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Low-temperature charge-discharge lithium ion battery and negative electrode material thereof

A technology of lithium ion battery and negative electrode material, applied in battery electrodes, secondary batteries, circuits, etc., can solve the problems of poor kinetics and low specific capacity, achieve good electronic conductivity, high specific capacity, and is conducive to large-scale The effect of production and use

Pending Publication Date: 2022-04-26
BEIHANG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The invention intends to solve technical problems such as poor charging and discharging kinetics, low specific capacity, and risk of lithium analysis in low temperature charging and discharging of existing lithium ion battery negative electrode materials.

Method used

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  • Low-temperature charge-discharge lithium ion battery and negative electrode material thereof
  • Low-temperature charge-discharge lithium ion battery and negative electrode material thereof
  • Low-temperature charge-discharge lithium ion battery and negative electrode material thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0041] (1) Negative electrode sheet preparation: use commercial cuprous sulfide Cu 2 S is used as the negative electrode active material, figure 1 The X-ray diffraction spectrum of the negative electrode material is shown, which proves that it is cuprous sulfide in monoclinic phase. Negative electrode active material, conductive agent Ketjen black, and binder sodium alginate were mixed in a mass ratio of 7:2:1, added water and stirred evenly, then evenly coated on the copper foil current collector, and dried in vacuum at 80°C Obtain the negative pole piece, the load capacity of negative pole active material is 3mg / cm 2 .

[0042] (2) Half-cell preparation: use metal lithium foil as the counter electrode, glass fiber as the diaphragm, and select 1 mol / L lithium bistrifluoromethanesulfonimide (LiTFSI) as the electrolyte dissolved in 1,3-dioxolane ( DOL), ethylene glycol dimethyl ether (DME) mixed solution (DOL:DME=1:1Vol%), in a glove box with water and oxygen content lower t...

Embodiment 2

[0044] (1) Preparation of the negative pole piece: the negative pole piece was prepared by the method in step (1) of Example 1.

[0045] (2) Positive electrode sheet preparation: use commercial NMC811 as the positive active material, mix positive active material, conductive agent Ketjen black, and binder PVDF at a mass ratio of 7:2:1, add N-methylpyrrolidone and stir evenly , uniformly coated on the aluminum foil current collector, and dried in vacuum at 80°C to obtain a positive electrode sheet, the loading capacity of the positive active material is 7mg / cm 2 .

[0046] (3) Lithium-ion battery preparation: use glass fiber as the diaphragm, choose 1mol / L lithium bistrifluoromethanesulfonimide (LiTFSI) as the electrolyte, dissolve in 1,3-dioxolane (DOL), ethylene glycol In a mixed solution of dimethyl ether (DME) (DOL:DME=1:1Vol%), in a glove box with water and oxygen content lower than 0.1ppm , diaphragm, electrolyte, positive electrode sheet, gasket, and positive electrode ...

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Abstract

Copper-based sulfide CuxS (1 < = x < = 2) is used as the negative electrode material of the low-temperature lithium ion battery, the material is used as a negative electrode, and one of a nickel cobalt manganese (NCM) ternary material, a nickel cobalt aluminum (NCA) ternary material, a lithium iron phosphate (LiFePO4) material, a lithium cobalt oxide (LiCoO2) material and a lithium manganate (LiMn2O4) material is used as a positive electrode. And matching to form the lithium ion total battery. The copper-based sulfide involved in the negative electrode material can be subjected to constant-current charging and discharging under the low-temperature condition of-60 DEG C, and provides the specific capacity of 182mAh / g, which is equivalent to 52% of the capacity at 25 DEG C; and the lithium ion battery has high working voltage (1.8 V relative to Li < + > / Li), has no risk of lithium precipitation during low-temperature charging and discharging, has a constant-current charging and discharging cycle life of more than 60 times at-60 DEG C, and provides guarantee for safe and stable charging and discharging of the lithium ion battery under an extremely low-temperature condition.

Description

technical field [0001] The invention relates to the field of lithium ion batteries, in particular to a lithium ion battery capable of charging and discharging at low temperature (-60°C) and a method for preparing the negative electrode material thereof. Background technique [0002] Due to the advantages of high voltage, high energy density, and long cycle life, lithium-ion batteries have been widely used in portable electronic devices and new energy vehicles. At present, the application of lithium-ion batteries is gradually expanding to fields such as deep sea exploration, polar scientific research, national defense and military industry, aerospace and other fields. These application scenarios have high requirements for the low-temperature charge and discharge performance of lithium-ion batteries. For example, deep-sea exploration requires lithium Ion batteries can work normally at -40°C, while the aerospace field further requires a harsher -80°C. At present, the ideal ope...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/58H01M4/136H01M10/0525H01M4/62
CPCH01M4/5815H01M10/0525H01M4/136H01M4/621H01M4/624H01M2004/027
Inventor 朱禹洁陈奕帆
Owner BEIHANG UNIV