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Reflecting and thermal-insulating coating for buildings and preparation method of reflecting and thermal-insulating coating

A technology of reflective heat-insulating coatings and heat-insulating fillers, applied in the field of coatings, can solve the problems of construction personnel and the surrounding environment, pollution of the environment, and large limitations. It achieves high reflectivity of visible light and near-infrared light, stable chemical properties, Avoid the effects of drastic changes

Inactive Publication Date: 2017-11-07
合肥泓定科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although there are many studies on architectural reflective heat-insulating coatings, there are still many problems in practical applications, such as: unstable performance, although the reflective heat-insulating coatings reported in patent 200510028388. Single, mainly white or light-colored paint, with relatively large limitations, etc.
[0003] Architectural reflective heat-insulating coatings mainly include two types: solvent-based and water-soluble. The white heat-insulating coatings disclosed in Chinese patents with publication numbers CN103014 and CN1204677 are a kind of alkyd resin-based solvent-based reflective heat-insulating coatings. Low, only 3 to 5 years, and the volume used is mostly xylene, which pollutes the environment
Another Chinese patent whose publication number is CN102898905A uses fluororesin, fumed silica, hollow hollow glass microspheres and mixed organic solvents to prepare reflective heat-insulating coatings. Although this coating has high solar reflectance and hemispherical emissivity, its Most of the mixed solvents used are alcohols or esters, which will have a certain impact on the construction personnel and the surrounding environment
[0004] Therefore, the existing reflective and heat-insulating coatings for buildings restrict their application in the field of building energy conservation.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] The preparation method of modified hollow glass microspheres is:

[0025] Add hollow glass microspheres to water containing 2wt% sodium lauryl sulfate, then dropwise add 150g / L indium trichloride solution and 60g / L zirconium oxychloride alcohol aqueous solution, stir evenly, add ammonium bicarbonate, and ultrasonically disperse Precipitate after treatment, wash with water after precipitation, then heat up to 500°C at 20°C / h, keep warm for 50 minutes, then heat up to 900°C at 100°C / h, keep warm for 3 hours, and then you can get modified hollow glass microspheres . The solvent in the aqueous alcohol solution is 70% by volume of ethanol and 30% by volume of water.

[0026] Modified rutile titanium dioxide is prepared by the following method:

[0027] Add rutile titanium dioxide to acetone, then add titanate coupling agent and stir evenly, condense and reflux for 4 hours at a temperature of 60° C. to obtain a mixture, and filter, wash and dry the mixture to obtain modifie...

Embodiment 2

[0029] The preparation method of modified hollow glass microspheres is:

[0030] Add hollow glass microspheres to water containing 1wt% sodium stearate, then dropwise add 100g / L indium trichloride solution and 80g / L zirconium oxychloride alcohol aqueous solution, stir evenly, add ammonium bicarbonate, after ultrasonic dispersion treatment Precipitate, wash with water after precipitation, then raise the temperature at 30°C / h to 600°C, keep it warm for 30 minutes, then raise the temperature at 80°C / h to 800°C, keep it warm for 5 hours, and the modified hollow glass microspheres can be obtained. The solvent in the aqueous alcohol solution is 50% by volume of ethanol and 50% by volume of water.

[0031] Modified rutile titanium dioxide is prepared by the following method:

[0032] Add rutile titanium dioxide to acetone, then add titanate coupling agent and stir evenly, condense and reflux for 2 hours at a temperature of 80°C to obtain a mixture, filter, wash and dry the mixture t...

Embodiment 3

[0034] A building reflective heat-insulating coating, calculated in parts by weight, comprising the following components:

[0035] 80 parts of mixtures of acrylic acid emulsion and silica sol, 15 parts of modified rutile titanium dioxide of embodiment 1, 10 parts of modified hollow glass microspheres of embodiment 1, 2 parts of ammonium acrylate dispersant, 0.8 parts of tetrachloroisophthalonitrile 6 parts, 6 parts of modified ammonium polyacrylate, 2 parts of mineral oil, 9 parts of propylene glycol ethyl ether and 50 parts of deionized water.

[0036] Preparation:

[0037] 1) Add ammonium acrylate dispersant, tetrachloroisophthalonitrile, and 1 / 2 mineral oil into deionized water according to the formula amount, and stir and mix thoroughly at a speed of 300r / min;

[0038] 2) Add the modified rutile titanium dioxide of Example 1 and the modified hollow glass microspheres of Example 1 to the mixture of step 1) and disperse at a rotating speed of 1000r / min;

[0039] 3) Add the...

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Abstract

The invention discloses a reflecting and thermal-insulating coating for buildings and a preparation method of the reflecting and thermal-insulating coating. The reflecting and thermal-insulating coating contains the following components in parts by weight: 70-90 parts of a film forming substance, 10-20 parts of modified rutile type titanium dioxide, 5-15 parts of a thermal-insulating filling, 1-3 parts of a wetting dispersant, 0.5-1 part of a mildew preventive, 4-8 parts of a thickening agent, 1-3 parts of a defoaming agent, 6-12 parts of a film forming aid and 40-60 parts of deionized water, wherein the thermal-insulating filling is a modified hollow glass bead, and the modified hollow glass bead is mainly prepared from hollow glass beads, indium trichloride and zirconium oxychloride. The coating is relatively high in reflectivity and emissivity and low in heat conductivity coefficient, has a good thermal-insulating effect and can be applied to indoor thermal insulation.

Description

technical field [0001] The invention belongs to the technical field of coatings, and in particular relates to a building reflective heat-insulating coating and a preparation method thereof. Background technique [0002] Architectural reflective and heat-insulating coatings are new functional architectural coatings that have been used and paid attention to in recent years. In the hot summer and warm winter and hot summer and cold winter climate regions where the summer temperature is too high in our country, the coating not only has the decorative effect of ordinary exterior wall coatings, but also can reflect solar radiant heat to reduce the surface temperature of the coating film, and reduce the damage caused by summer coating. A series of problems caused by the high surface temperature of the membrane. Although there are many researches on architectural reflective heat-insulating coatings, there are still many problems in practical applications, such as: unstable performa...

Claims

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Application Information

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IPC IPC(8): C09D133/00C09D5/33C09D7/12
CPCC09D133/00C08K2003/2241C08L2201/08C08L2205/03C09D5/004C08L33/02C08K13/06C08K9/10C08K7/28C08K9/04C08K3/22C08K3/36
Inventor 汪琦汪泽维
Owner 合肥泓定科技有限公司
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