Method of producing glass substrate for information recording medium

A glass substrate, information recording technology, applied in the manufacture of optical record carriers, optical record carriers, and record carriers, etc., can solve the problems of deterioration, inability to perform high-density recording, and inability to adapt to the high conspiracy of magnetic recording.

Inactive Publication Date: 2000-01-12
HOYA CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] However, for those chemically strengthened glass substrates disclosed in documents such as the above-mentioned JP-A-1-239036, the Young's modulus is about 80 GPa, which may be difficult to meet the strict requirements for hard disks in the future.
For those glasses that are chemically strengthened by conventional ion exchange methods, since they contain a large amount of alkali metal components, when used for a long time in a high temperature and humid environment, alkali metal ions will be released from the pinhole part of the magnetic film or The weak part of the magnetic film such as the peripheral part of the magnetic film or the part where the glass is exposed is precipitated, which causes corrosion or deterioration of the magnetic film, which is its disadvantage
[0011] In addition, for the crystallized glass disclosed in US Pat. No. 5,391,522 specification, although Young's modulus and heat resistance are slightly superior to the above-mentioned chemically strengthened glass substrates, the roughness is lower than that of chemically strengthened glass substrates. The substrate is poor, and the reduction of the flying height of the magnetic head is limited, so it cannot meet the requirements of high-level magnetic recording, which is its problem
[0012] In addition, when seeking high-speed rotation of a magnetic disk made of a conventional information recording medium glass substrate in order to achieve high-speed data, it is difficult to ensure the stability of the flying height (the distance between the magnetic head and the magnetic disk during playback recording).
[0013] On the other hand, the magnetic recording medium made of glassy carbon disclosed in Japanese Patent Laid-Open No. 3-273525 is superior to the above-mentioned chemically strengthened glass substrate or crystal in terms of heat resistance and light weight. glass substrate, but its surface has too many defects to allow high-density recording
In addition, since the Young's modulus of glassy carbon is very small, and its strength is also poor, it is necessary to increase the thickness of the substrate, and it is difficult to achieve thinning of the substrate, which is its problem.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~45

[0092] First, in order to obtain glasses with the oxide compositions shown in Tables 1 to 8, various glass raw materials were weighed according to the proportions shown in each table, and about 100 Kg of the mixture was prepared in each example. The said glass Raw materials include: silica powder, aluminum hydroxide, aluminum oxide, lithium carbonate, lithium sulfate, sodium carbonate, sodium nitrate, calcium carbonate, magnesium carbonate, magnesium oxide, titanium oxide, iron oxide, nickel oxide, yttrium oxide, lanthanum oxide , neodymium oxide, copper oxide, antimony oxide, arsenous acid, etc.

[0093] It should be noted that although the compositions listed in the following tables are the composition of the glass itself, if the values ​​after the decimal point are ignored, these values ​​are roughly the same as the amount of the glass raw material oxide used ( The same applies to the other embodiments).

[0094] Then, a platinum-made atmosphere is used to heat batch-type ...

Embodiment 46

[0125] The chemically strengthened glass substrate (2.5-inch disk) obtained in Example 1 was immersed in molten salt of potassium pyrosulfate (300° C.) for 5 minutes to prevent alkali metal components (Li, Na, K) from Treatment of dissolution in glass substrates. The glass substrate treated to prevent the elution of alkali metal ions was immersed in ultrapure water at 80°C for 24 hours to evaluate by ion chromatography. The results showed that the alkali metal components (Li, Na, K) dissolved in water The amount is 0.1-0.3 μmol / tablet. On the other hand, when the alkali metal elution prevention treatment is not performed, the elution amount of the above-mentioned alkali metal component is 15 to 20 μmol / tablet.

[0126] In addition, as the treatment for preventing the elution of alkali metals, hydrogensulfate or a mixed salt of the two may be used in addition to the above-mentioned molten salt of pyrosulfate. Also, other than molten salts, heated concentrated sulfuric acid, h...

Embodiment 47~94

[0128] In Tables 10-13, the glass composition of Examples 47-94 is shown by mol% value. These can be used as a starting material when melting glass, SiO 2 、Al 2 o 3 , Al(OH) 3 , MgO, Mg(OH) 2 , CaCO 3 , SrCO 3 , Sr(NO 3 ) 2 、BaCO 3 、TiO 2 , ZrO 2 , Li 2 CO 3 、Na 2 CO 3 , Y 2 o 3 and La 2 o 3 and other rare earth metal oxides, etc., weigh these metal oxides according to the proportions shown in Tables 10 to 13, and weigh 250 to 800g, and mix them thoroughly to obtain a mixed batch of materials, which are added to the platinum crucible , at a temperature of 1400-1500°C and in air for 3-6 hours to melt these glass components. After melting, inject the glass melt into a carbonaceous material with a size of 180×15×25mm or φ100×5mm. Put it in the mold, let it cool, put it into the annealing furnace immediately when it is cooled to the glass transition point, make it anneal in the range of the glass transition temperature for about 1 hour in the furnace, then let i...

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Abstract

The invention discloses a process for producing a glass substrate for an information recording medium by press-shaping a molten glass which gives a glass containing 0.1 to 30 mol% of TiO2, 1 to 45 mol% of CaO, 5 to 40 mol% of total of MgO and the above CaO, 3 to 30 mol% of total of Na2O and Li2O, 0 to 15 mol% of Al2O3 and 35 to 65 mol% of SiO2 and having properties of a liquidus temperature of 1360 DEG C or lower and a viscosity of at least 10 poise in a shaping-allowable temperature range, or by preparing a preform formed of a glass which contains 0.1 to 30 mol% of TiO2, 1 to 45 mol% of CaO, 5 to 40 mol% of total of MgO and the above CaO, 3 to 30 mol% of total of Na2O and Li2O, 0 to 15 mol% of Al2O3 and 35 to 65 mol% of SiO2 and has properties of a liquidus temperature of 1360 DEG C or lower and shaping the preform in the form of a disc by a re-heat pressing method. According to the above process, there can be mass-produced, with high productivity, high-quality glass substrates to be used for information recording media such as a magnetic disc, an optical disc, a magneto-optic disc, and the like.

Description

technical field [0001] This invention relates to the manufacturing method of the glass substrate for information recording media, and the method of manufacturing an information recording medium using the glass substrate obtained by this method. More specifically, the present invention relates to a method for manufacturing glass substrates that can be used in information recording media such as magnetic disks, optical disks, and magneto-optical disks with high quality, high productivity, and industrial scale, and by A method of manufacturing the above-mentioned information recording medium by providing a recording layer on the obtained glass substrate. technical background [0002] The main components of a magnetic recording device such as a computer are a magnetic recording medium and a magnetic recording and reproducing head. As the magnetic recording medium, there are known floppy disks and hard disks. Among them, an aluminum alloy can be used as a s...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C3/078C03C3/087C03C3/095G11B5/60G11B5/73G11B5/82G11B5/84G11B23/00
CPCG11B5/7315C03C3/078C03C3/087C03C3/095G11B5/6011G11B5/82G11B5/8404G11B23/0028G11B5/73921G11B7/26
Inventor 桥本和明邹学禄
Owner HOYA CORP
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