Complexing agent for removing phenolic compounds in water

A technology of phenolic compounds and complexing agents, which is applied in the field of complexing agents for removing phenolic compounds in water, can solve the problems of high cost, many factors and restrictions on the efficiency of phenol removal, and achieve low equipment requirements and low processing costs Effect

Inactive Publication Date: 2015-09-09
缪琼华
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The disadvantage is that this method can only remove low-boiling point phenols, and consumes a lot of energy. It takes about 180 kg of fuel equivalent to standard coal to evaporate 1 ton of waste water.
[0006] 3. Incineration method: The phenolic wastewater is sprayed into the incinerator, so that the phenolic organic matter undergoes an oxidation reaction at a high temperature of about 1100 ° C, and finally produces CO 2 and H 2 O emission, this method is simple in process and easy to operate, but it consumes a lot of energy, and the cost of incinerating 1 ton of phenol-containing wastewater is relatively high
Another key disadvantage of using the incineration method to treat phenol-containing wastewater is that once the operation is careless, the furnace temperature will drop, which will often cause incomplete combustion and easily cause secondary pollution.
This method must use high-efficiency extractant and alkali, and the operating cost is relatively high
[0008] 5. Resin dephenolization method: The main process of this method includes adsorption and desorption, using resin to adsorb phenol in wastewater, and then desorbing with lye to generate sodium phenolate. The process of this method is relatively complicated, and factors that affect the efficiency of dephenolization Many, relatively high operating costs
The biochemical method has relatively strict requirements on the q

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0054] A complexing agent for removing phenolic compounds in water, comprising the following raw materials by weight fraction:

[0055] 12 parts of γ-terpinene,

[0056] 18 parts of 3-phenyl-2-propyl acrylate,

[0057] Chlorinated anthocyanins 1 part,

[0058] 18 parts of ferric ammonium oxalate,

[0059] α-Cubene 16 parts,

[0060] 0.8 part of oxadiazolone,

[0061] Methoxypyridine 11 parts,

[0062] 11 parts of N-nitrosophenylamine salt,

[0063] 15 parts of ferric chloride,

[0064] 5 parts of asiaticoside,

[0065] Hexathiazole 3 parts,

[0066] 3 parts bornyl acetate,

[0067] 20 parts polyacrylamide,

[0068] [R-(R*,R*)]-2,3,4-trihydroxybutyraldehyde 8 parts,

[0069] Fucoxanthin 8 parts,

[0070] 2-hydroxyethyl cellulose 4 parts.

[0071] Before treatment: 1L water sample contains m-cresol 10mg, 2,4,6-trichlorophenol 10mg, p-nitrophenol 5mg, add 50mg of this complexing agent;

[0072] After treatment: m-cresol 0.01mg, 2,4,6-trichlorophenol and p-nitrophenol ...

Embodiment 2

[0074] A complexing agent for removing phenolic compounds in water, comprising the following raw materials by weight fraction:

[0075] 18 parts of γ-terpinene,

[0076] 25 parts of 3-phenyl-2-propyl acrylate,

[0077] Chlorinated anthocyanins 0.9 parts,

[0078] 18 parts of ferric ammonium oxalate,

[0079] α-Cubene 15 parts,

[0080] 0.8 part of oxadiazolone,

[0081] Methoxypyridine 10 parts,

[0082] 10 parts of N-nitrosophenylamine salt,

[0083] 13 parts of ferric chloride,

[0084] 4 parts of asiaticoside,

[0085] Hexathiazole 3 parts,

[0086] 5 parts of bornyl acetate,

[0087] 22 parts polyacrylamide,

[0088] [R-(R*,R*)]-2,3,4-trihydroxybutyraldehyde 10 parts,

[0089] Fucoxanthin 9 parts,

[0090] 5 parts of 2-hydroxyethyl cellulose.

[0091] Before treatment: 1L water sample contains 10mg of phenol, 10mg of 2,4-dichlorophenol, 5mg of p-nitrophenol, add 50mg of this complexing agent;

[0092] After treatment: phenol, 2,4-dichlorophenol and p-nitrophe...

Embodiment 3

[0094] A complexing agent for removing phenolic compounds in water, comprising the following raw materials by weight fraction:

[0095] γ-terpinene 15 parts,

[0096] 20 parts of 3-phenyl-2-propyl acrylate,

[0097] Chlorinated anthocyanins 1 part,

[0098] 18 parts of ferric ammonium oxalate,

[0099] α-Cubene 15 parts,

[0100] 0.8 part of oxadiazolone,

[0101] Methoxypyridine 12 parts,

[0102] 9 parts of N-nitrosophenylamine salt,

[0103] 15 parts of ferric chloride,

[0104] 6 parts of asiaticoside,

[0105] Hexathiazole 2 parts,

[0106] 4 parts bornyl acetate,

[0107] 24 parts polyacrylamide,

[0108] [R-(R*,R*)]-2,3,4-trihydroxybutyraldehyde 9 parts,

[0109] Fucoxanthin 8 parts,

[0110] 5 parts of 2-hydroxyethyl cellulose.

[0111] Before treatment: 1L water sample contains m-cresol 20mg, 2,4,6-trichlorophenol 18mg, 2,4-dichlorophenol 12mg, add 50mg of this complexing agent;

[0112] After treatment: No mesocresol, 2,4-dichlorophenol and 2,4,6-trichl...

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PUM

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Abstract

The invention relates to a complexing agent for removing phenolic compounds in water. The complexing agent is made from, Nu-terpinene, 3-phenyl-2-propyl acrylate, cyanidin chloride, iron ammonium oxalate, Alpha-copaene, climbazole, buflomedil, Cupferron, ferric chloride, asiaticoside, hexythiazox, bornyl acetate, polyacrylamide, [R-(R*, R*)]-2, 3, 4-hydroxybutyraldehyde, fucoxanthine, and 2-hydroxyethyl cellulose. The complexing agent has high ability to complex with the phenolic compounds, complex precipitant forms fast, the removal rate of the phenolic compounds is up to 99%, the complexing agent is of low toxicity, required usage of the complexing agent is low, no hazard is caused to the water, and the treatment cost is low.

Description

technical field [0001] The invention relates to a complexing agent for removing phenolic compounds in water, belonging to the technical field of environmental protection. Background technique [0002] Phenolic compounds are protoplasmic poisons, which can produce toxicity to all biologically active bodies and cause cell damage. High-concentration phenol solution can coagulate protein and continue to penetrate into the body, causing deep tissue damage, necrosis and even systemic poisoning. Even low-concentration phenol solution can also denature protein. Phenolic wastewater not only poses a serious threat to human health, but also harms animals and plants. The treatment of phenolic wastewater has always been a major problem in the field of sewage treatment at home and abroad. In my country, phenol, m-cresol, 2,4-dichlorophenol, 2,4,6-trichlorophenol, pentachlorophenol, and p-nitrophenol are listed as phenolic pollutants for priority control. [0003] Domestic dephenoliza...

Claims

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Application Information

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IPC IPC(8): C02F1/52C02F1/58C02F101/34
CPCY02W10/37
Inventor 缪琼华
Owner 缪琼华
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