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Method for manufacturing conductive polypropylene fibers

A technology of polypropylene fiber and manufacturing method, applied in the direction of conductive/antistatic filament manufacturing, fiber treatment, conjugated synthetic polymer artificial filament, etc., can solve the problem of lack of elasticity, conductivity, fiber strength inferior to metal conductive fiber, Metal conductive fiber is hard and other problems, to achieve durable self-generated conductivity, good self-generated conductivity, and improve the effect of breaking strength

Active Publication Date: 2013-03-20
ZHEJIANG SCI-TECH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] For many years, scientific and technological workers have used ordinary fiber-forming polymers as the matrix to develop conductive fibers of polymer materials by adding conductive substances. In this way, the fibers not only have conductive properties, but also have the excellent processing performance of ordinary synthetic fibers. Functional fiber with spinnability, but the conductivity and fiber strength of polymer matrix conductive fiber are not as good as metal conductive fiber, and metal conductive fiber is too hard and lacks elasticity, which is greatly restricted in use

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] The manufacture method of conductive polypropylene fiber of the present invention, this manufacture method adopts following steps:

[0023] In step A), 15 copies of tetraacicular zinc oxide whiskers with a diameter of 0.2-1um and a length of 5-15um are taken according to the number of parts by mass; 5 copies of whiskers with a diameter of 0.2-0.6um and a length of 5-12um Conductive potassium titanate whiskers; after mixing the above materials evenly, bake them in a vacuum furnace at 350°C for 4-6 hours; after cooling, stir and disperse them in absolute ethanol with sodium hexametaphosphate, and treat them with atmospheric pressure plasma for 10-20 minutes; then Ultrasonic disperse and wash in deionized water containing calcium stearate dispersion at 60-70°C for 30 minutes, take the suspended whiskers in the upper layer of the solution and filter them through 120 mesh, take the modified whiskers mixed solution, and repeat the operation 3-5 times until filtered Clear; aft...

Embodiment 2

[0027] The manufacture method of conductive polypropylene fiber of the present invention, this manufacture method adopts following steps:

[0028]A) According to the number of parts by mass, take 12 copies of tetraacicular zinc oxide whiskers with a diameter of 0.2-1um and a length of 5-15um; 3 copies of electrical conductivity with a diameter of 0.2-0.6um and a length of 5-12um Potassium titanate whiskers; after mixing the above materials evenly, bake them in a vacuum furnace at 300°C for 4 hours; after cooling, stir and disperse them in absolute ethanol with sodium hexametaphosphate, and then treat them with normal pressure plasma for 10 minutes; Ultrasonic dispersion and cleaning in deionized water of calcium acid dispersion for 25 minutes, take the suspended whiskers in the upper layer of the solution and filter through 100 mesh, take the modified whisker mixed solution, and repeat the operation 3 times until filtering; after filtering, dry in a vacuum oven , to obtain a m...

Embodiment 3

[0032] The manufacture method of conductive polypropylene fiber of the present invention, this manufacture method adopts following steps:

[0033] A) According to the number of parts by mass, take 18 copies of tetraacicular zinc oxide whiskers with a diameter of 0.2-1um and a length of 5-15um; 8 copies of electrical conductivity with a diameter of 0.2-0.6um and a length of 5-12um Potassium titanate whiskers; after mixing the above materials evenly, bake them in a vacuum furnace at 400°C for 6 hours; after cooling, stir and disperse them in absolute ethanol with sodium hexametaphosphate, and then treat them with normal pressure plasma for 20 minutes; Ultrasonic dispersion and cleaning in deionized water of calcium acid dispersion for 35 minutes, take the suspended whiskers in the upper layer of the solution and filter through 150 mesh, take the modified whiskers mixed solution, and repeat the operation 5 times until filtering; after filtering, dry in a vacuum oven , to obtain a...

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Abstract

The invention discloses a method for manufacturing conductive polypropylene fibers. The method comprises the following steps of: A) uniformly mixing tetrapod-shaped zinc oxide whiskers with conductive potassium titanate whiskers, baking the mixture in a vacuum furnace, cooling, then dispersing by stirring in absolute ethyl alcohol containing sodium hexametahposphate, performing plasma treatment at normal pressure, and performing ultrasonic dispersion, cleaning, filtering and drying in deionized water containing a calcium stearate dispersion liquid to obtain a modified whisker mixture; B) mixing and stirring the modified whisker mixture with antimony doped tin oxide conductive powder, superconducting carbon black, an aluminate coupling agent, polyethylene wax and a PP-g-MAH compatibilizer, adding isotactic polypropylene powder into the mixture, and stirring to obtain a conductive isotactic polypropylene blend; and C) preparing the conductive isotactic polypropylene blend and other compatible polypropylene (PP) or polyethylene (PE) into the conductive polypropylene fibers with the conductive polypropylene as a skin layer through composite spinning.

Description

technical field [0001] The invention relates to a method for manufacturing conductive polypropylene fibers, including zinc oxide whiskers (ZnO), conductive potassium titanate whiskers (PTW), ATO conductive powder, superconductive carbon black and other fibers, which belong to functional fibers Manufacturing Technology. Background technique [0002] Polypropylene fiber, also known as PP fiber or polypropylene fiber, is a fiber spun from isotactic polypropylene. Its biggest advantage is light weight and a density of 0.91 / cm 3 , 20-30% lighter than ordinary chemical fibers, is the smallest specific gravity of all textile fibers, it has high strength, large elongation, high initial modulus, and excellent elasticity. The wear resistance of polypropylene fiber is second only to that of polyamide fiber; it has good corrosion resistance, especially for inorganic acid and alkali stability; it does not mold, rot, and is not afraid of moths; but polypropylene fiber does not absorb wat...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F8/06D01F1/09D01D5/34
Inventor 汪进前郑荣福凌荣根
Owner ZHEJIANG SCI-TECH UNIV
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