The invention discloses a structure of a notebook computer illuminant keyboard, which comprises a substrate, a light guide plate, a flexible circuit board, a silicone keypad, a scissor foot and a keycap. The light guide plate is fixed on the substrate, the flexible circuit board is fixed on the upper layer of the light guide plate through a hook of the substrate, the front face of the flexible circuit board is provided with light reflection printing ink, the silicone keypad is directly pasted on the flexible circuit board, the keycap is connected with the substrate through the scissor foot, a light-emitting diode (LED) lamp providing a power supply for the light guide plate is pasted on the back face of the flexible circuit board, two layers of printing ink are arranged on the front face of the light guide plate, the printing ink at the bottom layer is white or mirror plane silver used for increasing light reflection, and the printing ink at the top layer is black used for shading towards the upward direction. The previous front face flat design of the light guide plate is changed to the design with mechanical holes, the light reflection layer and the shading layer are additionally arranged on the front face of the light guide plate, an illuminant layer is additionally arranged on the front face of the flexible circuit board, and materials of a back light plate, a power circuit, a shading piece and the like on the previous keyboard design are reduced.