic vibration, ammonium persulfate solution with a mass concentration of 10% was added dropwise under microwave radiation heating, and reacted for 3 hours after the dropwise addition, and naturally Cool to room temperature, vacuum-dry t...

Embodiment 3

[0035] A preparation method of high-efficiency scale inhibitor for circulating cooling water system:

[0036] Add succinic anhydride and diethanolamine to dimethylacetamide according to the mass ratio of 1:1, stir and react for 2 hours, add p-toluenesulfonic acid and toluene, gradually heat up to reflux and separate the water generated by the reaction. After anhydrous generation, add acrylic acid to the system, continue to stir the reaction until anhydrous generation, distill under reduced pressure to remove solvent and small molecule, obtain hyperbranched polyamide ester, hyperbranched polyamide ester and 2-acrylamide-2-formaldehyde Propanesulfonic acid was added into deionized water at a mass ratio of 1:6, and after being dissolved by ultrasonic vibration, ammonium persulfate solution with a mass concentration of 20% was added dropwise under heating by microwave radiation, and reacted for 2 hours after the addition was completed, and cooled naturally to room temperature. The...

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Abstract

The invention provides a preparation method of an efficient scale inhibitor for a circulating cooling water system, and relates to the field of scale inhibitors, and the preparation method specifically comprises the following steps: preparing an intermediate A; preparing an intermediate B; uniformly mixing and stirring the intermediate A, the intermediate B, a maleic acid-acrylic acid copolymer, inorganic salt and water to obtain a mixed solution; adding methylated-beta-cyclodextrin, and uniformly stirring so as to obtain the scale inhibitor. According to the efficient scale inhibitor preparedthrough the method, the scale inhibition rate of a static scale inhibition experiment reaches 90% or above, the optimal scale inhibition rate of the performance can reach 99.1%, the scale inhibitionrequirement of a circulating cooling water system can be met, and the efficient scale inhibitor has very wide application prospects.

Description

technical field [0001] The invention relates to the field of scale inhibitors, in particular to a preparation method of a high-efficiency scale inhibitor for a circulating cooling water system. Background technique [0002] In the production process of many industrial sectors, a large amount of waste heat is generated, which needs to be transferred to the natural environment with heat transfer medium in time to ensure the normal operation of the production process. Because natural water has excellent heat transfer performance and low cost, and is rich in resources, it is used as a heat transfer medium for industrial waste heat. It is called cooling water in industrial production. Industrial cooling water is the largest user of industrial water in all countries. The physical and chemical properties of the cooling water outside the temperature do not change significantly. If appropriate cooling measures are taken to form a recycling system, it is an important way to save indus...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F5/12C02F101/10C02F101/14C02F101/20C02F103/02
CPCC02F5/125C02F2101/10C02F2101/101C02F2101/14C02F2101/20C02F2103/023C02F2303/22
Inventor 蔡勇竞
Owner 安徽遨信网络科技有限公司
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