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77results about How to "Increased active surface" patented technology

Method for improving pore structure of kaolin microsphere in-situ crystallization product

The invention relates to a method for improving the pore structure of a kaolin microsphere in-situ crystallization product. The method comprises the following steps of: preparing kaolin spray microspheres with the particle sizes of between 20 and 110 mu m by using mixed kaolin grout by spray drying, wherein the mixed grout comprises kaolin, deionized water, a dispersant and an organic pore cannelforming template agent; the dispersant is sodium silicate or sodium pyrophosphate; and the organic pore cannel forming template agent is polyvinyl pyrrolidone or polyvinyl alcohol; baking the spray microspheres at the temperature of between 900 and 1,100 DEG C for 1 to 3 hours so as to obtain kaolin baked microspheres; mixing the kaolin baked microspheres with the mullite content of between 2 and12 percent, sodium silicate, a directing agent, solution of sodium hydroxide and deionized water; crystalizing the mixture at the temperature of between 90 and 95 DEG C for 16 to 36 hours; and filtering and drying so as to obtain a crystallization product which has a medium / large-pore structure and comprises a NaY molecular sieve. The crystallization product has a well-developed large-pore structure and the abrasion index of not more than 1.5 percent and comprises 20 to 50 percent of NaY molecular sieve.
Owner:PETROCHINA CO LTD +1

Zr-Co-Re thin film getter provided with protection layer, and preparation method thereof

The invention relates to a Zr-Co-Re thin film getter provided with a protection layer, and a preparation method thereof. The Zr-Co-Re thin film getter is composed of a getter layer and the protection layer; main components of the getter layer are Zr, Co, and one or more selected form rare earth elements La, Ce, Pr, and Nd; and main component of the protection layer is Ni. Pulsed laser deposition film plating is adopted, and deposition of the double-layer structured thin film getter containing the protection layer and the getter layer on texture monocrystalline silicon is carried out. The texture substrate is capable of increasing effective area of the getter thin film, and so that inspiratory flow rate and inspiratory capacity are increased. The surface of the getter layer is plated with a Ni protection layer; Ni is capable of realizing dissociation of hydrogen, and increasing absorption amount of hydrogen; and the Ni protection layer is capable of inhibiting absorption of oxygen and reducing activation temperature. Activation of the Zr-Co-Re thin film getter can be realized in roasting processes at a temperature of 180 to 350 DEG C; after roasting, the Zr-Co-Re thin film getter possesses excellent inspiration performance at room temperature, can be used for internal gas residue removing of high vacuum microelectronic devices.
Owner:GENERAL RESEARCH INSTITUTE FOR NONFERROUS METALS BEIJNG

CuO/Cu nanowire negative electrode material in core-shell structure and preparation method and application thereof

The invention discloses a CuO / Cu nanowire negative electrode material in a core-shell structure and a preparation method and application of the CuO / Cu nanowire negative electrode material. The CuO / Cu nanowire negative electrode material is mainly composited from CuO and Cu, wherein the Cu is in a nanowire shape, the CuO is flower-like, the Cu serves as an inner core of the nanowire negative electrode material, and the CuO is coated on the outer surface of the Cu to form the core-shell structure. The preparation method comprises the following steps: copper acetate, ethidene diamine and a hydrazine hydrate solution are added in a sodium hydroxide solution, the mixture is sealed and then put into a water bath of 60-80 DEG C to be heated to obtain a copper nanowire suspension liquid, then the copper nanowire is separated, washed, and immersed in hydrogen peroxide, the flower-like CuO grows on site on the surface of the copper nanowire, and is separated, washed and dried to obtain the CuO / Cu nanowire negative electrode material in the core-shell structure. The CuO / Cu nanowire negative electrode material in the core-shell structure can be used to prepare a negative electrode for a high-conductivity lithium ion battery, and has better electrical conductivity and mechanical property.
Owner:CHANGSHA RES INST OF MINING & METALLURGY

Novel ferroferric oxide nano-particle and silicon oxide nano-fiber compounded Fenton-like catalyst and preparation method thereof

The invention discloses a novel ferroferric oxide nano-particle and silicon oxide nano-fiber compounded Fenton-like catalyst and a preparation method thereof. The content of ferroferric oxide nano-particle in the catalyst is 15wt%-50wt%. The preparation method comprises the following steps: taking silicon oxide nano-fiber as a carrier; slowly heating and decomposing ferric acetylacetonate in an organic solvent, thereby generating fine ferroferric oxide nano-particle and growing on the surface of the silicon oxide nano-fiber carrier; quickly increasing the temperature, thereby increasing the degree of crystallinity of the nano-particle; and roasting, thereby forming the novel ferroferric oxide nano-particle and silicon oxide nano-fiber compounded Fenton-like catalyst. The novel ferroferric oxide nano-particle and silicon oxide nano-fiber compounded Fenton-like catalyst provided by the invention has the characteristics of easiness in magnetism recovery, excellent dispersity in water, high adsorption capacity, high Fenton catalytic activity, and the like. The invention has the advantages of simple preparation process, short production period, high controllability, low demand on equipment and easiness in large-scale production.
Owner:CENT SOUTH UNIV

