The invention provides 
graphene microcapsules, intelligent 
thermoregulation fibers and preparation methods thereof. The 
graphene microcapsules comprise a core material and a shell material, wherein the core material is a 
graphene material, and the shell material is a 
synthetic polymer or natural 
polymer material; the content of the core material is 15wt%-60wt% preferably. The preparation method ofthe graphene microcapsules comprises the following steps: an 
aqueous dispersion of the graphene material and a shell material 
raw material are mixed and emulsified, and a suspension is formed, the 
aqueous dispersion of the graphene material is prepared from deionized water, graphene and a surfactant; the shell material 
raw material is a 
prepolymer of a 
synthetic polymer or the natural 
polymer material; a curing agent or an initiator is added to the suspension, a curing reaction is performed, filtering and 
drying are performed, and the graphene microcapsules are obtained. By graphene microencapsulation, not only are 
dispersity and compatibility of graphene in a substrate improved, but also heat conduction and storage performance of the microcapsules is improved, a 
spinning process is optimized, and smoothness of surfaces of graphene modified fibers is improved.