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Lithium vanadium phosphate cathode material with low-temperature electrochemical properties

A lithium vanadium phosphate and cathode material technology, applied in battery electrodes, circuits, electrical components, etc., can solve problems such as poor cycle performance, poor low-temperature electrochemical performance, low electronic conductivity of lithium vanadium phosphate, etc., and achieve particle size distribution The effect of narrow range, lower battery internal resistance, and high conductivity

Inactive Publication Date: 2015-10-14
GUIZHOU RADIO & TV UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The technical problem to be solved in the present invention is: use CeO2 and carbon composite coating to modify lithium vanadium phosphate to solve the problems of low electronic conductivity and poor cycle performance of lithium vanadium phosphate, and further improve the low-temperature electrochemical performance of lithium vanadium phosphate cathode material. Disadvantages of poor performance

Method used

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  • Lithium vanadium phosphate cathode material with low-temperature electrochemical properties
  • Lithium vanadium phosphate cathode material with low-temperature electrochemical properties
  • Lithium vanadium phosphate cathode material with low-temperature electrochemical properties

Examples

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Embodiment 1

[0042] Dissolve 6.22g of citric acid in 30mL of deionized water, pour it into a beaker containing 2.70g of vanadium pentoxide, and stir on a magnetic heating stirrer at a constant temperature of 50°C for 60 minutes to form a dark blue solution. Dissolve 5.13g of ammonium dihydrogen phosphate and 1.68g of lithium carbonate in 30mL of deionized water respectively, add them to the above dark blue solution, and stir on a magnetic heating stirrer at a constant temperature of 50°C for 1 hour. The pH value was adjusted to 4 with acetic acid, and the mixed liquid was stirred at a constant temperature of 50° C. for 1 hour on a magnetic heating stirrer. Raise the temperature to 80°C, continue stirring to evaporate the solvent to form a dark blue wet gel, and put it in an oven at 85°C for 1 day to form a dry gel. The xerogel was ground in a mortar for 30 minutes to form a blue-green powder. Then keep the blue-green powder at 350°C for 4 hours under a hydrogen-nitrogen mixture containing...

Embodiment 2

[0047] Dissolve 6.22g of citric acid in 30mL of deionized water, pour it into a beaker containing 2.70g of vanadium pentoxide, and stir on a magnetic heating stirrer at a constant temperature of 50°C for 60 minutes to form a dark blue solution. Dissolve 5.13g of ammonium dihydrogen phosphate and 1.68g of lithium carbonate in 30mL of deionized water respectively, add them to the above dark blue solution, and stir on a magnetic heating stirrer at a constant temperature of 50°C for 1 hour. The pH value was adjusted to 4 with acetic acid, and the mixed liquid was stirred at a constant temperature of 50° C. for 1 hour on a magnetic heating stirrer. Raise the temperature to 80°C, continue stirring to evaporate the solvent to form a dark blue wet gel, and put it in an oven at 85°C for 1 day to form a dry gel. The xerogel was ground in a mortar for 30 minutes to form a blue-green powder. Then keep the blue-green powder at 350°C for 4 hours under a hydrogen-nitrogen mixture containing...

Embodiment 3

[0052] Dissolve 6.22g of citric acid in 30mL of deionized water, pour it into a beaker containing 2.70g of vanadium pentoxide, and stir on a magnetic heating stirrer at a constant temperature of 50°C for 60 minutes to form a dark blue solution. Dissolve 5.13g of ammonium dihydrogen phosphate and 1.68g of lithium carbonate in 30mL of deionized water respectively, add them to the above dark blue solution, and stir on a magnetic heating stirrer at a constant temperature of 50°C for 1 hour. The pH value was adjusted to 4 with acetic acid, and the mixed liquid was stirred at a constant temperature of 50° C. for 1 hour on a magnetic heating stirrer. Raise the temperature to 80°C, continue stirring to evaporate the solvent to form a dark blue wet gel, and put it in an oven at 85°C for 1 day to form a dry gel. The xerogel was ground in a mortar for 30 minutes to form a blue-green powder. Then keep the blue-green powder at 350°C for 4 hours under a hydrogen-nitrogen mixture containing...

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Abstract

The invention discloses a lithium vanadium phosphate cathode material with low-temperature electrochemical properties. The cathode material is characterized in that components of the cathode material comprise carbon-coated lithium vanadium phosphate and CeO2, wherein CeO2 accounts for 0.2-12% of mass of lithium vanadium phosphate; a cerium source is cerous nitrate hexahydrate; and carbon-coated lithium vanadium phosphate is synthesized by a sol-gel method. As carbon-coated lithium vanadium phosphate is synthesized by the sol-gel method so as to form nanostructured lithium vanadium phosphate, the synthesized lithium vanadium phosphate material has fine particles, particle size distribution range is narrow, specific surface area is greatly increased, and a C layer obstructs particle growth and provides good electrical contact among particles. CeO2 formed in the reaction repairs an incomplete C network to form a continuous composite coating. The composite coating provides a high-conductivity nanolayer among particles such that particles are endowed with low charge transfer resistance and high electrical conductivity. And then, battery cathode electrode polarization is reduced, internal resistance of a battery is lowered, and low-temperature electrochemical properties are enhanced.

Description

technical field [0001] The invention belongs to the technical field of positive electrode materials for lithium ion batteries, in particular to a carbon (C) and cerium oxide (CeO 2 ) Composite coated lithium vanadium phosphate (Li 3 V 2 (PO 4 ) 3 ) Cathode material and preparation method thereof. Background technique [0002] With the global energy and environmental problems becoming more and more serious, lithium-ion batteries have become widely used energy storage devices at room temperature due to their high specific energy, good cycle performance, and no pollution to the environment, and can be widely used in small civilian appliances , electric vehicles and other fields. The specific capacity of the positive electrode material of lithium ion battery is much lower than that of the negative electrode material, so the final performance of the battery depends largely on the performance of the positive electrode material. In addition to Li-Co-O, Li-Ni-O, Li-Mn-O system...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/58H01M4/583H01M4/139H01M10/058
CPCH01M4/139H01M4/5825H01M4/583H01M10/058Y02E60/10Y02P70/50
Inventor 江虹郭瑞松徐江海韩跃武刘志超吴琛
Owner GUIZHOU RADIO & TV UNIV