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High-temperature-resistant halogen-free flame-retarding thermoplastic elastomer and preparation method of high-temperature-resistant halogen-free flame-retarding thermoplastic elastomer

A thermoplastic elastomer and high temperature resistant technology, applied in the field of thermoplastic elastomer materials, can solve problems such as affecting the high temperature resistance of products, affecting the physical and mechanical properties of products, and reducing thermal aging of products.

Inactive Publication Date: 2017-05-31
TIANCHANG KANGNING PLASTIC TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

As we all know, engineering plastics are expensive and difficult to process, so they cannot be widely used like general-purpose plastics
On the other hand, the flame retardants used in the existing halogen-free thermoplastic elastomers are basically inorganic hydroxides. A large amount of filling not only affects the physical and mechanical properties of the product, but also largely destroys the overall organic structure. , which greatly reduces the thermal aging of the product, and also affects the high temperature resistance of the product

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] A high-temperature-resistant halogen-free flame-retardant thermoplastic elastomer, the raw materials of which include by weight: 60 parts of EVA, 45 parts of EPDM, 15 parts of ethylene-octene copolymer, 15 parts of high-density polyethylene, and 5 parts of organomodified siloxane , 30 parts of ammonium polyphosphate, 2 parts of aluminum hydroxide, 3 parts of zinc borate, 1 part of sulfur, 1.5 parts of accelerator TMTD, 0.5 parts of accelerator CZ, 2 parts of zinc oxide, 1 part of anti-aging agent RD, 18 parts of calcium carbonate, 3 parts of quartz powder, 10 parts of maleic anhydride grafted ethylene-vinyl acetate copolymer, 5 parts of naphthenic white oil, 2 parts of phenolic antioxidant, 0.2 part of lubricant, 3 parts of silicone powder;

[0024] Wherein, the method for preparing the organomodified siloxane includes: heating 10 parts of glycerin to 230° C. under the condition of nitrogen protection, adding sodium hydroxide as a catalyst for polymerization reaction, an...

Embodiment 2

[0026] A high-temperature-resistant halogen-free flame-retardant thermoplastic elastomer, the raw materials of which include by weight: 80 parts of EVA, 25 parts of EPDM, 35 parts of ethylene-octene copolymer, 1 part of high-density polyethylene, and 20 parts of organomodified siloxane , 10 parts of ammonium polyphosphate, 5 parts of aluminum hydroxide, 1 part of zinc borate, 5 parts of sulfur, 0.5 parts of accelerator TMTD, 2 parts of accelerator CZ, 0.5 parts of zinc oxide, 3 parts of anti-aging agent RD, 4 parts of calcium carbonate, 5 parts of quartz powder, 5 parts of maleic anhydride grafted ethylene-propylene copolymer, 20 parts of aromatic white oil, 0.5 parts of amine antioxidant, 2 parts of magnesium stearate, 1 part of silicone masterbatch;

[0027] Wherein, the content of vinyl acetate in the EVA is 45wt%, and its melt index is measured as 50g / 10min at 190°C and 2.16kg according to ASTM D1238; the third polymerizable monomer of the EPDM is ethylene norbornene Alken...

Embodiment 3

[0030] A high-temperature-resistant halogen-free flame-retardant thermoplastic elastomer, its raw materials include 65 parts by weight of EVA, 40 parts of EPDM, 20 parts of ethylene-octene copolymer, 10 parts of high-density polyethylene, 9 parts of organomodified siloxane, 25 parts of ammonium polyphosphate, 3 parts of aluminum hydroxide, 2 parts of zinc borate, 2 parts of sulfur, 1.2 parts of accelerator TMTD, 0.8 parts of accelerator CZ, 1.6 parts of zinc oxide, 1 part of anti-aging agent RD, 12 parts of calcium carbonate, quartz 3 parts of powder, 8 parts of maleic anhydride grafted ethylene-octene copolymer, 8 parts of paraffin-based white oil, 1.5 parts of thiobisphenol antioxidant, 0.5 part of stearic acid, and 2 parts of silicone oil;

[0031] Wherein, the content of vinyl acetate in the EVA is 35wt%, and its melt index is measured as 55g / 10min according to ASTM D1238 at 190°C and 2.16kg; the third polymerizable monomer of the EPDM is ethylene norbornene Alkenes with a...

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Abstract

The invention discloses a high-temperature-resistant halogen-free flame-retarding thermoplastic elastomer. The high-temperature-resistant halogen-free flame-retarding thermoplastic elastomer is prepared from the following raw materials in parts by weight: 60 to 80 parts of EVA (Ethylene-vinyl Acetate copolymer), 25 to 45 parts of EPDM (Ethylene-Propylene-Diene Monomer), 15 to 35 parts of an ethylene-octene copolymer, 1 to 15 parts of high density polyethylene, 5 to 20 parts of organic modified siloxane, 10 to 30 parts of ammonium polyphosphate, 2 to 5 parts of aluminum hydroxide, 1 to 3 parts of zinc borate, 1 to 5 parts of sulfur, 0.5 to 1.5 parts of an accelerant TMTD (Tetramethylthiuram Disulfide), 0.5 to 2 parts of an accelerant CZ, 0.5 to 2 parts of zinc oxide, 1 to 3 parts of an anti-ageing agent RD, 4 to 18 parts of calcium carbonate, 3 to 5 parts of ground quartz, 5 to 10 parts of an interface compatibilizer, 5 to 20 parts of a plasticizer, 0.5 to 2 parts of an antioxygen, 0.2 to 2 parts of a lubricant and 1 to 3 parts of a processing auxiliary agent. The thermoplastic elastomer disclosed by the invention has excellent high-temperature resistance and flame-retarding performance and has no halogen, low toxin and good comprehensive properties.

Description

technical field [0001] The invention relates to the technical field of thermoplastic elastomer materials, in particular to a high-temperature-resistant halogen-free flame-retardant thermoplastic elastomer and a preparation method thereof. Background technique [0002] Thermoplastic elastomer products not only have the excellent properties of high elasticity and aging resistance of traditional cross-linked vulcanized rubber, but also have the characteristics of ordinary plastic processing and wide processing methods, and can be produced by injection molding, extrusion, blow molding and other processing methods , environmentally friendly, non-toxic, and recyclable, which not only simplifies the processing process, but also reduces processing costs. Therefore, thermoplastic elastomer material has become the latest material to replace traditional rubber. It is a more humane and high-grade new synthetic material, and it is also a standard environmental protection material in the ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/08C08L23/16C08L23/06C08L51/06C08L83/04C08L83/06C08K13/02C08K3/32C08K3/22C08K3/38C08K3/06C08K3/26
CPCC08L23/0853C08L2201/02C08L2201/08C08L2201/22C08L2205/02C08L2205/035C08L2207/04C08L2207/062C08L23/0815C08L23/16C08L23/06C08L51/06C08L83/04C08L83/06C08K13/02C08K2003/323C08K2003/2227C08K2003/387C08K3/06C08K2003/2296
Inventor 祁建兵
Owner TIANCHANG KANGNING PLASTIC TECH
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