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Solar cell, preparation method thereof, and solar cell module comprising solar cell

A technology of solar cells and conductive layers, applied in the field of solar cells, can solve problems such as affecting the performance of silicon substrate sheets, and achieve the effect of reducing costs

Inactive Publication Date: 2015-07-01
BYD CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In order to solve the technical problem that copper atoms pass through the anti-reflection film layer and enter the N+ type silicon to form impurities and affect the performance of the silicon substrate sheet when the existing copper electrodes are used for solar cells, the present invention provides a special conductive layer The special conductive layer plays the role of anti-reflection and conductivity at the same time, and can prevent the copper atoms in the copper electrode from passing through the conductive layer and entering the silicon.

Method used

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preparation example Construction

[0022] The invention provides a method for preparing the solar battery sheet, which method includes preparing a conductive layer, a copper front electrode, and a back electric field on the front and back of the silicon substrate sheet after sequentially performing texturing, diffusion junction, and removal of phospho-silicate glass. , the back electrode to obtain a solar battery sheet.

[0023] The invention provides a preparation method of the solar battery sheet, which does not contain conventional antireflection film layers, conductive layers AZO (aluminum-doped zinc oxide), ITO (tin-doped indium oxide), ATO (antimony-doped tin oxide) or SnO 2 (Tin dioxide) has both anti-reflective and conductive effects. The invention provides a method for preparing the solar battery sheet. Preferably, the method for preparing the copper front electrode is to print the copper front electrode paste on the surface of the conductive layer and then dry, oxidize, reduce and sinter in a tunnel ...

Embodiment 1

[0042] Step 1: Preparation of conductive copper paste

[0043] a. Preparation of the organic vehicle: According to the mass ratio of lauryl alcohol ester: butyl carbitol = 70:30, the organic solvent is mixed evenly to form the mixed solvent of the slurry. Get the mixed solvent of 90.5 mass parts, add the ethyl cellulose STD-4 of 8.0 mass parts (U.S. Dow produces, viscosity specification is 4m Pas), the hydrogenated castor oil of 0.5 mass parts, the cetyl alcohol of 1.0 mass parts, Heat to 65°C to fully dissolve and stir for 4 hours to obtain an organic vehicle.

[0044] b. Preparation of inorganic binder: use medium particle size D 50 Pb powder with a thickness of 0.30±0.1 μm is used as an inorganic binder for copper conductive paste.

[0045] c. Preparation of copper slurry: Stir 10 parts by mass of the organic carrier and place it in the stainless steel tank of the high-speed disperser, add 5.0 parts by mass of fine Pb powder as the inorganic binder while stirring, and sti...

Embodiment 2

[0051] Prepare solar cell sheet S2 according to the method of Example 1, the difference is that the Pb powder therein is replaced by a mixed powder of Pb powder and Sn powder (mass ratio Pb powder: Sn powder=1:1), the Pb powder and Sn powder Medium particle size D 50 Both are 0.30±0.1 μm.

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Abstract

The invention provides a solar cell, which comprises a silicon substrate sheet, a conductive layer covering the front surface of the silicon substrate sheet, a copper front electrode arranged on the surface of the conductive layer, a back surface field arranged on the back face of the silicon substrate sheet, and a back electrode conducted with the back surface field, wherein the conductive layer is an aluminum-doped zinc oxide layer, a tin-doped indium oxide layer, an antimony-doped tin oxide layer or a tin dioxide layer. The invention also provides a solar cell preparation method and a solar cell module comprising the solar cell. The copper back electrode and the copper front electrode obtained by using the technology of the invention have good appearances, strength of welding between the electrodes and a photovoltaic welding strip and electric performance of the cell remain almost the same as those of a battery with silver electrodes prepared by the traditional technology, and in addition, as copper paste is adopted to replace the traditional silver paste, the cost of the cell is greatly reduced.

Description

technical field [0001] The invention belongs to the field of solar cells, and in particular relates to a solar cell sheet, a preparation method thereof, and a solar cell module containing the cell sheet. Background technique [0002] Crystalline silicon solar cells are the leading products in the photovoltaic market, and conductive paste is the main auxiliary material for making crystalline silicon solar cells. Conductive paste is the largest material cost item on the cell except for silicon materials. This type of paste is mainly made of mixed rolling of metal powder, inorganic glass powder, organic carrier, etc., and its types include silver paste on the glossy surface and silver paste on the backlight surface. paste, back electric field aluminum paste, etc. [0003] At present, the research on the conductive paste of crystalline silicon solar cells has the following directions, 1. In the preparation of high-performance paste to improve the photoelectric conversion effici...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L31/0224H01L31/18H01L31/048
CPCH01L31/022425H01L31/048H01L31/18Y02E10/50Y02P70/50
Inventor 姜占锋谭伟华秦世嵘
Owner BYD CO LTD
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