Oil and gas field environment-friendly fracturing propping agent and preparation method thereof
A fracturing proppant and oil and gas field technology, applied in the field of materials, can solve the problems of debris blocking fractures, fracturing equipment damage, low strength of quartz sand, etc., and achieve the effects of smooth oil and gas circulation, increased oil production rate, and low bulk density
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Embodiment 1
[0045] The raw materials of environmental protection fracturing proppants in oil and gas fields are as follows in weight percentage: 20% solid drilling waste, 5% sand, 5% iron slag, 5% Portland cement, 6% sulphoaluminate cement, 6% curing agent, Manganese dioxide 3%, 4% sodium sulfate, 2% barium carbonate, 8% water swelling rubber particles, 0.5% activator, 0.4% enhancer, 0.2% defoamer, 0.5% water reducing agent, 0.6% sizing agent, 1.5% sodium hydroxymethyl cellulose; wherein the composition of the curing agent includes by weight percentage: 7% fly ash, 8% kaolin, polydimethyldiallylammonium chloride 10%, 6wt% concentration Polyaluminum chloride aqueous solution 4%, polyoxyethylene lauryl ether 0.15%, hydrogen peroxide 4%, sodium aluminate 5%, calcium oxide 19%, sodium hydroxymethyl cellulose 8%, sodium metasilicate 6%, epoxy Ethane 10%, dioxane 1%, 8-hydroxyquinoline 1.0%, ethylenediaminetetraacetic acid 12%, cellulose ether 13%.
[0046] Preparation method: (1) Material prepar...
Embodiment 2
[0048] The raw materials of environmental protection fracturing proppants in oil and gas fields are as follows: 50% drilling solid waste, 6% sand, 2% iron slag, 6% Portland cement, 8% sulphoaluminate cement, 9% curing agent, Manganese dioxide 3%, 6% sodium sulfate, 5% barium carbonate, 8% water-swelling rubber particles, 1% activator, 0.8% enhancer, 0.2% defoamer, 0.1% water reducing agent, 0.5% sizing agent, 1.5% sodium hydroxymethyl cellulose; the curing agent includes by weight percentage: 6% fly ash, 8% kaolin, polydimethyldiallylammonium chloride 10%, 6wt% concentration of polymerization chlorination Aluminum aqueous solution 5%, polyoxyethylene lauryl ether 0.2%, hydrogen peroxide 4%, sodium aluminate 8%, calcium oxide 22%, sodium hydroxymethyl cellulose 8%, sodium metasilicate 8%, ethylene oxide 12 %, dioxane 3%, 8-hydroxyquinoline 1.0%, ethylenediaminetetraacetic acid 10%, cellulose ether 15%.
[0049] The preparation method is the same as above.
Embodiment 3
[0051] The raw materials of oil and gas field environmental protection fracturing proppants are as follows: 55% solid drilling waste, 5% sand, 4% iron slag, 6% Portland cement, 6% sulphoaluminate cement, 8% curing agent, Manganese dioxide 2%, 6% sodium sulfate, 5% barium carbonate, 8% water-swelling rubber particles, 1% activator, 0.4% enhancer, 0.5% defoamer, 0.5% water reducing agent, 0.6% sizing agent, 1.5% sodium carboxymethyl cellulose. Wherein, the curing agent includes by weight percentage: 7% fly ash, 8% kaolin, 9% polydimethyldiallyl ammonium chloride, 6wt% polyaluminum chloride aqueous solution 5%, polyoxygen Ethylene lauryl ether 0.1%, hydrogen peroxide 3%, sodium aluminate 6%, calcium oxide 19%, sodium hydroxymethyl cellulose 9%, sodium metasilicate 8%, ethylene oxide 10%, dioxane 2 %, 8-hydroxyquinoline 1.0%, ethylenediaminetetraacetic acid 15%, cellulose ether 10%.
[0052] The preparation method is the same as above.
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