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Process for preparing metal oxide nano powder

An oxide and nanopowder technology, applied in titanium oxide/hydroxide, zirconium oxide, titanium dioxide and other directions, can solve the problems of pollution and high cost, and achieve the effect of simple process, low equipment investment and low production cost

Inactive Publication Date: 2006-06-28
YANGZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the metal alkoxide method needs to use a large amount of expensive organometallic compounds, and the organic substances used as solvents are often some toxic substances; so this method is expensive and easily causes pollution problems

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Take 100g of titanium tetrachloride liquid, slowly add 150ml of distilled water for hydrolysis, and add 300ml of distilled water to dilute to about 500ml. Slowly add 25% ammonia water dropwise under vigorous stirring until the pH is 9 to obtain titanium hydroxide gel. Suction filter and wash the titanium hydroxide gel until there is no chloride ion (0.1M AgNO 3 test). Mix the wet titanium hydroxide gel and ethanol in a mass ratio of 1:0.5, place it in an autoclave, keep it at 120°C at about 0.3MPa for 8 hours, then cool to room temperature, filter, and dry at 110°C for 6 hours , roasted at 350°C for 4h in a high-temperature furnace to obtain titanium dioxide nanopowder.

[0021] Sample after N 2 The specific surface area, particle size, particle size distribution and crystal shape of the nano-powder were measured by adsorption BET, TEM and XRD respectively, and the bulk density of the nano-powder was measured by the stacking method. The specific surface area of ​​th...

Embodiment 2

[0023] Take 80 g of zirconium oxychloride solid, add 300 ml of distilled water to dissolve. Slowly add 20% ammonia water dropwise under vigorous stirring until the pH is 9 to obtain zirconium hydroxide gel. Suction filter and wash the zirconium hydroxide gel until there is no chloride ion (0.1M AgNO 3 test). Mix the wet zirconium hydroxide gel and ethanol in a mass ratio of 1:1, place it in an autoclave, and keep it at 120°C at about 0.3Mpa for 8 hours, then cool to room temperature, filter, and dry at 110°C for 6 hours , roasted in a high-temperature furnace at 450°C for 6 hours to obtain zirconia nanopowder.

[0024] Sample after N 2 The specific surface area, particle size, particle size distribution and crystal shape of the nano-powder were measured by adsorption BET, TEM and XRD respectively, and the bulk density of the nano-powder was measured by the stacking method. The specific surface area of ​​the resulting zirconia is 213m 2 / g, the particle size is 8.6nm (TEM)...

Embodiment 3

[0026] Take 95g of titanium tetrachloride liquid, slowly add 150ml of distilled water for hydrolysis, and add 300ml of distilled water to dilute to about 500ml. Aluminum trichloride (AlCl 3 ·6H 2 O) 10g, stirred to dissolve it. Slowly add 15% ammonia water dropwise under stirring until the pH is 9 to obtain a titanium hydroxide-aluminum mixed gel. Suction filter and wash the titanium hydroxide-aluminum mixed gel until there is no chloride ion (0.1M AgNO 3 test). Mix the wet titanium hydroxide-aluminum mixed gel with ethanol in a mass ratio of 1:0.8, place it in an autoclave, and keep it at 130°C at about 0.35Mpa for 4 hours, then cool to room temperature, filter, 110 ℃ drying for 6 hours, and calcination in a high-temperature furnace at 500 ℃ for 4 hours to obtain titanium-aluminum composite oxide nanopowder.

[0027]Sample after N 2 The specific surface area, particle size, particle size distribution and crystal shape of the nano-powder were measured by adsorption BET, ...

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Abstract

A process for preparing the nano-particles of metallic oxide includes such steps as dissolving metallic salt in water to obtain aqueous solution of sol, mixing it with ammonia water to become gel of metallic hydroxide, ageing, filtering, water washing to obtain wet gel, mixing it with alcohol, alcoholizing reaction, filtering, baking and calcining. It has high catalytic performance and catalyst carrier effect.

Description

technical field [0001] The invention relates to a method for preparing titanium oxide, zirconium oxide and titanium-zirconium-based composite oxide nanopowder, which belongs to the technical field of chemical catalyst preparation. Background technique [0002] Generally speaking, the smaller the particle size of a solid particle, the larger its specific surface area will be. As a catalyst, the larger the specific surface area, the more catalytic active centers provided per unit surface, and the higher the catalytic activity, which is beneficial to the conversion of reactants. Metal oxides are commonly used catalysts or catalyst supports. The commonly used methods for preparing metal oxides include dispersion method, solvent evaporation method, precipitation method and so on. The process of preparing metal oxides by precipitation method is simple, the performance of the obtained nano-powder is good, and it is easy to add other trace elements. The particles are larger. In ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01G23/053C01G25/02C04B35/624C04B35/49C04B35/462
Inventor 菅盘铭徐林沈常美高强
Owner YANGZHOU UNIV
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