Treatment method of chemical and chemical engineering waste liquid

A treatment method and technology for chemical wastewater, applied in chemical instruments and methods, oxidized water/sewage treatment, aerobic and anaerobic process treatment, etc., can solve problems such as unstable treatment effect, blockage, and water quality fluctuations

Inactive Publication Date: 2021-06-18
HUNAN POLYTECHNIC OF ENVIRONMENT & BIOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, the concentration of calcium, magnesium ions and suspended solids is relatively high. Compared with COD, the concentration of ammonia nitrogen is relatively high and COD is relatively low, which will cause fouling and blockage of equipment pipelines, especially pollutants containing chromium and mercury, which are difficult to deal with
If the wastewater is not treated and directly discharged into the environment, it will cause serious pollution to the environment and easily cause great harm to humans and animals.
At present, the treatment method of chemical organic wastewater containing persistent organic pollutants is mainly to carry out advanced oxidation (such as iron-carbon micro-electrolysis, metal powder reduction, Fenton method, etc.) pretreatment first, and then biological treatment. For effective treatment of various substances, there are often problems of water quality fluctuations, and the treatment effect is unstable. After sewage treatment, it only meets the standard discharge indicators. There is a certain environmental protection pressure and has a potential impact on the environment.

Method used

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  • Treatment method of chemical and chemical engineering waste liquid

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] The invention provides a treatment method for chemical and chemical waste liquid, the specific steps are as follows:

[0026] Step 1: Oxidation treatment: Mix nitric acid and sodium hypochlorite at a ratio of 1:1 to make an oxidant, prepare ammonium persulfate with a molar ratio of 1:2 to the oxidant as an initiator, and use it to chemical wastewater with a BOD5 / COD value of 0.07 The oxidizing agent and the initiator added in the ratio of 5g / L and 1g / L in the water, carry out the oxidation reaction, and oxidize and decompose the organic matter in the waste water;

[0027] Step 2: Acid-base neutralization treatment: mix calcium hydroxide and ammonia water in a ratio of 1:1 to make an alkaline solution, add the alkaline solution to the wastewater, carry out acid-base neutralization reaction, adjust the pH value of the wastewater, and add After adding polyaluminum chloride to the wastewater, solid-liquid separation treatment is carried out to remove suspended solids in the...

Embodiment 2

[0033] The invention provides a treatment method for chemical and chemical waste liquid, the specific steps are as follows:

[0034] Step 1: Oxidation treatment: Mix nitric acid and sodium hypochlorite in a ratio of 2:3 to make an oxidant, prepare ammonium persulfate with a molar ratio of 1:3 to the oxidant as an initiator, and use it to chemical wastewater with a BOD5 / COD value of 0.15 The oxidizing agent and the initiator added in the ratio of 7g / L and 2g / L in the water are carried out to carry out the oxidation reaction, and the organic matter in the waste water is oxidized and decomposed;

[0035] Step 2: Acid-base neutralization treatment: mix calcium hydroxide and ammonia water in a ratio of 1:1.5 to make an alkaline solution, add alkaline solution to the wastewater, carry out acid-base neutralization reaction, adjust the pH value of the wastewater, and add After adding polyaluminium chloride to the wastewater, solid-liquid separation treatment is carried out to remove s...

Embodiment 3

[0041] The invention provides a treatment method for chemical and chemical waste liquid, the specific steps are as follows:

[0042] Step 1: Oxidation treatment: Mix nitric acid and sodium hypochlorite in a ratio of 3:5 to make an oxidant, prepare ammonium persulfate with a molar ratio of 1:5 to the oxidant as an initiator, and use it to chemical wastewater with a BOD5 / COD value of 0.25 The oxidizing agent and the initiator added in the ratio of 10g / L and 3g / L in the water are used for oxidation reaction, and the organic matter in the waste water is oxidized and decomposed;

[0043] Step 2: Acid-base neutralization treatment: mix calcium hydroxide and ammonia water in a ratio of 1:2 to make an alkaline solution, add the alkaline solution to the wastewater, carry out acid-base neutralization reaction, adjust the pH value of the wastewater, and add After adding polyaluminium chloride to the wastewater, solid-liquid separation treatment is carried out to remove suspended solids i...

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Abstract

The invention discloses a chemical and chemical engineering waste liquid treatment method, and particularly relates to the technical field of chemical and chemical engineering waste liquid treatment. The chemical and chemical engineering waste liquid treatment method comprises the following specific steps: 1, carrying out oxidation treatment; 2, carrying out acid-base neutralization treatment; 3, carrying out stirring treatment; 4, carrying out precipitation treatment; 5, carrying out toxicity neutralization treatment; and 6, carrying out biological filtration. According to the invention, through oxidation and acid-base neutralization treatment, soluble solvents such as methanol, ethanol and acetic acid are degraded into organic matters such as acetic acid and propionic acid which are easily utilized by microorganisms, so that degradation of part of organic pollutants in the wastewater is realized; through stirring and precipitation treatment, nitrogen-containing, phosphorus-containing and lead-containing wastes are converted into gas or are precipitated, so that extraction and cleaning are facilitated; through toxicity neutralization treatment, toxic wastes containing chromium and mercury are separated from water, so that various chemical pollutants in the wastewater can be effectively removed; and microorganisms are utilized to carry out biochemical oxidation on organic matters, so that the degradation of part of organic pollutants in the wastewater is finally realized.

Description

technical field [0001] The embodiments of the present invention relate to the technical field of chemical and chemical waste liquid treatment, and in particular to a treatment method for chemical and chemical waste liquid. Background technique [0002] The chemical industry, also known as the chemical processing industry, generally refers to the process industry in which chemical methods play a major role in the production process. The chemical industry is an industrial sector that has been formed since the beginning of the 19th century and has developed rapidly. The chemical industry is a knowledge- and capital-intensive industry. With the development of science and technology, it has gradually developed into a multi-industry and multi-variety production department from the initial production of only a few inorganic products such as soda ash and sulfuric acid, and organic products mainly extracted from plants to make dyes. A large number of comprehensive utilization of re...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/14C02F101/30
CPCC02F1/5236C02F1/62C02F1/66C02F1/76C02F3/107C02F3/30C02F3/34C02F9/00C02F2101/30
Inventor 曾琦斐
Owner HUNAN POLYTECHNIC OF ENVIRONMENT & BIOLOGY
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