Coumarin-thiacalix [4] arene fluorescent reagent as well as preparation method and application thereof
A technology of aromatic hydrocarbon fluorescence and thiacalix, applied in the direction of fluorescence/phosphorescence, chemical instruments and methods, luminescent materials, etc., can solve problems such as poisoning and damage to the immune system
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Example Embodiment
[0085] Example one:
[0086] (1) Synthesis of 1,3-Alternating-Bis(phthalimidoethoxy)thiacalix [4] as an intermediate material
[0087] N 2 Protect, in a 50mL round bottom flask, add thiacalix[4] (721mg, 1.00mmol), N-hydroxyethylphthalimide (1.75g, 8.57mmol), triphenylphosphine (800mg , 3.05mmol), 20 mL of dry tetrahydrofuran, under an ice bath, then slowly add diethyl azodicarboxylate (531mg, 3.05mmol) dropwise, after the addition, stir the reaction at room temperature for 48h, evaporate the solvent, add hot methanol while hot 20 mL, cooled, a large amount of white solid crude product was precipitated, and the crude product was separated by column chromatography (elution machine: ethyl acetate: n-hexane V: V=1: 4) to obtain 748 mg of white product with a yield of 70%. m.p. 288~290℃; 1 H NMR(CDCl 3 , 400 MHz), δ(ppm): 0.738[ s, 9H, C(CH 3 ) 3 ], 1.284[s,9H, C(CH 3 ) 3 ], 4.457(t,2H,J=5.5 Hz, NCH 2 ), 4.880(t,2H,J=6.0Hz,OCH 2 ), 6.828(s,2H,ArH), 7.264(d,2H,J=7.5Hz, OH), 7.487(s,2H, ...
Example Embodiment
[0097] Embodiment two:
[0098] Add the probe compound acetonitrile stock solution (1.00×10 -4 mol·L -1 , 1mL), anion F - (2.00×10 -3 mol·L -1 , 1 mL). Dilute to the mark with acetonitrile solution, shake well, and move it into a 1cm quartz cuvette for fluorescence spectroscopy and ultraviolet-visible absorption spectrometry. The excitation and emission wavelengths measured by the fluorescence spectroscopy of the probe solution are 385 / 454nm.
[0099] The reagents used are analytical reagents, and the test water is double distilled water.
[0100] The model of the fluorescence spectrophotometer used is Cary Eclipse fluorescence spectrophotometer, manufactured by the American VARIAN company. The UV-Visible spectrophotometer model is UV-vis TU-1901, manufactured by Beijing Puxi General Instrument Co., Ltd.
[0101] In the acetonitrile solution, the probe itself has weak fluorescence emission, the excitation wavelength is 385nm, the emission wavelength is 454nm, and the fluorescence...
Example Embodiment
[0106] Embodiment three:
[0107] In a 10.0 mL volumetric flask, add the probe's N,N-dimethylformamide stock solution (1.00×10 -4 mol·L -1 , 1mL), cation Zn 2+ (2.00×10 -3 mol·L -1 , 1 mL). Dilute with N,N-dimethylformamide solution to the mark, shake well, and move it into a 1cm quartz cuvette for fluorescence spectroscopy and ultraviolet-visible absorption spectrometry. The excitation and emission wavelengths measured by the probe's fluorescence spectroscopy are 365 / 450 nm.
[0108] The reagents used are analytical reagents, and the test water is double distilled water.
[0109] The model of the fluorescence spectrophotometer used is Cary Eclipse fluorescence spectrophotometer, manufactured by the American VARIAN company. The UV-Visible spectrophotometer model is UV-vis TU-1901, manufactured by Beijing Puxi General Instrument Co., Ltd.
[0110] In the N,N-dimethylformamide solution, the excitation wavelength is 365nm and the emission wavelength is 450 nm. The fluorescence emissi...
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