Nuclide decontaminating solution as well as preparation method and application thereof

A decontamination solution and nuclide technology, which is applied in the field of decontamination solution, can solve the problems of reduced solubility, reduced fluidity of decontamination agent, limited solubility, etc., to achieve improved decontamination efficiency, improved chelation efficiency, and improved chelation Effect

Active Publication Date: 2020-11-03
湖南福嘉环境安全科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, EDTA-Na 2 , carboxymethyl chitosan and sodium alginate have limited solubility in water, solids will precipitate at low temperatures, and the environmental adaptability is poor
Moreover, when sodium alginate and carboxymethyl chitosan are used together, it will affect their respective solubility, reduce the solubility of both at the same time, increase the viscosity of the solution, reduce the fluidity of the decontaminant, and make it difficult to wash the wound. large amount of radioactive residue
Moreover, the decontaminant contains a large amount of polysaccharides, and is in a neutral environment, so it is not easy to store for a long time, and it is easy to deteriorate
[0006] Chinese patent application CN110483694A discloses a novel hydrogel for radionuclide contamination and decontamination, its preparation method and application. The novel hydrogel comprises the following components in terms of mass percentage: 15.07%-48.65% acrylamide, 0.14 %-0.47% sodium alginate, 0.04%-0.12% diethyltriaminepentaacetic acid calcium sodium salt, 0.03%-0.11% ammonium persulfate and 50%-85% water; The pure physical interaction between molecular segments and between macromolecules and small molecules cross-links into a three-dimensional network structure. The content of sodium alginate, diethyltriaminepentaacetic acid calcium sodium salt and ammonium persulfate is too small to form a chemical structure. The above chelation adsorption is purely physical filtration, so the decontamination effect is poor
Moreover, this patent application needs to make polymer components into hydrogels, and the preparation process of the products is complicated, mainly relying on the three-dimensional network structure and adhesion effect of acrylamide hydrogels to adsorb radionuclides, because the viscosity of hydrogels is relatively high. High, so it is impossible to enter the gaps with small spacing for the adsorption of radionuclides, and the adsorbed hydrogel cannot be eluted from the gaps smoothly, resulting in low overall decontamination efficiency, application range and environmental adaptability Need to be improved, and the storage time is short

Method used

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  • Nuclide decontaminating solution as well as preparation method and application thereof
  • Nuclide decontaminating solution as well as preparation method and application thereof
  • Nuclide decontaminating solution as well as preparation method and application thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0054] A nuclide decontamination solution, consisting of the following components in weight percent: 0.3% pentasodium diethylenetriaminepentaacetic acid, 0.1% auxiliary chelating agent, 0.1% sodium silicate, 0.1% adsorbent, and 1% surfactant , potassium sorbate 0.1%, X-278 water-based silicone defoamer (purchased from Yantai Hengxin Chemical Technology Co., Ltd.) 0.1%, tartaric acid 0.1%, sodium borate 0.1%, water balance.

[0055] The auxiliary chelating agent is a mixture of sodium gluconate, disodium edetate and hydroxyethylene diphosphonic acid, and the mass ratio of the three is 3:1:1;

[0056] The adsorbent is a mixture of chitosan and sodium alginate, and the mass ratio of the two is 0.5:1;

[0057] The surfactant is a mixture of alkyl glucoside and polyoxyethylene octylphenol ether, and the mass ratio of the two is 1:1.

[0058] The preparation method of nuclide decontamination solution is as follows:

[0059] (1) Mix diethylenetriaminepentaacetic acid pentasodium,...

Embodiment 2

[0063] A nuclide decontamination solution, consisting of the following components in percentage by weight: 6% of pentasodium diethylenetriaminepentaacetic acid, 5% of auxiliary chelating agent, 2% of disodium hydrogen phosphate, 2% of adsorbent, and 10% of surfactant %, sodium benzoate 1%, X-278 water-based silicone defoamer 1%, sodium carbonate 1%, urea 2%, water balance.

