Moisture-curing liquid waterproofing composition for free-smashing bricks suitable for joint pretreatment and repair

A pretreatment, moisture curing technology, applied in the field of materials, can solve the problems of poor durability, curing, incomplete curing, etc., and achieve the effects of excellent bonding compatibility, good water resistance, and extended durability

Active Publication Date: 2022-02-15
SHANGHAI NIUYUAN IND TRADE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

If the coating is damaged, there is no self-repair function, and the film is formed by volatilization of water, and the construction is greatly affected by the ambient temperature and humidity;
[0007] (3) Inorganic repair fluids mainly rely on sodium silicate and other solutions or sols to form precipitations with calcium ions and magnesium ions in the waterproof base material and then adsorb on the surface or gaps, but there are slow water-stop penetration and penetration Defects of small depth, poor water resistance, and poor durability;
[0008] (4) The non-shattering brick waterproof liquid of the reactive system is mainly based on two-component amine-cured epoxy, two-component polyurethane, two-component polyurea, etc. On the one hand, this kind of non-reactive brick waterproofing is more reliable than non-reactive waterproofing, but this kind of two-component product needs to be diluted with a solvent to reduce the viscosity before it can penetrate, and the mixing operation of the two components is more troublesome, and it is easy to mix the ratio, resulting in Curing too fast, small penetration depth or incomplete curing or even impossible curing
[0009] After the above types of smashing-free brick waterproofing system are constructed, the construction of the beautifying agent will often cause problems of curing and bonding, which will cause the problem of cracking and degumming of the beautifying agent in the later use process.

Method used

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  • Moisture-curing liquid waterproofing composition for free-smashing bricks suitable for joint pretreatment and repair
  • Moisture-curing liquid waterproofing composition for free-smashing bricks suitable for joint pretreatment and repair
  • Moisture-curing liquid waterproofing composition for free-smashing bricks suitable for joint pretreatment and repair

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0152] Example 1: Self-made alkoxy-silicon-modified polymer A1 with a chain segment formed from the condensation reaction of epichlorohydrin with active hydrogen-containing compounds such as alcohols, phenols, acids or amines as the main chain

[0153]In this example, self-made alkoxy-silicon modified polymer A1, which is formed by the condensation reaction of epichlorohydrin with active hydrogen-containing compounds such as alcohols, phenols, acids, or amines, is the main chain: The aminoalkoxysilane of the group carries out ring-opening reaction with the above-mentioned epoxy resin to bind the alkoxysilane to the epoxy resin, and the epoxy resin selects bisphenol A glycidyl ether type epoxy resin E51 (NPEL-128 ), alkoxysilanes containing active hydrogen groups are selected (C 6 h 5 )NH-(CH2)3-Si(OCH 3 ) 3 , that is, the secondary aminosiloxane of γ-anilinopropyl trimethoxysilane, according to the equimolar ratio of -CH(O)CH2 and NH, react to obtain viscous epichlorohydrin...

Embodiment 2

[0155] Example 2: Self-made alkoxy silicon-modified polymer A1 with a chain segment formed from the condensation reaction of epichlorohydrin with active hydrogen-containing compounds such as alcohols, phenols, acids or amines as the main chain

[0156] (1) Equipped with a dropping funnel (connected to vacuum during distillation), reflux water condenser (connected to N during atmosphere protection) 2 ), a stirrer and a thermometer in a four-necked flask; polytetramethylene ether glycol (PTMEG 2000, molecular weight 2000, a primary hydroxyl-terminated homopolymer obtained by monomer tetrahydrofuran ring-opening polymerization), optional Select commercially available BASF products 2000 as a raw material, first remove water under reduced pressure at 110 °C, and 2 Cool to room temperature under protection for use. In a four-necked flask, react with IPDI (commercially available) for 3 hours under nitrogen protection at 70-80°C, and prepare isocyanate-blocked Terminated polytetram...

Embodiment 3

[0159] Example 3: Self-made alkoxy silicon-modified polymer A1 with a chain segment formed by the condensation reaction of epichlorohydrin with an active hydrogen-containing compound such as alcohol, phenol, acid or amine as the main chain

[0160] The alkoxysilane is bonded to the epoxy resin through the ring-opening reaction between the mercaptoalkoxysilane with active hydrogen groups and the above epoxy resin. The epoxy resin is bisphenol A glycidyl ether type epoxy resin E51 (NPEL-128), the alkoxysilane containing active hydrogen group selects HS-(CH2)3-Si(OCH 3 ) 3 , that is, KH-590, which is formed by the condensation reaction of epichlorohydrin with active hydrogen-containing compounds such as alcohols, phenols, acids or amines, according to the equimolar ratio of -CH(O)CH2 and SH. The segment of the main chain is an alkoxy silicon modified polymer A1.

[0161] The specific preparation method is as follows: 1.0kg epoxy resin E51 (NPEL-128) is added to a four-necked fl...

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Abstract

The invention discloses a non-shattering brick moisture-curing liquid waterproof composition (C) suitable for pretreatment and repair of beautiful joints, which comprises: an alkoxysilyl group having a structure of formula (I) composed of different chain segments Modified polymer (A), catalyst (C1) selected from metal-containing catalysts, guanidine and imidium, and a combination of catalysts (C2) comprising units of formula (II), active diluent (D) having a structure of formula (III): P 1 -{L 1 ‑[C(=O)‑L 2 ] z -(CR 1 2 ) a ‑Si(OR 2 ) b R 3 (3‑b)} c (I); B f Si(OR 4 ) d R 5 e o (4‑f‑d‑e) / 2 (II); R 8 ‑[Si(OR 6 ) g R 7 (3‑g) ] h (III). Wherein, the alkoxy silicon-based modified polymer (A) contains A1 and A2, and the sum of A2 and A1 is not less than 50 parts by mass. The moisture-curing liquid waterproof composition (C) has excellent adhesive compatibility with the two-component epoxy resin beauty joint agent, and can have a good repair effect on the cracking and peeling of the base surface after the application of the beauty joint agent .

Description

technical field [0001] The invention relates to a brick-shatter-free moisture-curing liquid waterproof composition which can be used for pretreatment and repair of beautiful joints, in particular to a moisture-curing composition based on a siloxane modified polymer; it belongs to the field of material technology. Background technique [0002] For housing construction, waterproofing is one of the most basic requirements. With the continuous improvement of living standards, people have higher and higher requirements for kitchen and bathroom functions, design standards and aesthetics. Usually, the floors of kitchens and bathrooms of newly built houses should be waterproofed according to certain requirements, and the seams of tiles should be beautifully seamed. If the waterproof layer is intact, there will be no leakage after decoration. However, due to unprofessional waterproofing or the poor quality of waterproof materials and seam sealants used during house decoration, or th...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G77/04
CPCC09J163/00C09J183/04C08L2205/035C08L2205/025C08L75/14C08L75/04C08L63/00C08L75/08C08L47/00
Inventor 娄从江
Owner SHANGHAI NIUYUAN IND TRADE
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