Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Ultraviolet light curing adhesive for 3D printing powder and preparation method of ultraviolet light curing adhesive

A technology of 3D printing and ultraviolet light, applied in the direction of adhesive type, ester copolymer adhesive, polymer adhesive additive, etc., can solve the problem of corrosion resistance and aging resistance reduction, ultraviolet light can not pass, bonding Reduced strength and other problems, to achieve the effect of fast bonding speed, simple and easy preparation method, and low cost

Inactive Publication Date: 2017-10-13
苏州汉力新材料有限公司
View PDF4 Cites 2 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the traditional UV-curable adhesive still has some defects in the specific application process. During the process, internal stress is likely to be generated, resulting in a significant drop in bond strength; in addition, there may be shadows in the bonded parts in some places, and ultraviolet light cannot pass through or can only partially pass through, resulting in these parts not being completely cured, corresponding to these The bonding strength of the parts is reduced and the corrosion resistance and aging resistance are reduced

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] A kind of 3D printing powder is used UV-curable binder, and its each component is counted as:

[0027] 40 parts of acrylate, 3 parts of 2-methyl-2-hydroxy-1-phenyl-1-acetone, 3 parts of polysulfide rubber, 5 parts of calcium carbonate, isopropyl tri(dioctyl pyrophosphate acyloxy) 1 part of titanate, 1 part of hydroquinone, the balance of styrene,

[0028] The acrylate is composed of acrylic acrylate and bisphenol A epoxy acrylate in a mass ratio of 3:1.

[0029] Described a kind of 3D printing powder uses ultraviolet light curing adhesive, comprises the following steps:

[0030] (1) 80% styrene and acrylic acid ester, polysulfide rubber, calcium carbonate, isopropyl tris (dioctyl pyrophosphate acyloxy) titanate, hydroquinone in the above-mentioned formula ratio are at a temperature of 40 Stir and mix evenly at -50°C;

[0031] (2) The remaining 20% ​​styrene is used to miscible 2-methyl-2-hydroxyl-1-phenyl-1-propanone, and 2-methyl-2-hydroxyl-1-phenyl-1 - After the a...

Embodiment 2

[0034] A kind of 3D printing powder is used UV-curable binder, and its each component is counted as:

[0035] 40 parts of acrylate, 1 part of 2-methyl-2-hydroxy-1-(4-tert-butyl) phenyl-1-propanone, 4 parts of carboxyl liquid nitrile rubber, 10 parts of silicon dioxide, isopropyl tri 2 parts of (dioctyl phosphate acyloxy) titanate, 0.5 parts of p-tert-butylcatechol, the balance of xylene,

[0036] The acrylate is composed of acrylic acrylate and bisphenol A epoxy acrylate in a mass ratio of 4:1.

[0037] Described a kind of 3D printing powder uses ultraviolet light curing adhesive, comprises the following steps:

[0038] (1) 80% xylene and acrylate, carboxyl liquid nitrile rubber, silicon dioxide, isopropyl tris (dioctyl phosphate acyloxy) titanate, p-tert-butylcatechol in the above formula ratio Stir and mix evenly at a temperature of 40-50°C;

[0039] (2) The remaining 20% ​​xylene is used to miscible 2-methyl-2-hydroxyl-1-(4-tert-butyl)phenyl-1-propanone, and 2-methyl-2-h...

Embodiment 3

[0042] A kind of 3D printing powder is used UV-curable binder, and its each component is counted as:

[0043] 50 parts of acrylate, 5 parts of 1-(4-(2-hydroxyethoxy)-phenyl)-2-hydroxy-2-methyl-1-acetone, 5 parts of polyvinyl alcohol tert-butyraldehyde, 15 parts of aluminum oxide Parts, 3 parts of isopropyl dioleate acyloxy (dioctyl phosphate acyloxy) titanate, 1.5 parts of p-benzoquinone, the balance of ethyl acetate,

[0044] The acrylate is composed of acrylic acrylate and bisphenol A epoxy acrylate in a mass ratio of 4:1.

[0045] Described a kind of 3D printing powder uses ultraviolet light curing adhesive, comprises the following steps:

[0046] (1) 80% ethyl acetate and acrylate, polyvinyl alcohol tert-butyraldehyde, aluminum oxide, isopropyl dioleic acid acyloxy (dioctyl phosphate acyloxy) titanate, P-benzoquinone is stirred and mixed evenly at a temperature of 40-50°C;

[0047] (2) The remaining 20% ​​ethyl acetate is used to miscible 1-(4-(2-hydroxyethoxy)-phenyl)-...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention belongs to the field of adhesives and particularly relates to an ultraviolet light curing adhesive for 3D printing powder and a preparation method of the ultraviolet light curing adhesive. The ultraviolet light curing adhesive for the 3D printing powder is characterized in that the adhesive is a resin adhesive, is used for rapid forming of the 3D printing powder, is quickly cured under ultraviolet light irradiation, is adhered onto powder particles to form a whole body, does not need post-treatment and comprises the following components in parts by weight: 30-50 parts of acrylate, 1-5 parts of a photo-initiator, 3-5 parts of a toughening agent, 5-15 parts of a filling agent, 1-3 parts of a coupling agent, 0.5-2 parts of a stabilizing agent and the balance of a diluting agent. The adhesive prepared by the preparation method provided by the invention is simple in use condition, green and environment-friendly, good in product performance, high in precision and high in adhering speed; selected resin has no thermal effect during curing, smaller contraction force is generated in the curing process, and the adhesive force is strong; raw materials are widely available, and the preparation method is simple and easy to implement, low in cost and beneficial to market popularization.

Description

technical field [0001] The invention belongs to the field of adhesives, and in particular relates to an ultraviolet light curing adhesive for 3D printing powder and a preparation method thereof. Background technique [0002] 3D printing is hailed as another industrial revolution that subverts traditional manufacturing. Its molding process is: first design the required computer three-dimensional curved surface or solid model by software, and then layer it according to a certain thickness according to the process requirements, transform the original three-dimensional electronic model into two-dimensional plane information, and then convert the original three-dimensional electronic model into two-dimensional plane information The layered data is processed to a certain extent, the processing parameters are input, and the numerical control code is generated: under the control of the microcomputer, the numerical control system sequentially processes each thin layer in a plane proc...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C09J133/12C09J163/10C09J11/04C09J11/06C09J11/08B33Y70/00
CPCC09J133/12B33Y70/00C08K2003/2227C08K2003/2241C08K2003/265C08K2003/3045C08L2205/03C09J11/04C09J11/06C09J11/08C08L63/10C08K13/02C08K3/26C08K3/36C08K3/22C08K3/30
Inventor 徐伟
Owner 苏州汉力新材料有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products