[0064] The auxiliary chelating agent is a mixture of sodium gluconate, disodium edetate and hydroxyethylene diphosphonic acid, and the mass ratio is 5:3:1;

[0065] Described adsorbent is the mixture of chitosan and sodium alginate, and mass ratio is 2:1;

[0066] The surfactant is a mixture of alkyl glucoside and polyoxyethylene octylphenol ether with a mass ratio of 3:1.

[0067] The preparation method of nuclide decontamination solution is as follows:

[0068] (1) Mix pentasodium diethylenetriaminepentaacetic acid and auxiliary chelating agent with 50% water of formula quantity, dissolve until trans...

Embodiment 3

[0072] A nuclide decontamination solution, consisting of the following components in weight percent: 3% pentasodium diethylenetriaminepentaacetic acid, 2.5% auxiliary chelating agent, 2% sodium citrate, 1% adsorbent, and 5% surfactant , potassium sorbate 0.5%, X-278 water-based silicone defoamer 1%, citric acid 1%, sodium borate 1%, water balance.

[0073] The auxiliary chelating agent is a mixture of sodium gluconate, disodium edetate and hydroxyethylene diphosphonic acid, and the mass ratio of the three is 4:2:1;

[0074] The adsorbent is a mixture of chitosan and sodium alginate, and the mass ratio of the two is 1:1;

[0075] The surfactant is a mixture of alkyl glucoside and polyoxyethylene octylphenol ether, and the mass ratio of the two is 2:1.

[0076] The preparation method of nuclide decontamination solution is as follows:

[0077] (1) Mix pentasodium diethylenetriaminepentaacetic acid, auxiliary chelating agent and 40% water of formula quantity, dissolve until tr...

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Abstract

The invention relates to the technical field of decontaminating solutions, in particular to a nuclide decontaminating solution as well as a preparation method and application thereof. The nuclide decontaminating solution consists of the following components in percentage by weight: 0.3-6% of pentasodium diethylenetriamine pentaacetate, 0.1-5% of an auxiliary chelating agent, 0.1-2% of a buffer agent, 0.1-2% of an adsorbent, 1-10% of a surfactant, 0.1-1% of a preservative, 0.1-1% of a defoaming agent, 0.1-1% of an acid-base regulator, 0.1-2% of a stabilizer and the balance of water. The methodhas the advantages of being high in decontamination efficiency, wide in application range, high in environmental adaptability and long in storage time.

Description

technical field [0001] The invention relates to the technical field of decontamination liquid, in particular to a nuclide decontamination liquid and its preparation method and application. Background technique [0002] Radioactive pollution refers to the occurrence of radioactive substances or rays that exceed national standards on the surface or inside of materials, human bodies, and environmental media in places due to human activities. With the rapid development of science and technology and economy, nuclear energy is widely used in energy, military, medical, testing and other fields. When people are engaged in various nuclear-related practical activities, wounds such as cuts, stab wounds, explosion injuries, and burns may occur. Various body surface wounds are in a radioactively polluted environment, and wounds may be contaminated by radioactive substances. After the radioactive material enters the human body through the wound, it will transfer to tissues such as blood,...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A61K31/198A61K31/191A61K31/722A61K31/715A61K31/663A61P17/02A61P39/02A01N25/00A01N25/30A01N37/44A01N37/36A01N43/16A01N57/20A01P3/00A01P1/00A61K8/44A61K8/365A61K8/55A61K8/73A61Q19/10
CPCA01N25/00A01N25/30A01N37/36A01N37/44A01N43/16A01N57/20A61K8/365A61K8/44A61K8/55A61K8/733A61K8/736A61K31/191A61K31/198A61K31/663A61K31/715A61K31/722A61K2800/5922A61Q19/10A61P17/02A61P39/02A61K2300/00
Inventor 曹乐根王毅清
Owner 湖南福嘉环境安全科技有限公司
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