The invention belongs to the technical field of
straw pyrolysis, and particularly relates to a method for directionally producing ketoaldehyde-rich pyrolytic oil through self-heating corn
straw pyrolysis, which comprises the following steps: S1,
cutting naturally aired corn straws into segments, and crushing the segments into
straw particles, S2, carrying out acid
pickling on the straw particles by using a 1% diluted
hydrochloric acid solution, s3, carrying out liquid-
solid separation on the straw particles after acid
pickling, and baking the straw particles by using high-temperature
flue gas to further reduce the
water content of the raw materials, and S4, feeding the straw particles subjected to baking pretreatment into a high-temperature pyrolyzing furnace through a two-stage feeder, fully mixing with a
heat carrier from a
heat carrier heating furnace for
pyrolysis, and S5, the pyrolysis gas, the pyrolysis carbon and the
heat carrier enter a pyrolysis product separation box for efficient separation. According to the method, through accurate catalyst selection and rapid pyrolysis condition control, a
reaction path is guided to ketoaldehyde pyrolytic
oil generation, the additional value of the pyrolytic oil is remarkably improved, and low-quality fuel is converted into a chemical
raw material.