Hydrogen peroxide working solution regenerant used in preparation of hydrogen peroxide process according to anthraquinone method and preparation method of hydrogen peroxide working solution regenerant

Abstract

The invention discloses a hydrogen peroxide working solution regenerant used in preparation of a hydrogen peroxide process according to an anthraquinone method and a preparation method of the hydrogen peroxide working solution regenerant. The regeneration effect of the hydrogen peroxide working solution regenerant is better than that of the conventional activated aluminum oxide anthraquinone degradation product regenerant used in the industry. Compared with the conventional regenerant, after regeneration, the quantity of effective anthraquinone is increased by 0.8 to 2.1 percent. During the preparation process, the reaction between magnesium oxide and water is very slow, the reaction product magnesium hydroxide is hard to dissolve in water, covers magnesium oxide to inhibit further reaction between magnesium oxide and water, and can properly improve the alkalinity of a working solution, while slight alkalinity provides convenience for improving the activity and the selectivity of a palladium catalyst, accelerating the speed of the hydrogenation, and avoiding a great amount of degradation. Meanwhile, the regenerant provided by the invention has favorable stability, is less susceptible to pulverization in the working solution, and low in adsorption of effective anthraquinone in the working solution; the preparation method is simple in process step, can be suitable for large-scale industrial production, and has a relatively high economical effect.

Description

technical field [0001] The invention relates to a working fluid regenerant in the process of preparing hydrogen peroxide by anthraquinone method and a preparation method thereof. Background technique [0002] Hydrogen peroxide is an important inorganic green chemical product, widely used in chemical industry, textile, papermaking, food, medicine, metallurgy, electronics, agriculture, military and environmental protection and other fields. With the rapid development of the global economy, the application fields of hydrogen peroxide continue to expand, the demand for hydrogen peroxide is increasing, and the quality requirements are also getting higher and higher. At present, the anthraquinone method has become the main production method of hydrogen peroxide in the world today with its relatively mature technology. The process uses 2-ethylanthraquinone as a carrier, dissolves it in a mixed solvent of heavy aromatic hydrocarbons and trioctyl phosphate, and prepares it as a work...

AI Technical Summary

Problems solved by technology

The deactivated alumina ball should be replaced in time, if it is used for a long time, it will have a bad impact on the system

To sum up, there are many deficiencies in activated alumina balls as a regeneration agent: 1. Activated alumina balls can only regenerate part of the degraded products, and the regeneration of the degraded products is not thorough enough

2. Due to the insufficient mechanical strength of activated alumina balls, it is easy to pulverize in alkaline working fluid, which will increase the burden of alkali separation in the post-treatment process

3. When activated alumina balls are used for regeneration, the system often has the phenomenon of water and alkali, which will have a certain impact on production

However, when recycling waste alumina balls, the organic matter in the channels of the alumina ball is volatilized in a gaseous state, and these organic matter cannot be recycled, causing great pollution to the environment

[0013] Chinese patent CN101554996A proposes the use of a mixed regenerant of calcium oxide and silicon dioxide. The regenerant has a certain regeneration effect on the degradation product, but since the two substances are not mixed and formed, they are easily dispersed in the working fluid, causing changes in the physical properties of the working fluid. , not conducive to recycling

The content of alumina in the prepared regenerant is about 93% to 97%, the content of macropores above 75nm is more than 5%, the pore volume is more than 0.42ml / g, and the micro-diameter pore diameter is mainly concentrated in The process requires too much equipment, which increases the production cost

[0015] Chinese patent CN103878021A proposes the use of alkylaniline as a catalyst for regeneration of anthraquinone degradation products. The catalyst mainly regenerates the degradation products produced in the partial hydrogenation stage, but this catalyst has fewer types of renewable degradation products, and the regeneration efficiency is low. and difficult to separate and recycle

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