Method of producing glass substrate for information recording medium
A glass substrate, information recording technology, applied in the manufacture of optical record carriers, optical record carriers, and record carriers, etc., can solve the problems of deterioration, inability to perform high-density recording, and inability to adapt to the high conspiracy of magnetic recording.
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Embodiment 1~45
[0092] First, in order to obtain glasses with the oxide compositions shown in Tables 1 to 8, various glass raw materials were weighed according to the proportions shown in each table, and about 100 Kg of the mixture was prepared in each example. The said glass Raw materials include: silica powder, aluminum hydroxide, aluminum oxide, lithium carbonate, lithium sulfate, sodium carbonate, sodium nitrate, calcium carbonate, magnesium carbonate, magnesium oxide, titanium oxide, iron oxide, nickel oxide, yttrium oxide, lanthanum oxide , neodymium oxide, copper oxide, antimony oxide, arsenous acid, etc.
[0093] It should be noted that although the compositions listed in the following tables are the composition of the glass itself, if the values after the decimal point are ignored, these values are roughly the same as the amount of the glass raw material oxide used ( The same applies to the other embodiments).
[0094] Then, a platinum-made atmosphere is used to heat batch-type ...
Embodiment 46
[0125] The chemically strengthened glass substrate (2.5-inch disk) obtained in Example 1 was immersed in molten salt of potassium pyrosulfate (300° C.) for 5 minutes to prevent alkali metal components (Li, Na, K) from Treatment of dissolution in glass substrates. The glass substrate treated to prevent the elution of alkali metal ions was immersed in ultrapure water at 80°C for 24 hours to evaluate by ion chromatography. The results showed that the alkali metal components (Li, Na, K) dissolved in water The amount is 0.1-0.3 μmol / tablet. On the other hand, when the alkali metal elution prevention treatment is not performed, the elution amount of the above-mentioned alkali metal component is 15 to 20 μmol / tablet.
[0126] In addition, as the treatment for preventing the elution of alkali metals, hydrogensulfate or a mixed salt of the two may be used in addition to the above-mentioned molten salt of pyrosulfate. Also, other than molten salts, heated concentrated sulfuric acid, h...
Embodiment 47~94
[0128] In Tables 10-13, the glass composition of Examples 47-94 is shown by mol% value. These can be used as a starting material when melting glass, SiO 2 、Al 2 o 3 , Al(OH) 3 , MgO, Mg(OH) 2 , CaCO 3 , SrCO 3 , Sr(NO 3 ) 2 、BaCO 3 、TiO 2 , ZrO 2 , Li 2 CO 3 、Na 2 CO 3 , Y 2 o 3 and La 2 o 3 and other rare earth metal oxides, etc., weigh these metal oxides according to the proportions shown in Tables 10 to 13, and weigh 250 to 800g, and mix them thoroughly to obtain a mixed batch of materials, which are added to the platinum crucible , at a temperature of 1400-1500°C and in air for 3-6 hours to melt these glass components. After melting, inject the glass melt into a carbonaceous material with a size of 180×15×25mm or φ100×5mm. Put it in the mold, let it cool, put it into the annealing furnace immediately when it is cooled to the glass transition point, make it anneal in the range of the glass transition temperature for about 1 hour in the furnace, then let i...
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