The invention discloses an energetic room-temperature curing agent based on a hydroxyl-terminated polybutadiene bonding system, namely, 5-nitrobenzene-1, 3-dinitrile oxide. According to a preparationmethod of the energetic room-temperature curing agent based on the hydroxyl-terminated polybutadiene bonding system, with 1, 3-phthalic aldehyde as an initial raw material, the 5-nitrobenzene-1, 3-dinitrile oxide is synthesized through four steps of reactions of nitrification, oximation, halogenation and dehydrohalogenation. The invention further discloses a solidified body, which is formed by mixing hydroxyl-terminated polybutadiene and the 5-nitrobenzene-1, 3-dinitrile oxide, of the energetic room-temperature curing agent based on the hydroxyl-terminated polybutadiene bonding system. The prepared energetic room-temperature curing agent based on the hydroxyl-terminated polybutadiene bonding system, disclosed by the invention, has the advantages of good product quality, high yield and simple separation, is suitable for large-scale industrial production, is suitable for room temperature curing and forming of hydroxyl-terminated polybutadiene type cast composite propellent in a solid rocket engine and room temperature curing and forming of a HTPB type explosive mixture and can also be used for room temperature curing of other HTPB type adhesives, sealing materials and coatings.