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Lipophilic controlled release fertilizer for bioremediation of oil pollution environment and preparation method thereof

A bioremediation and slow-release fertilizer technology, which is applied to ammonium salt fertilizers, urea compound fertilizers, fertilizer mixtures, etc., can solve problems such as refractory degradation, nutrient loss, and slowdown of petroleum hydrocarbon biodegradation process, and achieve easy degradation and no secondary The effect of secondary pollution

Inactive Publication Date: 2008-07-30
CHINA NAT OFFSHORE OIL CORP +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] At present, the preparation of slow-release fertilizers specially for the bioremediation of oil-polluted environments has not been reported, and the agricultural slow-release fertilizers developed in the past are mainly used indoors or on-site Biodegradation Test of Petroleum Hydrocarbons
However, the application of agricultural slow-release fertilizers in the field of bioremediation has the following disadvantages: First, the composition and ratio of nutrient elements in agricultural slow-release fertilizers are often set according to the needs of plant growth, and cannot fully meet the growth of hydrocarbon-degrading bacteria. Due to the improper ratio of nutrient elements, it may lead to the slowdown of the biodegradation process of petroleum hydrocarbons or the loss of nutrients and cause other environmental problems; the second is that the coating materials used in some agricultural slow-release fertilizers contain a variety of synthetic polymer materials such as polymers. Acrylic acid, isobutylene, alkyd resin, etc., not only may have a toxic effect on petroleum hydrocarbon degrading bacteria, but also are difficult to degrade, which will cause secondary pollution to the repair environment; third, the surface of agricultural slow-release fertilizers is often hydrophilic. It is not easy to combine or absorb with hydrophobic oil film, and it is not conducive to the attachment of hydrocarbon degrading bacteria, which reduces the efficiency of petroleum hydrocarbon degradation

Method used

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  • Lipophilic controlled release fertilizer for bioremediation of oil pollution environment and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] Weigh 1000g of ammonium nitrate with a diameter of 1mm, place it in a drum coater, then weigh 167g of calcium dihydrogen phosphate, 3.0g of copper sulfate, ferrous sulfate, zinc sulfate, manganese sulfate, ammonium molybdate in 1:1: 1:1:0.5 ratio of trace elements mixed, 250g of diatomite with a particle size of 80-200 mesh, mixed evenly, placed in the feeding box of the coating machine, and then weighed 100g of polyvinyl alcohol, prepared to a concentration of 15 % aqueous solution, pour it into the high position tank of the coating machine. Set the rotation speed at 500 rpm and the temperature at 90° C., start the coating machine and the air compressor, and spray the polyvinyl alcohol on the surface of the ammonium nitrate particles after being atomized by the compressed air. At the same time, continue to sprinkle calcium dihydrogen phosphate, diatomaceous earth and trace elements to coat the surface of nitrogen fertilizer particles. After the mixture is sprinkled, co...

Embodiment 2

[0033] Weigh 1000g of urea with a granular diameter of about 3mm, place it in a drum coating machine, then weigh 231g of calcium dihydrogen phosphate, 5.4g of copper sulfate, ferrous sulfate, zinc sulfate, manganese sulfate, ammonium molybdate according to 1: 1: 1: 1: 0.5 ratio of trace elements and 154g of kaolin with a particle size of 80 to 200 meshes were mixed. After mixing evenly, they were placed in a feeding box, and 53g of polyvinyl alcohol was weighed to prepare a 15% aqueous solution. Pour into the upper tank of the coating machine. Set the rotation speed at 250 rpm and the temperature at 70° C., start the coating machine and the air compressor, and spray the polyvinyl alcohol on the surface of the ammonium nitrate particles after being atomized by the compressed air. At the same time, continue to sprinkle calcium dihydrogen phosphate, kaolin and trace elements to coat the surface of nitrogen fertilizer particles. After the mixture is sprinkled, continue to heat and...

Embodiment 3

[0035]Weigh 1000g of granular ammonium nitrate with a diameter of 5mm, place it in a drum coating machine, then weigh 286g of calcium dihydrogen phosphate, 7g of copper sulfate, ferrous sulfate, zinc sulfate, manganese sulfate, and ammonium molybdate in a ratio of 1:1 : 1: 1: 0.5 ratio of trace elements and 72g of talcum powder with a particle size of 80 to 200 mesh, mixed evenly, placed in the feeding box of the coating machine, and then 22.5g of polyvinyl alcohol was weighed to prepare a concentration of 15% aqueous solution, poured into the elevated tank. Set the rotation speed at 100 rpm and the temperature at 50° C., start the coating machine and the air compressor, and spray the polyvinyl alcohol onto the surface of the ammonium nitrate particles after being atomized by the compressed air. At the same time, continuously sprinkle calcium dihydrogen phosphate, talcum powder and trace elements to coat the surface of nitrogen fertilizer particles. After the mixture is sprink...

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Abstract

The invention provides lipophilic slow release fertilizer used for modifying environmental creatures in oil pollution positions and a preparation method for the fertilizer. The composition comprises granular nitrogen fertilizer, calcium dihydrogen phosphate, trace elements, polyvinyl alcohol, vegetable oil and fillers. The granular nitrogen fertilizer is placed in a barrate coating machine; the calcium dihydrogen phosphate, the trace elements and the fillers are mixed uniformly and placed in a feeding tank of the coating machine; the polyvinyl alcohol is prepared as water solution with the concentration of 15 percent, poured into an elevated tank of the coating machine and at the same time rotating speed and the temperature are set; the coating machine and an air compressor are started and the water solution is sprayed on a granular surface of nitrogenous fertilizer according to the set rotating speed and the temperature; meanwhile, the mixture of the calcium dihydrogen phosphate, the trace elements and the fillers are continuously sprinkled and the coating machine and the air compressor are heated to be rotated and the mixture is dried; the vegetable oil is dropped gradually and the two machines continue to rotate and then the coating machine and the air compressors are stopped; the temperature of the mixtures is decreased to room temperature to finish the products. The fertilizer can be attached to the oil and can slowly release the nutrients to maintain the constant growth of bacteria cells, thus remarkably promoting modifying efficiency of the creatures in the oil pollution places.

Description

technical field [0001] The present invention aims to provide a kind of lipophilic slow-release fertilizer which can be used for environmental bioremediation of oil polluted field and its preparation method. Efficiency of bioremediation of oil-contaminated sites. Background technique [0002] With the continuous increase of human exploitation of oil and the rapid development of the oil industry, there are more and more ways and opportunities for oil spills. A large amount of petroleum pollutants enter the environment, which not only destroys the ecological balance, restricts economic development, but also affects human health and survival. The efficient and environment-friendly removal methods of petroleum hydrocarbon pollutants are the frontier research fields of great concern in the world. [0003] Bioremediation refers to the controlled or spontaneous process of using organisms, especially microorganisms, to catalyze the degradation of environmental pollutants and reduce...

Claims

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Application Information

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IPC IPC(8): C05G1/00C05C9/00C05C3/00C05B1/00C05D9/02
CPCY02P60/21
Inventor 朱生凤肖东富梁生康朱有庆陈宇陆金仁侯志恒郭利果杨仕美
Owner CHINA NAT OFFSHORE OIL CORP
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