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A kind of preparation method of high slump polycarboxylate water reducer

A technology of water reducing agent and polycarboxylic acid, which is applied in the field of preparation of high slump-preserving polycarboxylic acid water reducing agent, can solve the problems of large investment in fixed assets, slow production efficiency, long production process, etc., and achieves staged hydrolysis and operation. Simple and fast response

Active Publication Date: 2019-12-24
KZJ NEW MATERIALS GROUP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] On the one hand, the current production process of polycarboxylate superplasticizers mostly adopts heating methods, such as steam heating, heat conduction oil heating, etc., which will cause environmental pollution
[0005] On the other hand, the current production process of polycarboxylate superplasticizers is relatively long, generally takes about 4 to 5 hours, and the production efficiency is slow, so it needs to be stocked in advance, and a certain amount of inventory needs to be occupied, resulting in waste of resources and large investment in fixed assets.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] (1) Add water and isopentenyl polyoxyethylene ether into the reactor, and then stir evenly under the protection of nitrogen.

[0021] (2) The reactor is irradiated under ultraviolet light, and then hydrogen peroxide is added at one time, and the first solution, the second solution and the third solution are added dropwise at a constant speed within 2-3h to carry out polymerization reaction. After the dropwise addition, 32% of The sodium hydroxide solution is neutralized to pH=6-7 to obtain a high-slump polycarboxylate superplasticizer. Wherein the first solution is an aqueous solution of 2,4,6-trimethylbenzoyl-diphenylphosphine oxide, and the second solution is maleic anhydride, carboxyl-terminated vinyl epoxy ether and diethyl vinyl phosphonate The mixed solution of body, the 3rd solution is the mixture of hydroxymethylsulfinic acid dihydrate, Mohr's salt, the white block (the mass ratio of the hydroxymethylsulfinic acid dihydrate, the Mohr's salt and the white block i...

Embodiment 2

[0023] (1) Add water and methallyl polyoxyethylene ether into the reactor, and then stir evenly under nitrogen protection.

[0024] (2) The reactor is irradiated under ultraviolet light, and then hydrogen peroxide is added at one time, and the first solution, the second solution and the third solution are added dropwise at a constant speed within 2-3h to carry out polymerization reaction. After the dropwise addition, 32% of The sodium hydroxide solution is neutralized to pH=6-7 to obtain a high-slump polycarboxylate superplasticizer. Wherein the first solution is an aqueous solution of Chivacure 1176, and the second solution is citric anhydride, carboxyl-terminated vinyl epoxy ether and 2-methyl-2-acrylic acid oxyphosphinate tris(oxyl-2,1-ethylene) The mixed liquid of ester monomer, the 3rd solution is the mixture of hydroxymethyl sulfinic acid dihydrate, Mohr's salt, the white block The ratio is 5:2:3) and 2-(phenylthioformylthio)propionic acid aqueous solution, the waveleng...

Embodiment 3

[0026] (1) Add water and allyl polyoxyethylene ether into the reactor, and then stir evenly under the protection of nitrogen.

[0027] (2) The reactor is irradiated under ultraviolet light, and then hydrogen peroxide is added at one time, and the first solution, the second solution and the third solution are added dropwise at a constant speed within 2-3h to carry out polymerization reaction. After the dropwise addition, 32% of The sodium hydroxide solution is neutralized to pH=6-7 to obtain a high-slump polycarboxylate superplasticizer. Wherein the first solution is an aqueous solution of 2-methyl-1-(4-methylthiophenyl)-2-morpholino-1-acetone, and the second solution is itaconic anhydride, carboxyl-terminated vinyl epoxy ether and The mixed solution of diethyl vinyl phosphonate monomer, the third solution is a mixture of hydroxymethylsulfinic acid dihydrate, Mohr's salt, and white block (hydroxymethylsulfinic acid dihydrate, Mohr's salt The mass ratio of hanging white block i...

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Abstract

The invention discloses a preparation method of a high slump retention polycarboxylate water reducer. Compared with the conventional solution polymerization method, the present invention adopts an initiation system combining a photoinitiator and a redox initiation system to increase the reaction rate, and has the advantages of fast reaction speed, high conversion rate, narrow molecular weight distribution, and low cost. It is easy to operate, easy to industrialized production, and has wide application prospects. The performance of the prepared polycarboxylate superplasticizer is stable, the molecular structure is a comb structure, the main chain contains polar groups, and the side chain contains polyoxyethylene-based segments to form a space barrier, which is conducive to improving the dispersion of cement and The ability to maintain dispersion reflects the advantages of high slump retention.

Description

technical field [0001] The invention belongs to the technical field of building admixtures, and in particular relates to a preparation method of a high-slump polycarboxylate water reducer. Background technique [0002] With the development of concrete in the direction of high performance and multifunctionality, concrete is required to have high workability, high strength, high durability, and can meet the application in many special cases. Superplasticizers with hyperdispersive properties have become one of the indispensable components in high performance concrete. [0003] In recent years, with the country's increasing emphasis on energy saving and emission reduction and the rapid promotion of the concept of low-carbon economy, scientific and technological workers are striving to improve the performance of concrete water reducing agents and also pay attention to how to reduce their energy consumption. In particular, enterprises are trying to find products with low energy c...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08F283/06C08F222/06C08F222/04C08F216/14C08F230/02C08F2/48C08F4/40C04B24/26C04B103/30
CPCC04B24/2694C08F2/48C08F4/40C08F283/065C04B2103/302C08F222/06C08F222/04C08F216/1416C08F230/02C08F2500/03
Inventor 柯余良方云辉陈小路桂苗苗林添兴
Owner KZJ NEW MATERIALS GROUP CO LTD
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