Preparation method of copper cobaltate porous microrod and nickel foam composite electrode material

The invention belongs to the field of preparation of inorganic nonmetallic materials, and particularly relates to a preparation method of a copper cobaltate porous microrod and nickel foam composite electrode material. The preparation method comprises the steps that clean nickel foam is soaked in an oxalic acid aqueous solution, and a mixed aqueous solution of soluble copper salt and soluble cobalt salt is dropwise added into the oxalic acid aqueous solution under the condition of stirring at room temperature; stirring reaction is conducted till micron-structure precursors grow out on the surface of the nickel foam, the nickel foam is taken out, cleaning, drying and calcining are sequentially conducted, and the copper cobaltate porous microrod and nickel foam composite electrode material is obtained. According to the preparation method of the copper cobaltate porous microrod and nickel foam composite electrode material, the technology is simple and easy to carry out, the product purity is high, the preparation cost is low, the diameter of a copper cobaltate microrod ranges from 0.5 micrometer to 2 micrometers, the length of the copper cobaltate microrod is about 5-10 micrometers, the size of a nano pore channel ranges from 10 nm to 50 nm, the uniformity and the dispersity of the product are both good, the copper cobaltate porous microrod and nickel foam composite electrode material can be directly applied to electrode materials of supercapacitors, the production technology is simple, and the preparation method is prone to be applied to practical large-scale production.
Owner:BOHAI UNIV

Preparation method and application of vanadyl phosphate catalyst

The invention relates to a vanadyl phosphate catalyst, an intensified preparation method by low congruent melting solvent, and application of the vanadyl phosphate catalyst. The method comprises the following steps: 1) mixing a vanadium source, low congruent melting solvent, benzyl alcohol and C3-C8 monohydric alcohol to obtain mixed materials, and reacting, wherein the low congruent melting solvent is formed by choline chloride and organic polyhydric alcohols; 2) mixing a reaction product obtained in 1) with a phosphorus source, raising the temperature to 100-200DEG C, and continuously reacting to obtain a vanadyl phosphate precursor; 3) roasting to obtain the vanadyl phosphate catalyst. The method is characterized in that green and low-price low congruent melting solvent is subjected tointensified preparation to obtain the vanadyl phosphate catalyst, the defects of secondary pollution, high cost, complex preparation process and the like since the performance of the vanadyl phosphatecatalyst is improved on the basis of noble metal are overcome. When the vanadyl phosphate catalyst is used for catalytic normal butane selectivity oxidation maleic anhydride reaction, the difficulties including low yield, poor selectivity and the like, are solved, and defects of high cost and serious pollution in a traditional catalyst improvement method are overcome.
Owner:INST OF PROCESS ENG CHINESE ACAD OF SCI

Ectropis grisescens warreh nuclear polyhedrosis virus bakthane insect disinfestation suspension agent and preparation method thereof

The invention discloses an ectropic obliqua nuclear polyhedrosis virus bacillus thuringiensis desinsection suspending agent and a preparation method thereof. The agent mainly comprises the ectropic obliqua nuclear polyhedrosis virus and the bacillus thuringiensis, wherein the content of the inclusion body of the ectropic obliqua nuclear polyhedrosis virus is (1.0x10<6>-1.0x10<10>)PIB/mL, and the content of the bacillus thuringiensis is between 3.0 and 25.0 percent. The ectropic obliqua nuclear polyhedrosis virus bacillus thuringiensis desinsection suspending agent comprises the ectropic obliqua nuclear polyhedrosis virus, the bacillus thuringiensis, polycarboxylate, sodium lignosulfonate, dioctyl sulfo succinic acid, alkyl sulfonate, white carbon black, magnesium aluminum silicatenf, sodium benzoate, xanthan gum, carboxymethyl cellulose, polyvinyl alcohol, glycol, propanediol, organosilicon defoamer and water which are mixed according to certain ratio. The agent and the preparation method thereof are not harmful to environment, organisms and human bodies, do not pollute the environment or have residue, and can effectively control the generation and harm of the ectropic obliqua; and the agent is suitable for the application in a large quantity, has long persistent period, increases the speed of the virus to kill pests, and ensures that the desinsection time of the virus pesticide is shortened to three to five days.
Owner:WUHAN UNIOASIS BIOLOGICAL TECH CO LTD

Microporous ultra-thin soft carbon nanosheet, and preparation method and application thereof

