Waste water processing method during heavy metal compound production process
A production process and wastewater treatment technology, applied in chemical instruments and methods, multi-stage water/sewage treatment, heating water/sewage treatment, etc., can solve problems such as high energy consumption of evaporation process and surface water pollution in the research and development stage, To achieve the effect of simple and easy method
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Embodiment 1
[0019] Add ammonium sulfide and ammonium bicarbonate to the cobalt carbonate wastewater as precipitant, polyacrylamide as flocculant, and filter and separate the wastewater into cobalt precipitate and ammonium chloride solution containing ammonium bicarbonate. Sales; ammonium chloride solution containing ammonium bicarbonate is almost completely converted into ammonium chloride solution without introducing other impurities. The ammonium chloride solution is concentrated by multi-effect evaporation to obtain evaporative condensate and ammonium chloride concentrate, and the condensate is cooled and crystallized and centrifuged to obtain crystallized ammonium chloride that can be sold outside; the evaporative condensate is relatively pure and can be used for cobalt carbonate of wash water.
Embodiment 2
[0021] When preparing the precursor of multi-element materials for the positive electrode of lithium batteries, the heavy metal compound is a mixture of cobalt, nickel and manganese compounds and a small amount of compounds such as iron, zinc, copper, vanadium, chromium, etc., sodium hydroxide is added to the wastewater as a precipitant, polyacrylamide The mixture with polyaluminum chloride is used as a flocculant, and after filtration and separation, the wastewater is divided into heavy metal precipitation such as cobalt, nickel, manganese, iron, copper, and a solution containing sodium salts such as sodium chloride or sodium sulfate and a small amount of free ammonia. Evaporate the free ammonia in the solution, and finally carry out multi-effect forced circulation evaporation concentration and separation.
Embodiment 3
[0023] When the heavy metal compound is cobalt oxide, sodium sulfide is added to the wastewater as a precipitant, and polyacrylic acid, sodium polyacrylate and calcium polyacrylate are used as flocculants. After filtering and separating into cobalt precipitates, the wastewater containing sodium chloride or sodium sulfate and other sodium salts is obtained. solution, the latter is directly concentrated and separated by multi-effect forced circulation evaporation.
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