Environment-friendly water-resistant reinforced latex for paper as well as preparation method and application thereof

An environmentally friendly, reinforced glue technology, applied in paper, papermaking, paper coating, etc., can solve the problems of paper straw stiffness, water resistance, heat resistance, poor printing suitability, and difficulty in satisfying consumers, so as to reduce bacterial pollution , Improve rigidity, improve gloss effect

Active Publication Date: 2020-08-14
ZHEJIANG HENGDA NEW MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] 2. Solve the problems of poor stiffness, water resistance, heat resistance and printability of existing paper straws
However, the existing straw base

Method used

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  • Environment-friendly water-resistant reinforced latex for paper as well as preparation method and application thereof
  • Environment-friendly water-resistant reinforced latex for paper as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] The preparation method of a kind of environment-friendly water-resistant reinforced latex for paper of this embodiment is obtained by the following method:

[0048] (1) Preparation of Dicyclopentenyl Oxyethyl Methacrylate

[0049] (a) According to the ratio, add ethylene glycol and dicyclopentadiene to the reactor 2 in sequence, then continue to slowly add p-toluenesulfonic acid, stir the obtained reaction solution evenly, and then gradually raise the temperature of the reaction system to 116°C , keep warm for 3h, after the reaction is over, cool to room temperature; finally add sodium carbonate aqueous solution, wash with distilled water, and rectify under reduced pressure to obtain ethylene glycol dicyclopentenyl ether; wherein: the ethylene glycol, dicyclopenta The mass ratio of diene, p-toluenesulfonic acid and sodium carbonate is 1:1.9:0.0012:0.0017.

[0050] (b) in reactor 3, add successively the mixture 1 that is formed by the ethylene glycol biscyclopentenyl et...

Embodiment 2

[0059] The preparation method of a kind of environment-friendly water-resistant reinforced latex for paper of this embodiment is obtained by the following method:

[0060] (1) Preparation of Dicyclopentenyl Oxyethyl Methacrylate

[0061] (a) According to the ratio, add ethylene glycol and dicyclopentadiene in the reactor 2 in sequence, then continue to slowly add p-toluenesulfonic acid, stir the obtained reaction solution evenly, and then gradually raise the temperature of the reaction system to 115°C , keep warm for 3.5h, after the reaction is over, cool to room temperature; finally add sodium carbonate aqueous solution, wash with distilled water, and rectify under reduced pressure to obtain ethylene glycol dicyclopentenyl ether; wherein: the ethylene glycol, bicyclic The mass ratio of pentadiene, p-toluenesulfonic acid and sodium carbonate is 1:1.9:0.0012:0.0017.

[0062] (b) in reactor 3, add successively the mixture 1 that is formed by the ethylene glycol biscyclopentenyl...

Embodiment 3

[0071] The preparation method of a kind of environment-friendly water-resistant reinforced latex for paper of this embodiment is obtained by the following method:

[0072] (1) Preparation of Dicyclopentenyl Oxyethyl Methacrylate

[0073] (a) According to the ratio, add ethylene glycol and dicyclopentadiene to the reactor 2 in sequence, then continue to slowly add p-toluenesulfonic acid, stir the obtained reaction solution evenly, and then gradually raise the temperature of the reaction system to 120°C , keep warm for 2.5h, after the reaction is over, cool to room temperature; finally add sodium carbonate aqueous solution, wash with distilled water, and rectify under reduced pressure to obtain ethylene glycol dicyclopentenyl ether; wherein: the ethylene glycol, bicyclic The mass ratio of pentadiene, p-toluenesulfonic acid and sodium carbonate is 1:1.9:0.0012:0.0017.

[0074] (b) in reactor 3, add successively the mixture 1 that is formed by the ethylene glycol biscyclopentenyl...

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Abstract

The invention discloses environment-friendly water-resistant reinforced latex for paper as well as a preparation method and application thereof, and belongs to the field of production of auxiliaries for papermaking. According to the method, styrene, butyl acrylate and the like are used as main reaction monomers; dicyclopentenyl oxyethyl methacrylate and dimethyl itaconate are used as main functional monomers; sodium dodecyl sulfate and nonylphenol polyoxyethylene ether are adopted as emulsifiers, persulfate is adopted as an initiator, sodium bicarbonate is adopted as a buffer agent, and modified styrene-acrylic latex is synthesized through a pre-emulsification seed emulsion polymerization process, and is compounded with cationic starch and chitosan to prepare the environment-friendly water-resistant enhanced latex for paper. The environment-friendly water-resistant enhanced latex for the paper is advanced in process, free of pollution and low in production cost; and straw base paper prepared from the environment-friendly water-resistant enhanced latex for the paper is good in stiffness, water resistance, heat resistance and printability, has a certain antibacterial property, can reduce bacterial pollution on the surface of the straw base paper, and has a wide market application prospect.

Description

technical field [0001] The invention belongs to the production field of auxiliary agents for papermaking, and in particular relates to an environment-friendly water-resistant reinforced latex for paper and a preparation method and application thereof. Background technique [0002] With the development of plastic bans at home and abroad, fast-moving products such as plastic tableware are gradually eliminated by the market. Countries such as the European Union have proposed "plastic reduction orders". Some international fast food chain giants have gradually begun to use paper straws instead of disposable plastic straws. Therefore, it is an inevitable trend to replace plastic straws with paper straws made of natural plant fibers. Plant fibers can biodegrade and will not pollute the environment; with the development of society and the improvement of people's living standards, the environmental protection and safety of food contact materials Security puts forward higher requireme...

Claims

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Application Information

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IPC IPC(8): C08F220/18C08F212/08C08F220/14C08F220/06C08F222/14C08F222/02C08F220/28D21H11/00D21H17/24D21H17/29D21H17/34D21H17/37D21H19/12D21H21/16
CPCC08F220/1804C08F212/08D21H11/00D21H17/29D21H17/37D21H19/12D21H17/34D21H17/24D21H21/16C08F220/14C08F220/06C08F222/14C08F222/02C08F220/281
Inventor 伊财富杨菊红徐冰程亚洲王启华
Owner ZHEJIANG HENGDA NEW MATERIAL CO LTD
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