A shaft seal packing exhibiting high sealing ability in initial assembly and also exhibiting, even after the packing is retightened, excellent sealing ability by an increased seal surface pressure obtained through an effect of pressing and by self-sealing ability obtained through an effect of fluid pressure. A valve element installed in a valve body is provided so as to be rotatable about or liftable along a valve shaft. The shaft seal packing is installed in a shaft seal chamber of a valve in which the valve shaft is set. The shaft seal packing is used for a shaft seal structure for the valve, and in the shaft seal packing, annular packing bodies having a generally V-shape cross- section are stacked on each other, the stack surfaces on the inner diameter side are made to be in intimate contact with each other, and a predetermined gap is formed between adjacent stack surfaces on the outer diameter side. In the shaft seal structure, force applied to the packing bodies by tightening force and fluid pressure is converted into radial force by the taper angle of the stack surface on the inner diameter side. This causes the inner peripheral surfaces of the packing bodies on the inner diameter side and the outer peripheral surface of the valve shaft on the sliding side are sealed between each other by surface contact, and also the gaps allow lip parts on the outer diameter side to be pushed and expanded, causing the lip parts and the shaft seal chamber on the fixed side to be sealed between each other by line contact.