External electric field induced orientation sedimentation method for preparing nano gap
A deposition method and nano-gap technology, applied in nanotechnology, nanotechnology, nanostructure manufacturing, etc., can solve problems such as the gap between prototype electrode pairs cannot be too large, the requirements for prototype electrode pairs are high, and the thickness and lateral width of the electrode surface are increased. , to achieve the effect that the device is simple and easy to control, the method is simple, and the process is easy
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Embodiment 1
[0016] Embodiment 1: A pair of gold electrodes with a micron or submicron gap is processed on a silicon-based material by a common photolithography process, and this is used as a prototype electrode. After degreasing the surface of the gold prototype electrode with an organic solvent (acetone or ethanol), put it in a freshly prepared piranha solution (sulfuric acid: hydrogen peroxide = 3: 1, volume ratio) for 15 minutes, take it out and rinse it with water, and use nitrogen flow Blow dry; then put the above electrode into the ethanol solution of the bifunctional molecular mercapto compound HS-R-Y (such as mercaptoethylamine or 1,6-hexanedithiol) for molecular assembly; put the electrode assembled with the bifunctional molecule into Colloidal gold nanoparticles are chemically adsorbed in the colloidal gold solution for electrode surface activation treatment. Put the above-mentioned surface-activated electrode into the electroless gold plating solution, and apply an alternating ...
Embodiment 2
[0017] Embodiment 2: A pair of silver electrodes with a (sub)micron gap is processed on a silicon-based material by a common photolithography process, and this is used as a prototype electrode. After cleaning the surface of the silver prototype electrode with an organic solvent (acetone or ethanol), put it into an ethanol solution of a bifunctional molecular mercapto compound HS-R-Y (such as mercaptoethylamine or 1,6-hexanedithiol, etc.) for molecular assembly; The silver electrode assembled with bifunctional molecules is put into colloidal silver or silver ion solution for activation. The above-mentioned surface-activated silver electrodes are put into silver, gold, copper, nickel, cobalt or alloy electroless plating solutions respectively, and an alternating electric field (voltage peak value of the alternating electric field) is applied along the direction of the electrode pair outside the electroless plating reactor 10~1000V / cm, frequency 10~10 6 Hz), induce the metal to ...
Embodiment 3
[0018] Embodiment 3: A platinum electrode pair with a micron or submicron gap is processed on a silicon-based material by a common photolithography process, and this is used as a prototype electrode. After cleaning the surface of the platinum prototype electrode, put it into the ethanol solution of hydroxycarboxylic acid, hydroxyphosphinecarboxylic acid or aminophosphinecarboxylic acid for molecular assembly; put the platinum electrode assembled with functional molecules into colloidal platinum solution or platinum ion solution Electrode surface activation treatment is carried out. Put the above-mentioned surface-activated platinum electrode into the electroless platinum plating solution, and apply an alternating electric field along the direction of the electrode pair outside the electroless plating reactor (the voltage peak value of the alternating electric field is 10~1000V / cm, and the frequency is 10 ~10 6 Hz), the metal platinum is induced to preferentially deposit and g...
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