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Preparation method of graphene/basalt heat conduction metal corrosion-resistant coating material

A technology of metal corrosion and basalt, applied in the field of coatings, can solve the problems of accelerated thermal aging and decomposition of coatings, corrosion of ship salt solution, poor heat dissipation of ship hulls, etc., to prevent corrosion, prevent electrochemical corrosion, and stabilize the total amount of negative charges Effect

Inactive Publication Date: 2019-08-30
吴波
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the above patented technical scheme, the paint coating can prevent oxygen and water from entering the paint to achieve the purpose of imitating electrochemical corrosion, but a large number of chloride ions with smaller particle sizes in seawater will penetrate into the substrate from the tiny gaps between the paint layers, thereby damaging Ships cause salt solution corrosion. In addition, the coating on the hull will cause the heat dissipation of the hull to deteriorate, resulting in excessive local temperature of the hull, which will accelerate the thermal aging and decomposition of the coating.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] The preparation method of graphene / basalt heat conduction anti-metal corrosion coating comprises the following steps:

[0027] 1) Add 50g of bisphenol A epoxy resin E44 and 12g of graphene / basalt composite powder into 280mL of acetone aqueous solution with a mass concentration of 50%, stir at 350r / min for 1.5h, add 3g of nano-titanium dioxide and 0.2g of amphetamine Triethoxysilane and continue to stir for 50 minutes, add 0.5g of defoamer polydimethylsiloxane and 1g of emulsifier OP-10 and continue to stir until the slurry is completely dispersed and uniform to obtain A component;

[0028] Wherein, the preparation method of graphene / basalt composite powder comprises the following steps:

[0029] Dissolve 3g of sodium alginate in 120mL of deionized water to obtain a sodium alginate solution; add 8g of basalt scales to 250mL of absolute ethanol, stir on a magnetic stirrer at 200r / min for 10min, and then disperse with ultrasonic vibration for 8min to obtain a dispersion. ...

Embodiment 2

[0033] The preparation method of graphene / basalt heat conduction anti-metal corrosion coating comprises the following steps:

[0034] 1) Add 50g of bisphenol A epoxy resin E06 and 15g of graphene / basalt composite powder into 300mL of acetone aqueous solution with a mass concentration of 50%, stir at 400r / min for 1h, add 5g of nano-titanium dioxide and 0.3g of aminopropyl Triethoxysilane and continue to stir for 60 minutes, add 1g of antifoaming agent polydimethylsiloxane and 1.5g of emulsifier OP-10 and continue stirring until the slurry is completely dispersed and uniform to obtain A component;

[0035] Wherein, the preparation method of graphene / basalt composite powder comprises the following steps:

[0036] Dissolve 5g of sodium alginate in 150mL of deionized water to obtain a sodium alginate solution; add 10g of basalt scales to 300mL of absolute ethanol, stir on a magnetic stirrer at 200r / min for 10min, and disperse with ultrasonic vibration to obtain a dispersion. g epo...

Embodiment 3

[0040] The preparation method of graphene / basalt heat conduction anti-metal corrosion coating comprises the following steps:

[0041] 1) Add 50g of bisphenol A epoxy resin bisphenol A epoxy resin E03, 10g of graphene / basalt composite powder into 250mL of acetone aqueous solution with a mass concentration of 50%, stir at 300r / min for 2h, add 2.5g of nanometer titanium dioxide and 0.1g of aminopropyltriethoxysilane and continue to stir for 30min, add 0.5g of antifoaming agent polydimethylsiloxane and 0.5g of emulsifier OP-10 and continue to stir until the slurry is completely dispersed and uniform to obtain A component ;

[0042] Wherein, the preparation method of graphene / basalt composite powder comprises the following steps:

[0043] Dissolve 2g of sodium alginate in 100mL of deionized water to obtain a sodium alginate solution; add 5g of basalt flakes into 200mL of absolute ethanol, stir on a magnetic stirrer at 150r / min for 20min, and disperse with ultrasonic vibration to o...

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PUM

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Abstract

The invention relates to the technical field of coating materials, and discloses a preparation method of a graphene / basalt heat conduction metal corrosion-resistant coating material. The preparation method comprises the following steps: 1) adding bisphenol A epoxy resin and graphene / basalt composite powder into an acetone aqueous solution, stirring, adding nano titanium dioxide and a silane coupling agent, continuously stirring, adding an antifoaming agent and an emulsifier, and continuously stirring until slurry is completely dispersed, thus obtaining a component A; 2) adding a curing agent and an ultraviolet absorber to ethyl acetate, stirring and uniformly mixing to obtain a component B; 3) mixing the component A and the component B, and uniformly stirring to obtain the graphene / basaltheat conduction corrosion-resistant coating material. The coating material prepared by the method not only can effectively resist the corrosion of chloride ions in seawater to a metal matrix of a hull, but also has better heat conduction and dissipation effects, and avoids adverse effects on the hull per se and a coating.

Description

technical field [0001] The invention relates to the technical field of coatings, in particular to a preparation method of a graphene / basalt heat-conducting anti-metal corrosion coating. Background technique [0002] Seawater is an electrolyte solution containing a variety of salts. The main salt is 3-3.5% sodium chloride. The radius of chloride ions is small, and the diffusion is difficult to be hindered. When it moves to the metal surface, it can be adsorbed on the metal surface. Chlorine The ions themselves have certain complexation properties. After being adsorbed on the surface of iron, due to their high activity, they can react with the passivation film or iron on the microscopic level. When there is a defect in the passivation film, there will be fresh At this time, the metal part is a large primary battery, and the exposed metal part of the gap becomes an activated anode area, while the other unexposed area is a large cathode area, thus forming a so-called large catho...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D163/00C09D5/08C09D7/61
CPCC09D5/08C09D7/61C09D163/00C08K13/06C08K9/10C08K3/042C08K3/34C08K3/36
Inventor 吴波王建忠
Owner 吴波
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