A superfine particulate matter purifying device comprises a gas discharge-electrocoagulation device and a static enhance bag type dedusting integrated device. The gas discharge-electrocoagulation device comprises an air flow inlet (1), a corona wire (2), a gas discharge tube (3), an air flow outlet divergent pipe (5), a direct current power supply (6) and a grounding electrode (7), and the static enhance bag type dedusting integrated device comprises an air inlet (8), a magnetic valve (9), an air pocket (10), a pulse valve (11), a jetting pipe (12), a filtering bag (13), a jetting hole (14), a dust skeleton (15), a dust hopper (16), a spiral dust discharge valve (17), wires (19) and ground wires (20). The air flow inlet is arranged at one end of the gas discharge tube, the other end of the gas discharge tube is connected with the air flow outlet divergent pipe, the dust skeleton is formed by distributing the wires and the ground wires in a vertical direction at intervals, and the superfine particulate matter purifying device is suitable for smoke dust removing and particularly superfine dust purifying devices for particulate matter (PM) below 2.5.