A kind of preparation method of high slump polycarboxylate water reducer
A technology of water reducing agent and polycarboxylic acid, which is applied in the field of preparation of high slump-preserving polycarboxylic acid water reducing agent, can solve the problems of large investment in fixed assets, slow production efficiency, long production process, etc., and achieves staged hydrolysis and operation. Simple and fast response
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Embodiment 1
[0020] (1) Add water and isopentenyl polyoxyethylene ether into the reactor, and then stir evenly under the protection of nitrogen.
[0021] (2) The reactor is irradiated under ultraviolet light, and then hydrogen peroxide is added at one time, and the first solution, the second solution and the third solution are added dropwise at a constant speed within 2-3h to carry out polymerization reaction. After the dropwise addition, 32% of The sodium hydroxide solution is neutralized to pH=6-7 to obtain a high-slump polycarboxylate superplasticizer. Wherein the first solution is an aqueous solution of 2,4,6-trimethylbenzoyl-diphenylphosphine oxide, and the second solution is maleic anhydride, carboxyl-terminated vinyl epoxy ether and diethyl vinyl phosphonate The mixed solution of body, the 3rd solution is the mixture of hydroxymethylsulfinic acid dihydrate, Mohr's salt, the white block (the mass ratio of the hydroxymethylsulfinic acid dihydrate, the Mohr's salt and the white block i...
Embodiment 2
[0023] (1) Add water and methallyl polyoxyethylene ether into the reactor, and then stir evenly under nitrogen protection.
[0024] (2) The reactor is irradiated under ultraviolet light, and then hydrogen peroxide is added at one time, and the first solution, the second solution and the third solution are added dropwise at a constant speed within 2-3h to carry out polymerization reaction. After the dropwise addition, 32% of The sodium hydroxide solution is neutralized to pH=6-7 to obtain a high-slump polycarboxylate superplasticizer. Wherein the first solution is an aqueous solution of Chivacure 1176, and the second solution is citric anhydride, carboxyl-terminated vinyl epoxy ether and 2-methyl-2-acrylic acid oxyphosphinate tris(oxyl-2,1-ethylene) The mixed liquid of ester monomer, the 3rd solution is the mixture of hydroxymethyl sulfinic acid dihydrate, Mohr's salt, the white block The ratio is 5:2:3) and 2-(phenylthioformylthio)propionic acid aqueous solution, the waveleng...
Embodiment 3
[0026] (1) Add water and allyl polyoxyethylene ether into the reactor, and then stir evenly under the protection of nitrogen.
[0027] (2) The reactor is irradiated under ultraviolet light, and then hydrogen peroxide is added at one time, and the first solution, the second solution and the third solution are added dropwise at a constant speed within 2-3h to carry out polymerization reaction. After the dropwise addition, 32% of The sodium hydroxide solution is neutralized to pH=6-7 to obtain a high-slump polycarboxylate superplasticizer. Wherein the first solution is an aqueous solution of 2-methyl-1-(4-methylthiophenyl)-2-morpholino-1-acetone, and the second solution is itaconic anhydride, carboxyl-terminated vinyl epoxy ether and The mixed solution of diethyl vinyl phosphonate monomer, the third solution is a mixture of hydroxymethylsulfinic acid dihydrate, Mohr's salt, and white block (hydroxymethylsulfinic acid dihydrate, Mohr's salt The mass ratio of hanging white block i...
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Abstract
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