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A kind of solar cell and its preparation method

A solar cell and anode layer technology, applied in circuits, photovoltaic power generation, electrical components, etc., can solve the problems of reducing the mobility of two-phase materials, destroying the crystal structure of materials, and reducing the fill factor, so as to reduce carrier migration loss and Recombination, increasing fill factor, and improving the effect of photogenerated current

Inactive Publication Date: 2015-08-26
陈卫兵
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Since the donor and the acceptor in the heterostructure of the blend system can be regarded as doping with each other, and doping will cause damage to the crystal structure of the material, the photogenerated carriers mainly move on the covalent bonds in the molecule, and move between the molecules Migration is relatively difficult, resulting in the recombination of electrons and holes during the migration process, significantly reducing the mobility of the two-phase material in the blend system, reducing the photogenerated current and reducing the fill factor

Method used

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  • A kind of solar cell and its preparation method
  • A kind of solar cell and its preparation method
  • A kind of solar cell and its preparation method

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Experimental program
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Embodiment 1

[0035] like figure 2 and image 3 As shown, a solar cell comprises a glass substrate layer 1 and an anode layer 2, an anode buffer layer 3, an active layer 4, a cathode interface layer 5 and a cathode layer 6 bonded sequentially on the glass substrate layer 1, and the The source layer 4 is composed of a plurality of donor material layers 8 and a plurality of acceptor material layers 7 arranged perpendicular to the glass substrate layer 1, the donor material layers 8 and the acceptor material layers 7 are laminated alternately, and one donor material layer The thickness a 9 of layer 8 and a layer 7 of receptor material bonded thereto is 200 nm.

[0036] The donor material layer 8 is a poly-3-hexylthiophene layer, and the acceptor material layer 7 is a [6,6]-phenyl-C61-butyric acid methyl ester layer.

[0037] The thickness b(10) of the active layer 4 is 100 nm.

Embodiment 2

[0039] Place the purchased solid samples poly-3-hexylthiophene (P3HT) and carbon 60 derivatives: [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) into clean reagent bottles, and add an appropriate amount of Put 1,2-dichlorobenzene solvent into an ultrasonic bath, when P3HT is completely dissolved, immediately add PCBM solution to form a mixed solution, and put the mixed solution into an ultrasonic bath for 5 minutes for standby. The concentrations of P3HT and PCBM mixed solution were 15mg / ml respectively.

[0040] Choose ITO glass from Tinwell Technology Ltd.Glass company, its square resistance is 35Ω / □, and its size is 38×38mm 2, the thickness is 1.1mm. Sonicate with toluene and acetone for 8 minutes in turn; then use deionized water for 5 minutes, repeat three times; blow dry with nitrogen, and let it stand in a constant temperature oven at 120°C for 30 minutes to remove organic matter on the surface of ITO. Then place the glass sheet on a homogenizer, and spin-coat a PED...

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Abstract

The invention belongs to the field of photoelectric devices and particularly provides a solar battery with a novel active layer and the preparation method for the solar battery. The solar battery comprises a glass substrate layer (1), an anode layer (2), an anode buffering layer (3), an active layer (4), a cathode interface layer (5) and a cathode layer (6), wherein the anode layer (2), the anode buffering layer (3), the active layer (4), the cathode interface layer (5) and the cathode layer (6) are combined on the glass substrate layer (1) in an attaching mode in sequence. The active layer (4) is composed of a plurality of donor material layers (8) and a plurality of receptor material layers (7). The plurality of donor material layers (8) and the plurality of receptor material layers (7) are arranged perpendicularly to the glass substrate layer (1). The donor material layers (8) and the receptor material layers (7) are alternately combined in an attaching mode, and the thickness a (9) of one donor material layer (8) and one receptor material layer (7) combined with the one donor material layer (8) in an attaching mode is less than or equal to 200nm. By means of the active layer of the solar battery, photoproduction excitons can be locally spread on a D / A interface and decomposed into electrons and electron holes, so that exciton decomposing efficiency is improved, and meanwhile current-carrier mobility is improved.

Description

technical field [0001] The invention belongs to the field of photoelectric devices, and in particular relates to a solar cell with a novel active layer and a preparation method thereof. Background technique [0002] With the development of the world economy, the demand for energy is increasing year by year, and the primary energy sources such as coal and oil are gradually being exhausted. However, solar energy, as a green and environmentally friendly renewable energy, has attracted more and more attention from all countries. [0003] After more than 50 years of development, monocrystalline silicon solar cells have been quite mature, and the energy conversion efficiency has grown from the initial 6% to the current 25%, approaching the theoretical limit of Shockley–Queisser. At the same time, polycrystalline silicon, amorphous silicon, gallium arsenide, indium copper selenium and cadmium telluride thin-film batteries have also been greatly developed, among which polycrystallin...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L51/42H01L51/48
CPCY02E10/549
Inventor 陈卫兵许中华杨伟丰
Owner 陈卫兵