6results about How to "Suppress shuffling" patented technology

The invention relates to the technical field of lithium ion battery positive electrode materials, in particular to an aluminum-yttrium-boric acid coated high-nickel positive electrode material and a preparation method and application thereof. The preparation method of the material comprises the following steps: synthesizing a doped and modified high-nickel ternary precursor from a mixed metal salt solution and a first aluminum source and / or a first yttrium source through a coprecipitation reaction; mixing the precursor with a lithium source, and performing first sintering treatment to obtain a base material; and mixing the base material with a solution containing boric acid, a second aluminum source and a second yttrium source, and carrying out solvent evaporation and second sintering treatment to obtain a final product. Through the synergistic effect of bulk phase doping and surface composite coating, generation of intragranular cracks and interface side reaction of the material in the circulation process are inhibited at the same time. The obtained positive electrode material successfully overcomes the technical problem that high capacity and long service life are difficult to consider at the same time, and the cycling stability is remarkably improved while the high specific capacity is kept.

This invention relates to the field of lithium-ion battery cathode material technology, specifically to a ternary composite doped high-nickel cathode material, its preparation method, and its application. The preparation method of the ternary composite doped high-nickel cathode material includes the following steps: preparing a solution A of nickel, cobalt, and manganese salts; preparing a solution B of aluminum, magnesium, and zirconium salts; in the presence of a precipitant, first performing a first co-precipitation reaction in solution A to generate a core precursor, then adding solution B to perform a second co-precipitation reaction to generate a shell precursor on the core surface, thus obtaining a core-shell structure precursor; mixing it with a lithium source and then performing gradient-segmented sintering, followed by post-treatment to obtain the final product. This invention, by concentrating the ternary composite doping elements in the shell layer, significantly improves the structural and thermal stability of the material while ensuring high capacity. The resulting cathode material exhibits excellent capacity retention and rate performance under high-pressure cycling conditions.

The application relates to the technical field of lithium ion batteries, in particular to a high-entropy high-nickel cobalt-free precursor, a high-entropy high-nickel cobalt-free single-crystal positive electrode material and a preparation method thereof and a lithium ion battery. The high-entropy high-nickel cobalt-free precursor comprises a core layer and a high-entropy doped shell layer coated on at least part of the surface of the core layer; the core layer comprises a first nickel-manganese hydroxide; the high-entropy doped shell layer comprises a high-entropy doped second nickel-manganese hydroxide; and the doped elements in the high-entropy doped second nickel-manganese hydroxide include titanium, magnesium, aluminum, zirconium and molybdenum. The high-entropy high-nickel cobalt-free precursor provided by the application is coated with a high-entropy doped shell layer containing titanium, magnesium, aluminum, zirconium and molybdenum on the surface of the core layer containing the first nickel-manganese hydroxide, which is beneficial to reducing the exposure degree of {010} active crystal faces in the precursor, promoting the preferred growth of the positive electrode material along the (003) plane, and further improving the electrochemical performance and cycle stability of the high-entropy high-nickel cobalt-free single-crystal positive electrode material.

The application provides a doped and repaired regenerated lithium nickel cobalt manganese oxide ternary material, a preparation method and application thereof, and belongs to the field of resource recycling science and engineering. The preparation method comprises the following steps: sequentially performing alkali washing and impurity removal and low-temperature pre-burning on waste lithium nickel cobalt manganese oxide material to obtain an activated material; mixing the activated material with a first lithium source, and performing one-time lithium supplement sintering to obtain one-time lithium supplement regenerated material; mixing the one-time lithium supplement regenerated material with a second lithium source and a lanthanide compound, and performing secondary sintering to obtain the doped and repaired regenerated lithium nickel cobalt manganese oxide ternary material. The application adopts a synergistic repair process of "alkali washing and impurity removal-low-temperature pre-burning-step-by-step lithium supplement-lanthanide element doping", does not need to use corrosive reagents and complex separation steps, and has the advantages of simple process, low energy consumption and green environmental protection. The obtained regenerated material restores the layered crystal structure, and when used as a lithium ion battery positive electrode material, has excellent cycle stability and rate performance.

The invention belongs to the technical field of lithium ion batteries, and discloses a single crystal positive electrode material for a lithium ion battery, nickel cobalt lithium manganate is used as a matrix, the surface of the matrix is coated with composite fluoride LiCoNxFy, x is more than or equal to 0.2 and less than or equal to 5, y is more than or equal to 4 and less than or equal to 8, the composite fluoride accounts for 1-5 mol% of the matrix, and a proper amount of protective layer can ensure that the matrix is uniformly and compactly covered, so that the single crystal positive electrode material is prepared. And meanwhile, the integrity of the alpha-NaFeO2 type layered structure of the matrix is kept. The invention also discloses a preparation method, double coating of NFn and LiCoF3 is realized through a three-step sintering process, and the prepared single crystal positive electrode material still keeps a complete alpha-NaFeO2 type layered structure. The invention also discloses a lithium ion battery composed of the single-crystal positive electrode material for the lithium ion battery.

The invention relates to the technical field of lithium ion batteries, and discloses a composite coated ternary positive electrode material as well as a preparation method and application thereof. According to the composite coated ternary positive electrode material provided by the invention, the antimony element is doped in the matrix, so that the crystal structure can be stabilized by Sb < 5 + > with high valence and large ion radius, and the mixed arrangement of cations is reduced; the cobalt and lithium elements of the first coating layer can form a stable spinel structure on the surface of a matrix, and interface side reaction is inhibited; surface coating of the tungsten element, the aluminum element, the titanium element and the zirconium element inhibits interface side reaction, the structural stability of the positive electrode material is improved, and the cycling stability and the thermal stability of the lithium ion battery are further improved.