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High-strength tableware particle material capable of being completely and naturally degraded and preparation method thereof

A high-strength, tableware technology, applied in the field of preparing biodegradable materials, can solve the problems of poor antibacterial performance, insufficient strength, low strength, etc., to improve antibacterial performance and antiaging performance, improve antibacterial performance and aging performance, improve the effect of strength

Pending Publication Date: 2021-12-10
广州绿徽新材料研究院有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] Chinese patent CN106084701A discloses a degradable plastic. Although it can achieve good thermoplasticity and fully degradable effect, its strength is low, its hydrophobicity is poor, and its antibacterial performance is not good, so it cannot meet the needs of tableware materials;
[0007] Chinese patent CN107083075A discloses a biodegradable straw disposable material. Although the material can be biodegraded, it still has problems of not high enough strength, not good toughness, easy to break, poor hydrophobicity, and poor antibacterial performance, which cannot meet the needs of high-end places. tableware requirements;
[0008] Chinese patent CN111793251A discloses a starch-based plastic tableware and its preparation method. The plastic tableware has good water resistance, heat resistance and biodegradability, but still has the characteristics of low strength and poor antibacterial performance, so it can only be used as a cheap one-time tableware;
Although the tableware is degradable, and the tableware has certain antibacterial properties by adding nano-silver, the addition of nano-silver itself is very small, and the direct addition of nano-silver causes nano-nanometer silver to not be uniformly dispersed in plastic tableware, and cannot guarantee long-term use. Partial mildew does not occur in the tableware under long-term preservation, and the tableware has low strength and poor hydrophobicity
[0010] With the rapid development of China's economy, people's living standards have improved significantly, and the demand for high-end catering has become more and more vigorous. The visible degradable plastic tableware prepared by the existing technology can only meet the disposable low-end consumption places, and plastic tableware generally has insufficient strength. High, easy to mildew, is also the main factor that it can not meet the needs of high-end tableware

Method used

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  • High-strength tableware particle material capable of being completely and naturally degraded and preparation method thereof

Examples

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Effect test

Embodiment 1

[0104] A high-strength tableware particle material that can be completely degraded naturally, made of the following raw materials in parts by weight: 70 parts of oxidized modified high-amylose pea starch, 4 parts of propylene glycol, 3 parts of acetyl tributyl citrate, and 3 parts of modified natural fiber , poly(3-hydroxybutyrate-co-4-hydroxybutyrate) P34HB12 parts, poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) PHBHHx7 parts, BASF's epoxy functionalized ADR 1 part of chain extender, 0.5 part of maleic anhydride, 0.5 part of polyoxyethylene (PEO), 8 parts of inorganic filler; its preparation method comprises the following steps:

[0105] ① Weigh according to the weight ratio: 70 parts of oxidized modified high straight chain pea starch, 4 parts of propylene glycol, and 3 parts of acetyl tributyl citrate are added to the high-speed mixer together, and the top cover is sealed. After stirring for 5-12 minutes, the Next, ultrasonically oscillate for 30 minutes, the ultrasonic powe...

Embodiment 2

[0111] A high-strength tableware particle material that can be completely and naturally degraded is made of the following raw materials in parts by weight: 80 parts of oxidized modified high linear sweet potato starch, 4 parts of glycerol, 5 parts of polyethylene glycol stearate, modified 8 parts of natural fiber, 8 parts of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) PHBV, 7 parts of poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) PHBHHx, BASF 1 part of oxygen functionalized ADR chain extender, 0.7 part of maleic anhydride, 0.7 part of polyoxyethylene (PEO), 6 parts of inorganic filler; its preparation method comprises the following steps:

[0112] ① Weigh according to the proportion by weight: 80 parts of oxidized modified high straight chain sweet potato starch, 4 parts of glycerol, and 5 parts of polyethylene glycol stearate are added to the high-speed mixer, the top cover is sealed, and stirred for 5-12 minutes Finally, at room temperature, ultrasonically oscillate for 30 ...

Embodiment 3

[0119] A fully degradable high-strength tableware particle material, made of the following raw materials in parts by weight: 80 parts of oxidized modified high linear tapioca starch, 5 parts of glycerol, 3.5 parts of acetyl tributyl citrate, modified natural fiber 7 parts, poly(3-hydroxybutyrate-co-3-hydroxyvalerate) PHBV5 parts, poly(3-hydroxybutyrate-co-4-hydroxybutyrate) P34HB10 parts, BASF epoxy functional 1 part of Nadr chain extender, 1 part of maleic anhydride, 0.7 part of polyoxyethylene (PEO), 3.5 parts of inorganic filler; Its preparation method comprises the following steps:

[0120] ① Weighing according to the proportion by weight: 80 parts of oxidized modified high straight-chain tapioca starch, 5 parts of glycerol, and 3.5 parts of acetyl tributyl citrate are added to the high-speed mixer together, and the top cover is sealed. After stirring for 5-12 minutes, At room temperature, ultrasonically oscillate for 30 minutes, the ultrasonic power is 480W, and the obtai...

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Abstract

The invention relates to a high-strength tableware particle material capable of being completely and naturally degraded and a preparation method of the high-strength tableware particle material. The high-strength tableware particle material is prepared from polyhydroxyalkanoate (PHAs), a modified natural organic plant fiber material, oxidized modified high-amylose starch, a composite plasticizer, a functional additive, a modifier and inorganic filler. Thethe particle material is obtained by carrying out melting reaction extrusion at 55-160 DEG C by virtue of a double-stage serial screw granulating unit, and carrying out mixing, reacting, extruding, cooling, cutting, drying, sterilizing and packaging. Various meal boxes, spoons, cups, bowls, dishes, knives, forks and trays are produced by adopting general equipment such as extrusion molding, plastic uptake or an injection molding unit. The adopted raw materials are rich in source, the raw material cost is low, the process is simple, the production cost is low, and the prepared tableware particle material has high strength, high aging resistance, high antibacterial property and high hydrophobic property and can meet the requirements of high-end catering degradable tableware.

Description

technical field [0001] The invention belongs to the technical field of preparing biodegradable materials, and in particular relates to a completely naturally degradable high-strength tableware particle material and a preparation method thereof. Background technique [0002] Actively preventing and stopping the flood of disposable plastic products has become the consensus of most countries in China and the world. The degradable plastic manufacturing industry has keenly captured this policy trend. According to statistics from Huaan Securities, 36 companies are building or planning to build degradable plastic projects, with a total new capacity of 4.405 million tons. Many of the biggest players in the food and beverage industry have pledged to eliminate plastic cutlery over the past year as they adapt to changes in consumer expectations and legislation. [0003] At present, the main methods of dealing with plastic waste in the world are landfill or incineration. Whether it i...

Claims

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Application Information

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IPC IPC(8): C08L3/20C08L67/04C08L99/00C08L71/02C08K13/06C08K9/04C08K3/22C08K3/34C08K3/04C08K3/08C08K5/053C08K5/11
CPCC08L3/20C08L2201/06C08L2205/16C08L2201/08C08K2201/011C08K2003/2241C08K2003/0806C08L2201/14C08L67/04C08L99/00C08L71/02C08K13/06C08K9/04C08K3/22C08K3/346C08K3/041C08K3/08C08K5/053C08K5/11
Inventor 谭晓露谭卓华黄炜岚
Owner 广州绿徽新材料研究院有限公司
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