Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Composite material using nano inorganic powder as surface with autocatalytic activity and preparation method thereof

A nano-inorganic, active surface technology, used in catalyst activation/preparation, chemical instruments and methods, physical/chemical process catalysts, etc. Process flow, saving precious metals, reducing the effect of environmental pollution

Inactive Publication Date: 2009-05-27
UNIV OF SCI & TECH BEIJING
View PDF0 Cites 14 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the commonly used catalysts in this process are precious metals such as platinum, palladium, silver, etc. Not only the waste of precious metals is serious, but also the whole process equipment is complicated, the process is complicated, and the operation technology is difficult, resulting in high product cost; various pretreatment liquids are unstable. , The composition is not easy to control, the pass rate of large-area plating is low, and the product quality is difficult to meet the requirements; in addition, the use of a large number of chemical reagents also makes the production process more polluted, which is increasingly not in line with the requirements of economic and social development

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] After the poly-p-phenylenebenzobisoxazole (PBO) fiber is repeatedly washed with ethanol and distilled water, it is immersed in a modified solution prepared by polyphosphoric acid and absolute ethanol at a volume ratio of 1:1 to 3 for 1 to 60 minutes, and then Wash repeatedly with distilled water.

[0019] Disperse 1-3g of nano-titanium dioxide powder in 50-500mL of distilled water, add 0.01-0.5g of sodium polyphosphate and 0.01-0.3g of sodium dodecylbenzenesulfonate as a dispersant, and adjust the pH to 7 with ammonia water ~12, ultrasonic vibration for 20~120min to prepare uniformly dispersed nano-titanium dioxide powder emulsion. The nano-titanium dioxide powder emulsion is placed in a constant temperature water bath, and the temperature is gradually raised to 50-100°C. Adjust the pH value to 2-6 with hydrochloric acid, then add 1-10 mL of silane coupling agent dropwise, and stir vigorously for 20-120 minutes.

[0020] Take 0.5-2.5g of the above-mentioned modified n...

Embodiment 2

[0024] Polyester fabric at 20~60g·L -1 After being treated in sodium hydroxide solution at 50-100°C for 10-60 minutes, wash repeatedly with distilled water.

[0025] Take 1-4g of nano-zinc oxide powder, dilute with 50-95% ethanol solution, and ultrasonically vibrate for 20-90 minutes to prepare uniformly dispersed nano-zinc oxide powder emulsion. The nano-zinc oxide powder emulsion is placed in a constant temperature water bath, and the temperature is gradually raised to 50-100° C., then 1-10 mL of titanate coupling agent is added dropwise, and vigorously stirred for 20-120 min.

[0026] Take 0.5-2.5g of the above-mentioned modified nano-zinc oxide powder and place it in 100-300mL of isopropanol solution, control the temperature at 50-100°C, and ultrasonically disperse for 20-90min to prepare a uniformly dispersed emulsion. Soak the modified polyester fabric in the emulsion, add 0.1-5mL titanate coupling agent dropwise into the emulsion, continue ultrasonic oscillation for 30...

Embodiment 3

[0030] Polypropylene plastic matrix at 20-50mL·L -1 Turpentine and 30~60mL·L -1 In a solution composed of non-ionic surfactants, treat at 50-90°C for 10-50 minutes, then in 250-400g·L -1 Chromic anhydride and 150~400g·L -1 Treat in a solution composed of sulfuric acid at 50-90°C for 10-50 minutes, and then wash repeatedly with distilled water.

[0031]Take 2-3g of nano tin oxide powder and disperse it in 50-400mL of deionized water, add 1-5g of sodium oleate as a dispersant at the same time, adjust the pH value to 7-12 with ammonia water, and oscillate ultrasonically for 20-100min to prepare evenly dispersed Nano tin oxide powder emulsion. The nano-tin oxide powder emulsion is placed in a constant temperature water bath, and the temperature is gradually raised to 50-100°C. Adjust the pH value to 2-6 with hydrochloric acid, then add 1-10 mL of silane coupling agent dropwise, and stir vigorously for 20-120 minutes.

[0032] Take 0.5-2.5g of the above-mentioned modified nano...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
particle diameteraaaaaaaaaa
Login to View More

Abstract

The invention discloses a compound material which takes nano inorganic power as an autocatalysis active surface as well as a preparation method thereof, and belongs to the field of compound material. The invention is characterized in that a nano inorganic power layer is used as the bedded compound material of the autocatalysis active surface; fiber, plastic, fabric, resin, glass, ceramics, monocrystal line silicon and metals are used as the material of a substrate; the nano inorganic power like nano titanium dioxide or nano magnesia or nano zinc oxide or nano alumina, or nano zirconia, or nano nickel oxide, or nano jewellers putty, or nano cobalt oxide is used as an autocatalysis active material; an layer of nano inorganic power film is coated on the surface of the substrate material by adopting a dipping coating method and is used as the autocatalysis active surface; then a chemical method is adopted to load metals on the autocatalysis active surface of the nano inorganic power to develop the bedded compound material which has high quality and low cost, and takes the nano inorganic power as the autocatalysis active surface. The nano inorganic power is used as the autocatalysis active surface to replace the heavy metals of platinum, palladium and sliver in the traditional chemical plating, thus saving the heavy metals, reducing the product cost, shortening the technique flow and reducing the environment pollution.

Description

technical field [0001] The invention belongs to the field of composite materials, and relates to a layered composite material with a nano inorganic powder layer as a self-catalyzed active surface and a preparation method thereof. Background technique [0002] Loading metal on the surface of polymer materials, inorganic non-metallic materials and metal materials to develop new layered composite materials will have unique advantages that single materials do not have. It is currently the research focus and focus of international materials science and engineering. Development direction, has broad application prospects. Improving product quality, shortening process flow, reducing production cost, and reducing environmental pollution are the key points in the research and development of this type of layered composite material. [0003] Electroless plating is a typical method for preparing layered composite materials. Its principle is: in the absence of external current, the metal...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): B01J37/02B01J35/02B01J23/70B01J23/80B01J23/835
Inventor 刘雪峰谢建新栾燕燕
Owner UNIV OF SCI & TECH BEIJING
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products