Lipophilic controlled release fertilizer for bioremediation of oil pollution environment and preparation method thereof

A bioremediation and slow-release fertilizer technology, which is applied to ammonium salt fertilizers, urea compound fertilizers, fertilizer mixtures, etc., can solve problems such as refractory degradation, nutrient loss, and slowdown of petroleum hydrocarbon biodegradation process, and achieve easy degradation and no secondary The effect of secondary pollution

Inactive Publication Date: 2008-07-30
CHINA NAT OFFSHORE OIL CORP +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] At present, the preparation of slow-release fertilizers specially for the bioremediation of oil-polluted environments has not been reported, and the agricultural slow-release fertilizers developed in the past are mainly used indoors or on-site Biodegradation Test of Petroleum Hydrocarbons
However, the application of agricultural slow-release fertilizers in the field of bioremediation has the following disadvantages: First, the composition and ratio of nutrient elements in agricultural slow-release fertilizers are often set according to the needs of plant growth, and cannot fully meet the growth of hydrocarbon-degrading bacteria. Due to the improper ratio of nutrient elements, it may lead to the slowdown of the biodegradation process of pe

Method used

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  • Lipophilic controlled release fertilizer for bioremediation of oil pollution environment and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0030] Example 1

[0031] Weigh 1000g of ammonium nitrate with a diameter of 1mm, place it in a drum coating machine, then weigh 167g of calcium dihydrogen phosphate, 3.0g of copper sulfate, ferrous sulfate, zinc sulfate, manganese sulfate, and ammonium molybdate at 1:1: The trace elements are mixed in a ratio of 1:1:0.5, 250g of diatomaceous earth with a particle size of 80-200 mesh, after mixing, place in the feeding box of the coating machine, and then weigh 100g of polyvinyl alcohol to prepare a concentration of 15 % Aqueous solution, pour it into the upper tank of the coating machine. Set the rotation speed to 500rpm and the temperature to 90°C, start the coating machine and air compressor, after the polyvinyl alcohol is atomized by the compressed air, it is sprayed on the surface of the ammonium nitrate particles. At the same time, continue to sprinkle calcium dihydrogen phosphate, diatomaceous earth and trace elements to coat the surface of the nitrogen fertilizer particles...

Example Embodiment

[0032] Example 2

[0033] Weigh 1000g of urea with a granular diameter of about 3mm and place it in a drum coating machine. Then weigh 231g of calcium dihydrogen phosphate, 5.4g of copper sulfate, ferrous sulfate, zinc sulfate, manganese sulfate, and ammonium molybdate according to 1: The trace elements obtained by mixing 1:1:1:0.5 ratio and 154g of kaolin with a particle size of 80-200 mesh, after mixing uniformly, place in a feeding box, and then weigh 53g of polyvinyl alcohol to prepare an aqueous solution with a concentration of 15%. Pour into the upper slot of the coating machine. Set the rotation speed to 250 rpm and the temperature to 70°C, start the coating machine and the air compressor, and spray the polyvinyl alcohol on the surface of the ammonium nitrate particles after being atomized by the compressed air. At the same time, continuously sprinkle calcium dihydrogen phosphate, kaolin and trace elements to coat the surface of the nitrogen fertilizer particles. After the ...

Example Embodiment

[0034] Example 3

[0035]Weigh 1000g of granular ammonium nitrate with a diameter of 5mm and place it in a drum coating machine, then weigh 286g of calcium dihydrogen phosphate, 7g of copper sulfate, ferrous sulfate, zinc sulfate, manganese sulfate, and ammonium molybdate in a ratio of 1:1 :1:1:0.5 ratio of trace elements and 72g of talc powder with a particle size of 80-200 mesh, after mixing uniformly, place in the feeding box of the coating machine, and then weigh 22.5g of polyvinyl alcohol to prepare a concentration of Pour the 15% aqueous solution into the upper tank. Set the rotation speed to 100 rpm and the temperature to 50° C., start the coater and air compressor, the polyvinyl alcohol is atomized by the compressed air and sprayed on the surface of the ammonium nitrate particles. At the same time, continue to sprinkle calcium dihydrogen phosphate, talcum powder and trace elements to coat the surface of the nitrogen fertilizer particles. After the mixture is sprayed, conti...

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Abstract

The invention provides lipophilic slow release fertilizer used for modifying environmental creatures in oil pollution positions and a preparation method for the fertilizer. The composition comprises granular nitrogen fertilizer, calcium dihydrogen phosphate, trace elements, polyvinyl alcohol, vegetable oil and fillers. The granular nitrogen fertilizer is placed in a barrate coating machine; the calcium dihydrogen phosphate, the trace elements and the fillers are mixed uniformly and placed in a feeding tank of the coating machine; the polyvinyl alcohol is prepared as water solution with the concentration of 15 percent, poured into an elevated tank of the coating machine and at the same time rotating speed and the temperature are set; the coating machine and an air compressor are started and the water solution is sprayed on a granular surface of nitrogenous fertilizer according to the set rotating speed and the temperature; meanwhile, the mixture of the calcium dihydrogen phosphate, the trace elements and the fillers are continuously sprinkled and the coating machine and the air compressor are heated to be rotated and the mixture is dried; the vegetable oil is dropped gradually and the two machines continue to rotate and then the coating machine and the air compressors are stopped; the temperature of the mixtures is decreased to room temperature to finish the products. The fertilizer can be attached to the oil and can slowly release the nutrients to maintain the constant growth of bacteria cells, thus remarkably promoting modifying efficiency of the creatures in the oil pollution places.

Description

technical field [0001] The present invention aims to provide a kind of lipophilic slow-release fertilizer which can be used for environmental bioremediation of oil polluted field and its preparation method. Efficiency of bioremediation of oil-contaminated sites. Background technique [0002] With the continuous increase of human exploitation of oil and the rapid development of the oil industry, there are more and more ways and opportunities for oil spills. A large amount of petroleum pollutants enter the environment, which not only destroys the ecological balance, restricts economic development, but also affects human health and survival. The efficient and environment-friendly removal methods of petroleum hydrocarbon pollutants are the frontier research fields of great concern in the world. [0003] Bioremediation refers to the controlled or spontaneous process of using organisms, especially microorganisms, to catalyze the degradation of environmental pollutants and reduce...

Claims

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Application Information

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IPC IPC(8): C05G1/00C05C9/00C05C3/00C05B1/00C05D9/02
CPCY02P60/21
Inventor 朱生凤肖东富梁生康朱有庆陈宇陆金仁侯志恒郭利果杨仕美
Owner CHINA NAT OFFSHORE OIL CORP
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