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High-thermal-conductivity elastomer applied to new energy charging pile cable and preparation method

A charging pile, high thermal conductivity technology, applied in electric vehicle charging technology, electric vehicles, vehicle energy storage, etc., can solve the problems of cable service life reduction, poor light and thermal stability, poor aging resistance, etc., to reduce the transmission of electric energy, Strong light aging resistance and the effect of improving mechanical properties

Active Publication Date: 2022-08-05
ADVANCED THERMOPLASTIC POLYMER TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Due to the large load current value of the cable used for the charging pile (up to 400A), the conductor of the cable is prone to heat when it is energized, and it is frequently dragged and moved during use. The destruction and corrosion of air oxidation, wet water environment, and acid-base compounds and other factors, therefore, put forward higher requirements for the performance indicators of cables for charging piles. Polyvinyl chloride is widely used due to its convenient processing, excellent flame retardancy and low price In the wire and cable industry, but its stability to light and heat is poor, and its unstable group containing chlorine atoms is easy to release hydrogen chloride under the action of alkali, heat, light and other conditions to form a conjugated structure, which in turn causes material deformation. Brittle, and the thermal conductivity of polyvinyl chloride is poor. Under high temperature conditions, it is easy to form thermal stress concentration and cause micro-decomposition. Therefore, the PVC cable material used in the existing new energy charging pile cables has poor thermal conductivity and poor aging resistance. The service life is greatly reduced. Therefore, it is a technical problem to be solved to provide a high thermal conductivity elastomer used in new energy charging pile cables.

Method used

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  • High-thermal-conductivity elastomer applied to new energy charging pile cable and preparation method
  • High-thermal-conductivity elastomer applied to new energy charging pile cable and preparation method
  • High-thermal-conductivity elastomer applied to new energy charging pile cable and preparation method

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] The present embodiment provides a modified carbon nanotube, which is made by the following steps:

[0038] Step A1: Mix 0.01mol tetramethylpiperidinol, 0.8g sodium hydroxide, 0.04g methyltrioctylammonium chloride and 30mL anhydrous toluene, add cyanuric chloride solution dropwise in a water bath at 40°C, and stir The reaction was carried out for 4 h, filtered, and the filtrate was distilled under reduced pressure to remove toluene to obtain intermediate 1. The cyanuric chloride solution in toluene was prepared by mixing cyanuric chloride and toluene according to the dosage ratio of 0.01 mol: 20 mL;

[0039] Step A2: Mix 3.36g of Intermediate 1, 50mL of anhydrous toluene, and 1.25g of potassium carbonate, under nitrogen protection, stir in a water bath at 50°C, and then add allylamine toluene solution dropwise. After the dropwise addition, stir and react for 3h, filter , the filtrate is distilled under reduced pressure to remove toluene to obtain intermediate 2, and the ...

Embodiment 2

[0045] The present embodiment provides a modified carbon nanotube, which is made by the following steps:

[0046] Step A1: Mix 0.01 mol of tetramethylpiperidinol, 1.0 g of sodium hydroxide, 0.04 g of methyltrioctyl ammonium chloride and 40 mL of anhydrous toluene, add cyanuric chloride solution dropwise in a water bath at 40°C, and stir The reaction was carried out for 5 h, filtered, and the filtrate was distilled under reduced pressure to remove toluene to obtain intermediate 1. The cyanuric chloride solution in toluene was prepared by mixing cyanuric chloride and toluene according to the dosage ratio of 0.01 mol: 20 mL;

[0047] Step A2: Mix 3.36 g of Intermediate 1, 80 mL of anhydrous toluene, and 1.38 g of potassium carbonate, and under nitrogen protection, stir in a water bath at 50 °C, and then add allylamine toluene solution dropwise. After the dropwise addition, stir and react for 4 hours, and filter , the filtrate is distilled under reduced pressure to remove toluene ...

Embodiment 3

[0053] The present embodiment provides a kind of modified nano titanium dioxide, which is made by the following steps:

[0054] Step B1, put 35mL of anhydrous toluene in a three-necked flask, add 0.1mol KH-550, ice bath condition, dropwise add 0.105mol epichlorohydrin, after the dropwise addition, stir the reaction for 1h, remove the ice bath after the reaction is completed , continue to stir for 2h, spin the reaction product, when no more droplets drip from the condenser, place under vacuum and stir for 2h to obtain chlorosilane;

[0055] Step B2: Mix 0.1 g of chlorosilane, 10 mL of deionized water and 10 mL of absolute ethanol, add 2 g of nano-titanium dioxide, and stir for 4 hours. After the reaction, centrifuge at a speed of 1500 r / min, and wash the precipitate with deionized water for 3 times. , and vacuum dried to constant weight at 80°C to obtain modified nano-titanium dioxide.

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Abstract

The invention relates to a high thermal conductivity elastomer applied to a new energy charging pile cable and a preparation method thereof, and belongs to the technical field of high polymer materials, the high thermal conductivity elastomer comprises the following raw materials by weight: 100 parts of PVC resin, 20-30 parts of a polyurethane elastomer, 10-12 parts of modified carbon nanotubes, 3-5 parts of modified nano titanium dioxide, 5-10 parts of a plasticizer, 2-3 parts of an antioxidant, 4-7 parts of a stabilizer, and 2-4 parts of stearic acid; the heat conductivity coefficient of the elastomer material prepared by the invention is about 2.0 W / m.K, and compared with a traditional cable elastomer material, the elastomer material has relatively high heat conductivity, relatively high mechanical property and strong light aging resistance; the cable accessory prepared from the elastomer material has high heat dissipation and aging resistance, can reduce the lost transmission electric energy and improve the current-carrying capacity of the cable, and has long service life.

Description

technical field [0001] The invention belongs to the technical field of polymer materials, and in particular relates to a high thermal conductivity elastomer applied to a new energy charging pile cable and a preparation method. Background technique [0002] Compared with traditional vehicles, new energy electric vehicles have the characteristics of stable operation, no noise, no pollution, low carbon emissions, high safety, etc., and have broad market application prospects. With the large-scale promotion and industrial application of electric vehicles, The demand for electric vehicle charging pile cables has also doubled. [0003] Due to the large load current value of the cables used for charging piles (up to about 400A), the conductors are prone to heat during the power-on operation of the cables, and they are frequently dragged and moved during use, and are exposed to the outdoor environment for a long time. Air oxidation, wet water environment and damage and corrosion of...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L27/06C08L75/04C08K3/04C08K3/22C08K9/04C08K9/06
CPCC08L27/06C08K2201/011C08K2003/2241C08L2201/08C08L75/04C08K3/041C08K3/22C08K9/04C08K9/06Y02T90/14Y02T10/70Y02T10/7072
Inventor 刘悦李同兵钟荣栋
Owner ADVANCED THERMOPLASTIC POLYMER TECH
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