Flocculation method for removing particulate matters in waste water
A technology for particulate matter and wastewater, applied in the direction of flocculation/sedimentation water/sewage treatment, etc., can solve the problems of slow adsorption time to saturation, small flocculation capacity, nano-particle pollution, etc., and achieve stable properties, high removal rate, and simple and effective methods. Effect
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Embodiment 1
[0014] Dissolve 100g of degummed silk in water, then add 10g of tetramethylammonium iodide, 30g of manganese acetate and 40g of cobalt nitrate, mix well, reflux for 8 hours, and then dry to obtain a silk film; then place the silk film at 190-200 After treatment at ℃ for 2 hours, freeze and pulverize to obtain silk fibroin powder; then disperse 10g silk fibroin powder in 50g ethanol, add 5g methyl orthosilicate, 0.3g 2-aminobutyric acid and 0.3g diethyl phosphite, Stir for 3 hours, then add 0.5g of silane coupling agent KH550, stir for 1 hour and then filter with suction to obtain a solid compound; add 10g of sodium acrylate and 7g of 2-acrylamido-2-methylpropanesulfonic acid into water, stir for 10 minutes, add 0.8g of bis(2,3-epoxycyclopentyl) ether was stirred for 15 minutes; then 3g of solid compound and 0.05g of azobisisobutyronitrile were added, reacted at 90°C for 4 hours, and finally dried to obtain a flocculant. Using an aqueous solution containing 6% montmorillonite (...
Embodiment 2
[0016] Dissolve 100g of degummed silk in water, then add 20g of tetramethylammonium iodide, 50g of manganese acetate and 60g of cobalt nitrate, mix well, reflux for 8 hours, and then dry to obtain a silk film; then place the silk film at 190-200 After treatment at ℃ for 2 hours, freeze and pulverize to obtain silk fibroin powder; then disperse 10g silk fibroin powder in 50g ethanol, add 5g methyl orthosilicate, 0.3g 2-aminobutyric acid and 0.3g diethyl phosphite, Stir for 3 hours, then add 0.5g of silane coupling agent KH550, stir for 1 hour and then filter with suction to obtain a solid compound; add 10g of sodium acrylate and 7g of 2-acrylamido-2-methylpropanesulfonic acid into water, stir for 10 minutes, add 0.8g of bis(2,3-epoxycyclopentyl) ether was stirred for 15 minutes; then 3g of solid compound and 0.05g of azobisisobutyronitrile were added, reacted at 90°C for 4 hours, and finally dried to obtain a flocculant. Using an aqueous solution containing 6% montmorillonite (...
Embodiment 3
[0018] Dissolve 100g of degummed silk in water, then add 10g of tetramethylammonium iodide, 30g of manganese acetate and 40g of cobalt nitrate, mix well, reflux for 8 hours, and then dry to obtain a silk film; then place the silk film at 190-200 After treatment at ℃ for 2 hours, freeze and pulverize to obtain silk fibroin powder; then disperse 10g silk fibroin powder in 50g ethanol, add 8g methyl orthosilicate, 0.5g 2-aminobutyric acid and 0.5g diethyl phosphite, Stir for 3 hours, then add 0.6g of silane coupling agent KH560, stir for 1 hour and then filter with suction to obtain a solid compound; add 10g of sodium acrylate and 7g of 2-acrylamido-2-methylpropanesulfonic acid into water, stir for 10 minutes, add 0.8g of bis(2,3-epoxycyclopentyl) ether was stirred for 15 minutes; then 3g of solid compound and 0.05g of azobisisobutyronitrile were added, reacted at 90°C for 4 hours, and finally dried to obtain a flocculant. Using an aqueous solution containing 6% montmorillonite (...
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