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Strontium titanate modified nickel cobalt lithium manganate positive electrode material and lithium ion battery containing same

A technology of nickel-cobalt lithium manganese oxide and positive electrode materials, which is applied in the direction of positive electrodes, secondary batteries, battery electrodes, etc., can solve problems such as damage to electronic conduction paths, increased expansion of binders, and deterioration of cycle performance, so as to reduce production cost, reduce material internal stress, and improve the effect of production environment

Active Publication Date: 2021-11-09
HEFEI GUOXUAN HIGH TECH POWER ENERGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, reducing the particle size will cause serious agglomeration during the electrochemical cycle, and the large specific surface area brought about by reducing the particle size requires the addition of more binders, which increases the expansion of the binder at high temperatures. Lead to the destruction of the electron conduction path, thereby deteriorating its cycle performance at high temperature

Method used

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  • Strontium titanate modified nickel cobalt lithium manganate positive electrode material and lithium ion battery containing same
  • Strontium titanate modified nickel cobalt lithium manganate positive electrode material and lithium ion battery containing same
  • Strontium titanate modified nickel cobalt lithium manganate positive electrode material and lithium ion battery containing same

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] S1. According to the molar ratio of nickel, cobalt, and manganese elements = 7:1:2, mix soluble nickel sulfate, cobalt sulfate, and manganese sulfate with water, stir until completely dissolved, and obtain a mixture with a total concentration of metal ions of 1.0mol / L Solution A, then mixed solution A and concentration are 3.5mol / L sodium citrate complexing agent, concentration is 3.5mol / L sodium hydroxide solution precipitating agent, add in the reactor under nitrogen protection gas, adjust complexing agent and The flow rate of the precipitating agent is such that the pH in the reactor is maintained at 11.1-11.5 and the temperature is controlled at 50-55°C. The reaction is stirred for 8 hours and then aged for 10 hours. The nickel-cobalt-manganese precursor C is obtained after solid-liquid separation, washing and drying: Ni 0.7 co 0.1 mn 0.2 (OH) 2 .

[0044] S2, according to the general chemical formula Sr 0.98 TiO 3 : The stoichiometric ratio of each element in...

Embodiment 2

[0049] S1. According to the molar ratio of nickel, cobalt, and manganese elements = 6:2:2, mix soluble nickel sulfate, cobalt sulfate, and manganese sulfate with water, stir until completely dissolved, and obtain a mixture with a total concentration of metal ions of 1.5mol / L Solution A, then mixed solution A and concentration are 7.0mol / L sodium gluconate complexing agent, concentration is 7.0mol / L potassium hydroxide solution precipitating agent, add in the reactor under nitrogen protection gas, adjust complexing agent and The flow rate of the precipitating agent keeps the pH in the reactor at 10.2-11.4 and the temperature is controlled at 40-45°C. Stir the reaction for 36 hours and then continue aging for 36 hours. After solid-liquid separation, washing and drying, the nickel-cobalt-manganese precursor Ni 0.6 co 0.2 mn 0.2 (OH) 2 .

[0050] S2, according to the general chemical formula Sr 0.99 TiO 3 : The stoichiometric ratio of each element in 0.01La. Take chemically ...

Embodiment 3

[0054] S1. According to the molar ratio of nickel, cobalt, and manganese elements = 7:1:2, mix soluble nickel nitrate, cobalt nitrate, and manganese nitrate with water, stir until completely dissolved, and obtain a mixture with a total concentration of metal ions of 4.0mol / L Solution A, then the mixed solution A and the concentration of 3.5mol / L hydrazine hydrate complexing agent, the concentration of 3.5mol / L lithium hydroxide solution precipitation agent, add in the reaction kettle under the nitrogen protection gas, adjust the complexing agent and precipitation The flow rate of the agent is used to maintain the pH in the reactor at 11.8-12.0 and control the temperature at 60-70°C. Stir the reaction for 8 hours and then continue to age for 8 hours. After solid-liquid separation, washing and drying, the nickel-cobalt-manganese precursor Ni 0.7 co 0.1 mn 0.2 (OH) 2 .

[0055] S2, according to the general chemical formula Sr 0.98 TiO 3 : The stoichiometric ratio of each ele...

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Abstract

The invention belongs to the field of preparation of lithium ion battery materials, and particularly relates to a preparation method of a strontium titanate modified nickel cobalt lithium manganate positive electrode material, the prepared positive electrode material and a lithium ion battery containing the positive electrode material. The positive electrode material is a rare earth element doped strontium titanate modified nickel cobalt lithium manganate positive electrode material doped with large and small particles. The preparation method has the advantages that rare earth element doped strontium titanate modification and large and small particle mixing are adopted, requirements on a precursor is not high, the prepared precursor is wide in particle size distribution, a large and small particle mixed ternary material can be formed in a later period, ammonia water does not need to serve as a complexing agent in the preparation method, harm of ammonia water serving as a complexing agent to the safety and health of workers is avoided, and the treatment cost of wastewater is reduced.

Description

technical field [0001] The invention belongs to the field of preparation of lithium-ion battery materials, in particular to a nickel-cobalt-lithium-manganese-oxide cathode material and a lithium-ion battery containing it. Background technique [0002] In order to gradually solve the three major problems of energy shortage, greenhouse gas and air pollution that restrict the current economic development, lithium-ion batteries, as an energy storage device, have high working voltage, high energy density, long cycle life and low self-discharge rate. , No memory effect, no environmental pollution and other advantages. In the past ten years, it has achieved rapid development in technology, production and market, and has formed a large emerging industry, which has attracted more and more attention from all aspects. The improvement of cruising range, fast charging technology and safety performance of new energy electric vehicles requires lithium-ion batteries equipped with electric ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01G53/00H01M4/505H01M4/525H01M10/0525
CPCC01G53/50H01M4/505H01M4/525H01M10/0525C01P2002/72C01P2004/03C01P2006/40H01M2004/028Y02E60/10
Inventor 王庆莉王辉严雪枫李道聪丁楚雄杨茂萍陈方
Owner HEFEI GUOXUAN HIGH TECH POWER ENERGY
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