The invention relates to a microporous ultra-thin soft carbon nanosheet electrode material, and a preparation method and an application thereof. The thickness of the microporous ultra-thin soft carbonnanosheet electrode material is 20-30nm, and the morphology is a nanosheet having a uniform size; the microporous ultra-thin soft carbon nanosheet electrode material has a surface with a pleated structure; and the microporous ultra-thin soft carbon nanosheet electrode material has a large number of micropores and defect sites at the edge of a crystal lattice to provide additional ion storage sites. The microporous ultra-thin soft carbon nanosheet electrode material provided by the invention has the beneficial effects that the microporous ultra-thin soft carbon nanosheet electrode material hasa larger specific surface area and a large number of microporous structures than the conventional soft carbon electrode material, thereby and not only enhancing the diffusion performance of ions in amaterial body, but also increasing active interfaces between the material and the electrolyte, enhancing the kinetics of the material in an electrochemical reaction process, improving the capacitivecapacity contribution, exhibiting excellent rate performance and and achieving rapid charge and discharge.
Owner:WUHAN UNIV OF TECH

Gaseous hydrocarbon self-heating conversion catalyst and preparation method thereof

ActiveCN104549284AIncrease active metal dispersionGuaranteed catalyst activityMetal/metal-oxides/metal-hydroxide catalystsHydrogen productionOxide
The invention belongs to the technical field of gaseous hydrocarbon conversion catalysts, and relates to a catalyst for the field of synthesis gas produced by gaseous hydrocarbon self-heating conversion or hydrogen production and a preparation method of the catalyst. According to the catalyst disclosed by the invention, nickel is used as an active component; SiO2 at free state and 3Al2O3*2SiO2 of a mullite structure are used as carriers; MgO and / or a rare earth metal oxide are used as auxiliaries. The preparation method comprises the following steps: adopting a pulping method or a dry mixing method to prepare a semi-finished product, and then molding and baking the semi-finished product to obtain the finished product catalyst. The catalyst is high in anti-carbon deposition performance, good in strength and strength stability, and good in reactive metal dispersion effect, effectively avoids the reactive metal crystal grain aggregation in the using process, ensures the activity stability of the catalyst, and facilitates large-scale industrial production.
Owner:CHINA PETROLEUM & CHEM CORP

Thidiazuron suspension cotton defoliating agent

The invention provides a thidiazuron suspension cotton defoliating agent, which comprises the following components in percentage by weight: 47.5 to 52.5 percent of thidiazuron, 3 to 6 percent of GY-D01, 1 to 3 percent of GY-D04, 2 to 3.5 percent of naphthalene sulfonate polycondensate, 0.4 to 1.2 percent of alkyl naphthalene acid salt, 0.05 to 0.15 percent of xanthan gum, 0.3 to 4.0 percent of dimethyl silicon oil, 4.5 to 5.5 percent of ethylene glycol and the balance of water. The thidiazuron suspension cotton defoliating agent has the advantages of small particular size, large active surface area, high seepage force, no dust during medicine preparation, low cost, high medicine effect, cold and freezing resistance and the like. The thidiazuron suspension cotton defoliating agent has the advantages of both wettable powder and missible oil, can be wetted by water, has high suspension property after being diluted by water, and can be directly prepared into spray liquid to be used. The thidiazuron suspension cotton defoliating agent can effectively prevent cotton from remaining green when it is due to become yellow and ripe and delaying ripping, promote cotton bolls to open, improve flower rate before frosting, increase yield and improve cotton quality, and is an ideal medicinal agent for machine picking and manual picking.
Owner:XINJIANG JINHUA PESTICIDE

Preparation method of manganese (III) oxide porous micro-sheet/foamed nickel combined electrode material

The invention belongs to the preparation field of inorganic non-metallic materials, and especially relates to a preparation method of a manganese (III) oxide porous micro-sheet/foamed nickel combined electrode material. The method comprises the steps: immersing clean foamed nickel into an oxalic acid aqueous solution, adding a potassium permanganate aqueous solution drop by drop into the above solution at a room temperature and in a stirring condition, conducting stirring reaction until a micro-structure precursor grows on the surface of the foamed nickel, taking out the foamed nickel, conducting cleaning, drying and calcining in sequence, and finally obtaining a manganese (III) oxide porous micro-sheet/foamed nickel combined electrode material. The preparation method is simple and convenient, is low in manufacture cost, and produces products that have high purity. A manganese (III) oxide micro-sheet is 200-300nm in thickness and 3-5[Mu]m in dimension. The dimension of a nano-scale porous channel is 10-30nm. Products have great uniformity and dispersibility, can be directly applied to super-capacitor electrode materials, and can be easily applied to actual large-scale production.
Owner:BOHAI UNIV
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