Preparation of high-water-absorption material from sa-son seed gum graft polymeric acrylic acid (salt) by microwave radiation
A technology of grafting acrylic acid and microwave radiation, which is applied in the field of water-absorbing materials, can solve the problems of low grafting efficiency and long time, and achieve the effects of low energy consumption, shortened reaction cycle and good water absorption performance
Examples
Embodiment 1
[0022] Under cooling in an ice-water bath, neutralize 5 parts of acrylic acid with 18% sodium hydroxide to a neutralization degree of 80%. Then add 0.1 part of initiator (0.1 g / ml), and add 1 part of artemisia gum under thorough stirring. After stirring evenly, place it in a microwave reaction device, adjust the radiation power to 180W, and radiate for 4 minutes to carry out graft polymerization. After the reaction is completed, put the product into a 65°C device for drying, then pulverize it, and measure its water absorption and other properties. After the product was extracted with acetone in a Soxhlet extractor for 36 hours, the grafting efficiency, grafting rate and monomer conversion rate were calculated. Infrared spectroscopy (FT-IR), scanning electron microscopy (TEM), differential scanning calorimetry (DSC), and thermogravimetric analysis (TG-DTA) were used for characterization.
Embodiment 2
[0024] Under cooling in an ice-water bath, neutralize 5 parts of acrylic acid with 18% potassium hydroxide until the degree of neutralization is 80%. Then add 0.1 part of initiator (0.1 g / ml), and add 1 part of locust bean gum under thorough stirring. After stirring evenly, place it in a microwave reaction device, adjust the radiation power to 180W, and radiate for 4 minutes to carry out graft polymerization. After the reaction is completed, put the product into a 68°C device for drying, then pulverize it, and measure its water absorption and other properties. After extracting the product with acetone in a Soxhlet extractor for 36 hours, calculate its grafting efficiency, grafting rate and monomer conversion rate, etc., and apply infrared spectroscopy (FT-IR), scanning electron microscopy (TEM), differential scanning calorimetry Analysis (DSC), thermogravimetric analysis (TG-DTA) etc. for characterization.
Embodiment 3
[0026] Under cooling in an ice-water bath, neutralize 5 parts of acrylic acid with 18% ammonia water until the neutralization degree is 80%. Then add 0.1 part of initiator (0.1 g / ml), and add 1 part of guar gum under thorough stirring. After stirring evenly, place it in a microwave reaction device, adjust the radiation power to 180W, and radiate for 4 minutes to carry out graft polymerization. After the reaction is completed, put the product into a 70°C device for drying, then pulverize it, and measure its water absorption and other properties. After extracting the product with acetone for 40 h in a Soxhlet extractor, calculate its grafting efficiency, grafting rate and monomer conversion rate, etc., and apply infrared spectroscopy (FT-IR), scanning electron microscopy (TEM), differential scanning calorimetry Analysis (DSC), thermogravimetric analysis (TG-DTA) etc. for characterization.
PUM
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Description
Claims
Application Information
- IPC
- C08F251/00
- Inventors
- 王云普; 张继