Reflecting and thermal-insulating coating for buildings and preparation method of reflecting and thermal-insulating coating
A technology of reflective heat-insulating coatings and heat-insulating fillers, applied in the field of coatings, can solve the problems of construction personnel and the surrounding environment, pollution of the environment, and large limitations. It achieves high reflectivity of visible light and near-infrared light, stable chemical properties, Avoid the effects of drastic changes
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Embodiment 1
[0024] The preparation method of modified hollow glass microspheres is:
[0025] Add hollow glass microspheres to water containing 2wt% sodium lauryl sulfate, then dropwise add 150g / L indium trichloride solution and 60g / L zirconium oxychloride alcohol aqueous solution, stir evenly, add ammonium bicarbonate, and ultrasonically disperse Precipitate after treatment, wash with water after precipitation, then heat up to 500°C at 20°C / h, keep warm for 50 minutes, then heat up to 900°C at 100°C / h, keep warm for 3 hours, and then you can get modified hollow glass microspheres . The solvent in the aqueous alcohol solution is 70% by volume of ethanol and 30% by volume of water.
[0026] Modified rutile titanium dioxide is prepared by the following method:
[0027] Add rutile titanium dioxide to acetone, then add titanate coupling agent and stir evenly, condense and reflux for 4 hours at a temperature of 60° C. to obtain a mixture, and filter, wash and dry the mixture to obtain modifie...
Embodiment 2
[0029] The preparation method of modified hollow glass microspheres is:
[0030] Add hollow glass microspheres to water containing 1wt% sodium stearate, then dropwise add 100g / L indium trichloride solution and 80g / L zirconium oxychloride alcohol aqueous solution, stir evenly, add ammonium bicarbonate, after ultrasonic dispersion treatment Precipitate, wash with water after precipitation, then raise the temperature at 30°C / h to 600°C, keep it warm for 30 minutes, then raise the temperature at 80°C / h to 800°C, keep it warm for 5 hours, and the modified hollow glass microspheres can be obtained. The solvent in the aqueous alcohol solution is 50% by volume of ethanol and 50% by volume of water.
[0031] Modified rutile titanium dioxide is prepared by the following method:
[0032] Add rutile titanium dioxide to acetone, then add titanate coupling agent and stir evenly, condense and reflux for 2 hours at a temperature of 80°C to obtain a mixture, filter, wash and dry the mixture t...
Embodiment 3
[0034] A building reflective heat-insulating coating, calculated in parts by weight, comprising the following components:
[0035] 80 parts of mixtures of acrylic acid emulsion and silica sol, 15 parts of modified rutile titanium dioxide of embodiment 1, 10 parts of modified hollow glass microspheres of embodiment 1, 2 parts of ammonium acrylate dispersant, 0.8 parts of tetrachloroisophthalonitrile 6 parts, 6 parts of modified ammonium polyacrylate, 2 parts of mineral oil, 9 parts of propylene glycol ethyl ether and 50 parts of deionized water.
[0036] Preparation:
[0037] 1) Add ammonium acrylate dispersant, tetrachloroisophthalonitrile, and 1 / 2 mineral oil into deionized water according to the formula amount, and stir and mix thoroughly at a speed of 300r / min;
[0038] 2) Add the modified rutile titanium dioxide of Example 1 and the modified hollow glass microspheres of Example 1 to the mixture of step 1) and disperse at a rotating speed of 1000r / min;
[0039] 3) Add the...
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