Preparation method of gravure water-based ink

A water-based ink, gravure technology, applied in the field of printing ink, can solve the problems of poor resolubility, gap between gloss and printability, unstable PH of the system, etc., to achieve the effect of good adhesion and good printability

Active Publication Date: 2010-05-12
江苏卫星新材料股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The second-generation water-based ink uses solution-type styrene-acrylic acid copolymer resin as the linking material. The water-based ink developed at this time has significantly improved storage stability and water resistance. For example, Chen Lan and others use ketone aldehyde prepolymer Copolymerized with acrylates, the prepared water-based resin has the advantages of good gloss, good adhesion, excellent film-forming performance, strong water resistance and weather resistance after film formation, and water-based acrylate polymers. Excellent weather resistance, transparency and film-forming properties and better water solubility, but there is still a gap with solvent-based inks in terms of gloss and printability
In short, as far as the current water-based ink is concerned, whether it is high-grade water-based ink or low-grade water-based ink, there are unresolved problems such as unstable pH of the system, poor resolubility, and limited application in alkaline conditions, freezing environments, and high magnetic environments. question

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] First, mix and stir 10KG of acrylic acid, 3KG of styrene, 3KG of vinyl acetate, 4KG of water, 0.2KG of sodium lauryl sulfate, and 0.05KG of ammonium persulfate to obtain acrylic acid-styrene-vinyl acetate Ternary copolymer emulsion interpenetrating network water-soluble resin.

[0022] Then, the prepared acrylic-styrene-vinyl acetate terpolymer emulsion interpenetrating network water-soluble resin weighed 10KG and 2.5KG of transparent yellow pigment, 2KG of water, 1KG of isopropanol, 3KG of ethanol, 0.05 KG of defoamer SP-23, 0.05KG of wetting agent SP60, 0.05KG of leveling agent 2020, 0.05KG of polyacrylic acid sodium salt (TD-01), 0.05KG of methyltrimethoxysilane, 0.01KG The salicylophenone is placed in the ink mixing tank together, stirred on the mixer, the pigment mass is broken, the solid particles are fully mixed with the liquid linking material, the pigment is fully wetted and dispersed, and a paste ink is formed; Put the pasty ink in a three-roll ink press, and...

Embodiment 2

[0024] First, mix and stir 10KG of acrylic acid, 4KG of styrene, 3.5KG of vinyl acetate, 5KG of water, 0.8KG of sodium stearate, and 0.1KG of potassium persulfate to obtain acrylic acid-styrene-vinyl acetate three Meta-copolymerization emulsion interpenetrating network water-soluble resin.

[0025] Then, the prepared acrylic acid-styrene-vinyl acetate terpolymer emulsion interpenetrating network water-soluble resin weighed 10KG and 3.5KG of pink pigment, 3KG of water, 1KG of isopropanol, 3KG of ethanol, 0.1KG Defoamer F116, 0.1KG wetting agent OT75, 0.1KG leveling agent 475, 0.06KG polycarboxylate sodium salt (SN-Dispersant-5040), 0.07KG methyltriethoxysilane, 0.03 KG of sodium pentachlorophenolate is placed in the ink tank together, stirred on the mixer, the pigment group is broken, the solid particles are fully mixed with the liquid linking material, the pigment is fully wetted and dispersed, and a paste ink is formed ; Put the pasty ink in the three-roll ink press, and rep...

Embodiment 3

[0027] First, mix and stir 10KG of acrylic acid, 4KG of styrene, 4KG of vinyl acetate, 6KG of water, 0.4KG of sodium lauryl sulfate, and 0.06KG of potassium persulfate to obtain acrylic acid-styrene-vinyl acetate Ternary copolymer emulsion interpenetrating network water-soluble resin.

[0028]Then, the prepared acrylic-styrene-vinyl acetate terpolymer emulsion interpenetrating network water-soluble resin weighed 10KG and 5KG of carbon black pigment, 4KG of water, 3KG of isopropanol, 1.5KG of ethanol, 0.15 KG of defoamer D108, 0.07KG of wetting agent M301, 0.08KG of leveling agent FS1200, 0.1KG of sodium naphthalenesulfonate polymer (PD), 0.06KG of octyltriethoxysilane, 0.05KG Put the sodium pentachlorophenolate together in the ink tank, stir on the mixer, break the pigment group, and mix the solid particles and the liquid linking material fully, so that the pigment is fully wetted and dispersed to form a paste ink; Put the pasty ink in a three-roller ink press, and repeat the...

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PUM

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Abstract

The invention relates to a preparation method of gravure water-based ink. Most of the existing ink is not environment-friendly enough. The preparation method comprises the following steps: firstly, mixing and evenly stirring acrylic acid, styrene, vinyl acetate, water, an emulsifier and an initiator to obtain acrylic acid-styrene-vinyl acetate copolymer emulsion interpenetrating network-type water-soluble resin; then placing the acrylic acid-styrene-vinyl acetate copolymer emulsion interpenetrating network-type water-soluble resin and pigment, water, isopropyl alcohol, ethanol, a defoamer, a wetting agent, a leveling agent, a dispersant, a coupling agent and an antibacterial agent in an ink preparing barrel, and stirring to form a pasty ink material; and placing the pasty ink material in a three-roller ink grinding mill for ink grinding to lead pigment particles to be smashed completely and uniformly dispersed into a liquid binder, thus preparing the gravure water-based ink. The method is simple in technology, and the prepared ink has good printability, moisture friction resistance, high gloss and good adhesion, therefore, the gravure water-based ink can be used for different types of paper.

Description

technical field [0001] The invention belongs to the technical field of printing inks, and relates to a method for preparing gravure water-based ink, in particular to a method for preparing gravure water-based ink with an interpenetrating network water-soluble resin. Background technique [0002] Paper and plastic film are currently one of the main packaging materials. In traditional printing, organic solvent-based inks are mostly used for printing, especially in food packaging printing. Due to the use of organic solvent inks, hydrocarbons and residual solvents will be emitted, polluting the air and packaging items, and endangering health. With the continuous improvement of people's awareness of environmental protection, green environmental protection has become the development theme of the 21st century. In recent years, many countries have increased requirements and restrictions on hygiene and environmental protection in terms of packaging and printing. Therefore, solvent-b...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D11/10C09D11/107
Inventor 胡更生储国海傅建安周国俊项秀阳管力明卢红伟董志超
Owner 江苏卫星新材料股份有限公司
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