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Low-viscosity flame-retardant polyurethane metal paint

A metal coating and polyurethane technology, applied in the direction of polyurea/polyurethane coatings, anti-corrosion coatings, fire-proof coatings, etc., can solve the problems of polyurethane flame retardancy, water resistance, heat resistance, low cost of use, low popularity, etc., to achieve Improved consistency and anti-thixotropy, uniform distribution, excellent strength effects

Inactive Publication Date: 2016-03-09
NINGGUO LONGSHI METAL PROD CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Stainless steel or carbon steel tanks or inner walls of pipes are often protected by composite materials, but the process is complicated, the cost is high, and the popularity is low. At present, it is more common to use suitable coatings on the inner wall surface Form a protective coating, which is simple and effective to implement, and the cost of use is low
At present, most coatings used on the inner wall of high-temperature storage tank pipes are polyurethane coatings, but the polyurethane coatings in the prior art are not ideal in terms of flame retardancy, water resistance, and heat resistance.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] A low-viscosity flame-retardant polyurethane metal coating proposed by the present invention, its raw materials include by weight: 80 parts of modified polyurethane, 9 parts of water-based silicone resin, 12 parts of water-based aldehyde and ketone resin, 25 parts of talcum powder, 3 parts of bentonite, 8 parts of kaolin, 8 parts of calcium carbonate, 14 parts of nano-magnesium hydroxide, 3 parts of preservative, 3 parts of defoamer, 2.5 parts of leveling agent, and 6 parts of pigment.

[0020] The preparation method of the modified polyurethane is as follows: by weight, 30 parts of polyadipate-1,4-butylene glycol ester diol and 30 parts of polytetrahydrofuran are heated to 80 ° C, kept for 4 hours, and then vacuum dehydrated to obtain the first material; After mixing the first material with 7 parts of N,N-bis(2-hydroxyethyl)aminomethylene phosphonic acid diethyl ester and 8 parts of modified polymerized 1,6-hexamethylene diisocyanate, the N 2 Protection, heat up to 83°...

Embodiment 2

[0023] A low-viscosity flame-retardant polyurethane metal coating proposed by the present invention, its raw materials include by weight: 85 parts of modified polyurethane, 6 parts of water-based silicone resin, 15 parts of water-based aldehyde-ketone resin, 22 parts of talcum powder, 6 parts of bentonite, 5 parts of kaolin, 12 parts of calcium carbonate, 10 parts of nano-magnesium hydroxide, 4 parts of preservative, 2 parts of defoamer, 4 parts of leveling agent, and 5 parts of pigment.

[0024] The preparation method of the modified polyurethane is as follows: by weight, 40 parts of polyadipate-1,4-butylene glycol ester diol and 20 parts of polytetrahydrofuran are heated to 90 ° C, kept for 3 hours, and then vacuum dehydrated to obtain the first material; After mixing the first material with 10 parts of N,N-bis(2-hydroxyethyl)aminomethylene phosphonic acid diethyl ester and 5 parts of modified polymerized 1,6-hexamethylene diisocyanate, the N 2 Protection, heat up to 86°C, k...

Embodiment 3

[0027] A low-viscosity flame-retardant polyurethane metal coating proposed by the present invention, its raw materials include by weight: 82 parts of modified polyurethane, 8 parts of water-based silicone resin, 13 parts of water-based aldehyde-ketone resin, 24 parts of talcum powder, 4 parts of bentonite, 7 parts of kaolin, 9 parts of calcium carbonate, 13 parts of nano-magnesium hydroxide, 3.3 parts of preservative, 2.8 parts of defoamer, 3 parts of leveling agent, and 5.8 parts of pigment.

[0028] The preparation method of modified polyurethane is as follows: by weight, 33 parts of polyadipate-1,4-butylene glycol ester diol and 26 parts of polytetrahydrofuran are heated to 82 ° C, kept for 3.4 hours, and then vacuum dehydrated to obtain the first material ; After mixing the first material with 8 parts of N,N-bis(2-hydroxyethyl)aminomethylene phosphonic acid diethyl ester and 7 parts of modified polymerization 1,6-hexamethylene diisocyanate, feed N 2 Protection, heat up to ...

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PUM

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Abstract

The invention discloses a low-viscosity flame-retardant polyurethane metal paint. The paint comprises the following raw materials in parts by weight: 80 to 85 parts of modified polyurethane, 6 to 9 parts of aqueous organic silicone resin, 12 to 15 parts of aqueous aldehyde-ketone resin, 22 to 25 parts of talcum powder, 3 to 6 parts of bentonite, 5 to 8 parts of kaolin, 8 to 12 parts of calcium carbonate, 10 to 14 parts of nano magnesium hydroxide, 3 to 4 parts of antiseptic, 2 to 3 parts of antifoaming agent, 2.5 to 4 parts of flatting agent, and 5 to 6 parts of pigment; wherein the modified polyurethane is prepared from the following components: polyhexanedioic acid-1,4-butanediol ester diol, polytetrahydrofuran, N,N-bis(2-hydroxyethyl)amino methylene diethyl phosphonate, modified polymerized 1,6-hexamethylene diisocyanate, 1,6-hexanediol, 1,4-butanediol-sodium sulfonate, epoxy resin, cobalt octoate, N-methyl diethanolamine, and diethanolamine, and modified polymerized 1,6-hexamethylene diisocyanate is prepared by the following steps: polymerizing 1,6-hexamethylene diisocyanate and then grafting hydroxyl siloxane to the polymerized 1,6-hexamethylene diisocyanate.

Description

technical field [0001] The invention relates to the technical field of polyurethane coatings, in particular to a low-viscosity flame-retardant polyurethane metal coating. Background technique [0002] Most of the large-scale high-temperature liquid storage tanks or pipelines in my country currently use metal pipes, such as carbon steel and stainless steel. Generally, linings are added to the inner walls of these tanks and pipes or paints are directly painted on the inner walls to improve the high temperature resistance and corrosion resistance of these equipment and prolong their service life. Stainless steel or carbon steel tanks or inner walls of pipes are often protected by composite materials, but the process is complicated, the cost is high, and the popularity is low. At present, it is more common to use suitable coatings on the inner wall surface Form a protective coating, this kind of measure is simple and effective to implement, and the cost of use is low. At prese...

Claims

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Application Information

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IPC IPC(8): C09D175/04C09D183/04C09D161/02C09D5/18C09D5/08C09D7/12C08G18/66C08G18/48C08G18/42
Inventor 周立
Owner NINGGUO LONGSHI METAL PROD CO LTD
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