Processing technology of deep sea fish oil in high EPA (Eicosapentaenoic Acid) DHA (Docosahexaenoic Acid) contents

A technology of deep-sea fish oil and processing technology, which is applied in the field of oil processing, can solve the problems of DHA content reduction, small product separation scale, and long reaction time, so as to prevent and reduce the possibility of oxidation, simplify the decolorization and deodorization process, and shorten the heating time. Effect

Pending Publication Date: 2019-02-22
福建高龙海洋生物工程有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, fish oil is easily oxidized during processing, and DHA is easily damaged, which greatly reduces the content of DHA in fish oil products. To play the function of DHA, it is necessary to further concentrate the DHA and EPA in fish oil
[0003] But the polyene fatty acid in deep-sea fish oil, including DHA, is a thermally and chemically unstable substance, and it is extremely difficult to separate and purify it. At present, the separation and purification techniques for DHA mainly contain the following: 1. Urea inclusion method, mainly using Urea molecules can form stable crystal clathrates with straight-chain saturated fatty acids or monounsaturated fatty acids during the crystallization process, thereby obtaining high-purity DHA products. The disadvantages are long reaction time, low product yield, and serious urea residues; 2 , low-temperature solvent crystallization method, mainly using the different solubility of different fatty acids (salts) in organic solvents at low temperature to separate and purify
Its disadvantage is that it needs long reaction time, recycles a large amount of organic solvent, and the separation efficiency is not high; 3. Lipase concentration method, which selectively hydrolyzes triglycerides containing DHA/EPA, and finally enriches polyvalent unsaturated fatty acid triglycerides , its shortcoming is that the reaction time is long, and enrichment DHA a

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0030] Example one:

[0031] A processing technology of deep-sea fish oil with high EPA and DHA content includes the following steps:

[0032] Step 1. Pump the crude fish oil into the pretreatment tank, turn on the stirrer, and the stirring speed is 200 revolutions per hour; turn on the steam to heat up, and when the temperature reaches 70°C, spray 15% aqueous sodium hydroxide solution by mass to maintain the stirring speed 200-300r / h and temperature 70℃-80℃, stirring time is 0.25-0.5h; after stirring, the temperature drops to 40-60℃, sedimentation is 5-8 hours, and the lower impurity components are separated and removed; the crude fish oil and The mass ratio of the sodium hydroxide aqueous solution with a mass concentration of 15%-25% is 1:35.

[0033] Step 2. The fish oil pretreated in step 1 is mixed with citric acid at a mass ratio of 100:0.01, and the mixture is evenly distributed from the top of the packed tower by a distributor to each part of the packing in the tower; The b...

Example Embodiment

[0038] Embodiment two:

[0039] A processing technology of deep-sea fish oil with high EPA and DHA content includes the following steps:

[0040] Step 1. Pump the crude fish oil into the pretreatment tank, turn on the stirrer, and the stirring speed is 250 rpm; turn on the steam to heat up, and when the temperature reaches 75 ℃, spray 20% mass concentration of sodium hydroxide aqueous solution to maintain the stirring speed The temperature is 250r / h and the temperature is 75°C, and the stirring time is 0.35h; after the stirring, the temperature drops to 50°C, sedimentation is 7 hours, and the lower impurity components are separated and removed; the mass ratio of the crude fish oil to the sodium hydroxide solution is 1:40 .

[0041] Step 2. The fish oil and citric acid pretreated in step 1 are mixed at a mass ratio of 100:0.015, and the mixture is evenly distributed from the top of the packed tower by a distributor to each part of the packing in the tower; The bottom of the packed t...

Example Embodiment

[0046] Embodiment three:

[0047] A processing technology of deep-sea fish oil with high EPA and DHA content includes the following steps:

[0048] Step 1. Pump the crude fish oil into the pretreatment tank, turn on the stirrer, and the stirring speed is 300 rpm; turn on the steam to increase the temperature, and when the temperature reaches 80°C, spray into the 25% mass concentration sodium hydroxide aqueous solution and keep the stirring speed The temperature is 200r / h and the temperature is 70°C, and the stirring time is 0.25h; after the stirring, the temperature drops to 40°C, sedimentation is 5 hours, and the lower impurity components are separated and removed; the mass ratio of the crude fish oil to the sodium hydroxide solution is 1:55 .

[0049] Step 2. The fish oil and citric acid pretreated in step 1 are mixed at a mass ratio of 100:0.02, and the mixture is evenly distributed from the top of the packed tower by a distributor to each part of the packing in the tower; The b...

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PUM

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Abstract

The invention discloses a processing technology of deep sea fish oil in high EPA (Eicosapentaenoic Acid) DHA (Docosahexaenoic Acid) contents. The deep sea fish oil is subjected to the technologies such as fish oil pretreatment, decoloration and deodorization, fractionation and winterization. According to the processing technology disclosed by the invention, decoloration and deodorization are combined together, heating time is shortened while refining of oil is carried out at a lower temperature, DHA and EPA in the fish oil can be effectively prevented from being decomposed during a deodorization and decoloration process due to too high temperature, the probability of oxidation is reduced, meanwhile, generation of pollutants such as trans-fatty acid can be controlled, and the DHA and EPA contents of products can be increased; meanwhile, the DHA and EPA contents in the fish oil can be further increased through refining and an improved secondary winterization process, the DHA and EPA contents in the fish oil which is finally obtained through a method are three times or above higher than those of common fish oil, and the fish oil can be directly applied to healthcare products and babyfood.

Description

technical field [0001] The invention relates to a processing technology of deep-sea fish oil with high EPA and DHA content, and belongs to the technical field of oil processing. Background technique [0002] Fish oil is a general term for all oils in fish, including body oil, liver oil and brain oil. The main fish oil is a kind of oil extracted from fatty fish, rich in omega-3 polyunsaturated fatty acids (DHA and EPA ), has health benefits such as anti-inflammatory and blood lipid regulation. DHA is of great significance to the development of the brain, the beginning of the development of the neural tube in the brain, the myelination of brain nerve cells, the development of brain cells that control information transmission, the extension and expansion of neurons, and the gradual formation of neurotransmitters. Fish oil rich in DHA is deeply Consumers love it. However, fish oil is easily oxidized during processing, and DHA is easily damaged, which greatly reduces the conten...

Claims

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Application Information

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IPC IPC(8): C11C3/00
CPCC11C3/00
Inventor 陈晓军邵东平
Owner 福建高龙海洋生物工程有限公司
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