Road phase-change temperature regulator and preparation method thereof

A phase change and temperature regulation technology, which is used in the preparation of microspheres, chemical instruments and methods, and microcapsule preparations. Production and other issues, to achieve significant technical feasibility and economic feasibility, eliminate adverse effects, and low production costs

Inactive Publication Date: 2012-10-03
CHANGAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] To apply phase change materials in the road industry, the above three methods mainly have the following problems: (1) The impregnation method requires that phase change materials and road substrates must have good compatibility, such stringent requirements directly lead to The application of phase change materials has been greatly limited; (2) The pavement of the road is a porous interconnected structure, and the use environment is complex, including solar radiation, freeze-thaw cycle, atmospheric precipitation, groundwater, traffic load and many other environmental factors. The direct incorporation method It not only reduces the performance of the road substrate, but also the mixed phase change material cannot play its temperature regulation function stably and permanently; (3) The existing composite phase change material with microcapsule structure cannot meet the requirements of its compatibility with the road substrate. The main reason is that the microcapsule structure encapsulating the phase change material will be destroyed at a mixing temperature of 160°C to 180°C, resulting in a large loss of phase change material and failing to achieve the effect of energy storage and temperature regulation
In addition, in the prior art, the preparation process of compounding phase-change materials into a microcapsule structure is complicated, the preparation conditions are harsh, and the production cost is high. It is not suitable for mass production at the construction site and cannot meet the requirements of road construction.

Method used

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  • Road phase-change temperature regulator and preparation method thereof
  • Road phase-change temperature regulator and preparation method thereof
  • Road phase-change temperature regulator and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] The highway phase-change temperature-regulating agent of this embodiment is made of the following raw materials in parts by weight: 25 parts of phase-change materials, 25 parts of white carbon black, 2 parts of ethyl cellulose, 0.3 parts of plasticizer, and 15 parts of organic solvents; The phase change material is paraffin or / and C 12 ~C 20 straight-chain alkanes, the paraffin wax has a melting point of 36°C to 50°C, and the plasticizer is an aliphatic dibasic acid ester or / and citrate; the preferred phase change material is n-tetradecane, and the preferred plasticizer The plasticizer is diisooctyl sebacate, the preferred organic solvent is dehydrated alcohol, and the preferred average particle size of white carbon black is 50nm.

[0034] The preparation method of the highway phase-change temperature-regulating agent of the present embodiment may further comprise the steps:

[0035] Step 1, stirring the plasticizer and the organic solvent uniformly by weight to obtai...

Embodiment 2

[0041]This embodiment is the same as Example 1, except that the preferred phase change material is n-tridecane, n-pentadecane or paraffin wax with a melting point of 36°C to 50°C, or n-tridecane, n-decadecane At least two of tetradecane, n-pentadecane, and paraffin waxes with a melting point of 36°C to 50°C; preferred plasticizers are dimethyl sebacate, di-n-octyl sebacate, triethyl citrate or Tri-n-butyl citrate, or at least two of di-isooctyl sebacate, dimethyl sebacate, di-n-octyl sebacate, triethyl citrate and tri-n-butyl citrate, The preferred organic solvent is absolute methanol, cyclohexane or acetone, or at least two of absolute ethanol, absolute methanol, cyclohexane and acetone.

[0042] The preparation method of the highway phase-change temperature-regulating agent of this embodiment is the same as that of Embodiment 1.

[0043] The phase-change temperature-regulating agent for roads in this embodiment has a micron-scale capsule structure.

Embodiment 3

[0045] The road phase change temperature regulating agent of this embodiment is made of the following raw materials in parts by weight: 10 parts of phase change material, 10 parts of white carbon black, 1 part of ethyl cellulose, 0.1 part of plasticizer, and 10 parts of organic solvent; The phase change material is paraffin or / and C 12 ~C 20 straight-chain alkanes, the paraffin wax has a melting point of 36°C to 50°C, and the plasticizer is an aliphatic dibasic acid ester or / and citrate; the preferred phase change material is n-tridecane, and the preferred plasticizer The plasticizer is dimethyl sebacate, the preferred organic solvent is anhydrous methanol, and the preferred average particle size of white carbon black is 100nm.

[0046] The preparation method of the highway phase-change temperature-regulating agent of the present embodiment may further comprise the steps:

[0047] Step 1, stirring the plasticizer and the organic solvent uniformly by weight to obtain a mixed ...

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Abstract

The invention provides a road phase-change temperature regulator. The road phase-change temperature regulator is prepared from a phase change material, white carbon black, ethyl cellulose, a plasticizer and an organic solvent. The invention further provides a preparation method of the road phase-change temperature regulator. The preparation method of the road phase-change temperature regulator comprises the following steps: 1, uniformly stirring the plasticizer and the organic solvent to obtain a mixed solution; 2, adding the ethyl cellulose into the mixture to obtain a glue solution; 3, making the phase change material and the white carbon black into a moulded phase change material; and 4, uniformly stirring the moulded phase change material and the glue solution, and heating and drying to obtain the road phase-change temperature regulator. The road phase-change temperature regulator is wide in raw material source, simple in process and low in production cost and can be produced in batches on a construction site directly; and the road phase-change temperature regulator has a micro-scale capsule structure, can perform phase change along with change of the ambient temperature and store or release energy, can effectively regulate the surface temperature of a road and improve the capability of the road in responding to the change of the ambient l temperature.

Description

technical field [0001] The invention belongs to the technical field of phase-change energy storage materials, and in particular relates to a phase-change temperature-regulating agent for roads and a preparation method thereof. Background technique [0002] With the vigorous development of social economy, people's awareness of traffic safety is increasing day by day, and the quality of road performance has attracted more and more attention. However, there are various diseases on the pavement of existing roads in our country, which have seriously affected the performance of the road: asphalt pavement becomes soft when heated, prone to high-temperature rutting, and hardens when cold, prone to low-temperature cracking; cement concrete pavement thermal expansion and cold Shrinkage is prone to cracks on the road surface; in addition, the freeze-thaw cycle of water makes the road surface prone to damage such as potholes, deformation, and mud pumping. These diseases are all closely...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K5/06B01J13/02
Inventor 马骉汪海年畅玉皎
Owner CHANGAN UNIV
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