A metal surface silane treatment agent containing diethyltoluenediamine and its preparation method

A technology of diethyltoluenediamine and silane treatment agent, which is applied in the direction of metal material coating process, etc., can solve the problems of weak holding force of metal body, low energy consumption of production process, uneven density, etc., so as to improve film formation. Effects of mass, low polarization current density, and high dispersion stability

Inactive Publication Date: 2016-05-11
广州易泽得环保科技有限公司
View PDF4 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] In the field of metal surface treatment, although traditional phosphate conversion and chromate passivation surface treatment technologies can achieve good results, the waste liquid discharged during the treatment process contains heavy metal ions such as zinc, manganese, nickel, chromium and nitrous acid. Carcinogens such as salt are very serious to environmental pollution, and metal surface silanization treatment technology is considered to be expected to replace phosphate conversion treatment and chromate passivation treatment because it does not involve substances that are harmful to the environment, the production process has low energy consumption, and the technology has a wide range of applications. Chemical treatment is the latest development direction of metal surface protection alone. In the existing technology, the film formed on the surface of metal workpieces treated with silane solution has uneven density, holes, cracks, and weak adhesion to the metal body.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] A metal surface silane treatment agent containing diethyltoluenediamine is a mixed solution prepared from the following components, and the parts by weight (grams) of each component in each liter of the mixed solution are:

[0022] Vinyl triethoxysilane 40, aminopropyl triethoxysilane 48, water-based nano zinc oxide material 170, 1,4-cyclohexanedimethanol 3, ethylene glycol tert-butyl ether 2, sodium tripolyphosphate 3. Propylene glycol 4, zirconium tetrafluoride 3, ammonium molybdate 3, sodium carbonate 2-3, diethylene glycol butyl ether 2, boric acid 2, diethyltoluenediamine 0.5, and the rest is water;

[0023] The preparation method of described aqueous nano zinc oxide material is:

[0024] (1) Ultrasonic disperse nano-zinc oxide in absolute ethanol 10 times its mass to obtain a dispersion, and then add 4% of its mass of dicumyl peroxide and 2% of anilinomethyltriethoxysilane In the above dispersion, reflux reaction at 90°C for 1 hour, after the reaction, a nano-zin...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
particle sizeaaaaaaaaaa
particle sizeaaaaaaaaaa
Login to view more

Abstract

The invention discloses a metal surface silane treating agent containing plant ash. The metal surface silane treating agent is characterized by being a mixture solution prepared from the following ingredients in parts by weight (gram) in each liter of the mixture: 32-40 parts of vinyl triethoxysilane, 33-48 parts of aminopropyl triethoxy silane, 120-170 parts of aqueous nano-zinc oxide, 2-3 parts of 1,4-cyclohexanedimethanol, 1-2 parts of ethylene glycol butyl ether, 2-3 parts of sodium tripolyphosphate, 2-4 parts of propylene glycol, 2-3 parts of zirconium tetrafluoride, 2-3 parts of ammonium molybdate, 2-3 parts of sodium carbonate, 1-2 parts of diethylene glycol butyl ether, 1-2 parts of boric acid, 0.3-0.5 parts of diethyl toluenediamine and the balance of water. The aqueous nano-zinc oxide prepared by using the process provided by the invention has high dispersion stability and efficient adhesiveness, and is uniformly distributed on the surface of a metal, so that the metal has high compactness and anti-ion permeability; and due to the added assistant such as the zirconium tetrafluoride and the like, the compactness of a silane absorbing film is increased, the filming quality is improved, the film layer has the characteristics of being strong in adhesion capability, free of cavity and rift, compact and uniform and small in polarization current density, and the production process is environmental-friendly and pollution-free.

Description

technical field [0001] The invention mainly relates to a metal surface silane treatment agent and a preparation method thereof, in particular to a metal surface silane treatment agent containing diethyltoluenediamine and a preparation method thereof. Background technique [0002] In the field of metal surface treatment, although traditional phosphate conversion and chromate passivation surface treatment technologies can achieve good results, the waste liquid discharged during the treatment process contains heavy metal ions such as zinc, manganese, nickel, chromium and nitrous acid. Carcinogens such as salt are very serious to environmental pollution, and metal surface silanization treatment technology is considered to be expected to replace phosphate conversion treatment and chromate passivation treatment because it does not involve substances that are harmful to the environment, the production process has low energy consumption, and the technology has a wide range of applica...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Patents(China)
IPC IPC(8): C23C22/44
Inventor 王立新
Owner 广州易泽得环保科技有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products