Flame-retardant antistatic polypropylene composition and expanded beads prepared therefrom

A polypropylene composition and flame-retardant polypropylene technology, applied in the polymer field, can solve the problems of poor low-temperature impact resistance of polypropylene, difficulty in guaranteeing the quality of molded products, and decreased flame-retardant or anti-static properties. The effect of improving the flame retardant efficiency

Active Publication Date: 2021-04-09
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] Third, EPP beads have poor antistatic properties
However, in general, the filling amount of conductive filler required to form a conductive network or the amount of antistatic agent added is relatively large, resulting in a significant decrease in the mechanical properties of the polymer, and increasing the production cost and process difficulty of the material. Therefore, Reducing the amount of conductive filler is an important content in the development and application of antistatic composite materials
Chinese patent application 200510004023.0 reports the use of polymer antistatic agents to prepare antistatic polyolefin resin foams, with a surface intrinsic resistivity of 10 8 -10 13 Ωcm, the polymer antistatic agent used mainly includes polyether-polypropylene block copolymer, polyether ester amide and polyamide mixture, etc., but the antistatic addition is 4-6%, and it is short-acting Antistatic agent, the antistatic validity period is only 30 days
Chinese patent application 200710192215.8 reports the preparation method of antistatic and anticonductive polypropylene, and the surface intrinsic resistivity of the obtained polypropylene sheet is 10 10 -10 11 Ωcm, the addition amount of carbon black is 5-40%; due to the low apparent density of carbon black, the addition amount is relatively large, it is difficult to blend with polypropylene base resin, which increases the complexity of the process and product cost
[0008] The most important thing is that when the flame retardant and long-acting antistatic agent are added to the polypropylene beads, the cell structure and expansion ratio of the EPP expanded beads will be significantly affected, and the quality of the subsequent molded products will be difficult. guaranteed, thereby limiting its field of application
When flame retardant and antistatic agent are added at the same time, it will often cause the flame retardant or antistatic performance of each other to decrease at the same time
[0009] Fourth, the low temperature impact resistance of polypropylene is poor, especially propylene homopolymer
Due to the low melt strength of traditional general-purpose impact polypropylene, when it is used for the preparation of foamed beads, there are problems such as cell merger and rupture, poor molding ability, etc.
[0010] The common way to increase the melt strength of polypropylene is to reduce the melt index, that is, to increase the molecular weight of polypropylene, but this will cause difficulties in material melting and extrusion

Method used

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  • Flame-retardant antistatic polypropylene composition and expanded beads prepared therefrom
  • Flame-retardant antistatic polypropylene composition and expanded beads prepared therefrom
  • Flame-retardant antistatic polypropylene composition and expanded beads prepared therefrom

Examples

Experimental program
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Effect test

preparation example Construction

[0203] Preparation of Polypropylene Base Resin HMSPP

[0204] Preparation of Polypropylene Base Resin HMSPP701

[0205] The propylene polymerization reaction is carried out on a polypropylene unit, and the main equipment of the unit includes a prepolymerization reactor, a first loop reactor, a second loop reactor and a third gas phase reactor. The polymerization method and steps are as follows.

[0206] (1) Prepolymerization reaction

[0207] The main catalyst (DQC-401 catalyst, provided by Beijing Aoda Branch of Sinopec Catalyst Company), co-catalyst (triethylaluminum), and the first external electron donor (isopropylcyclopentyldimethoxysilane, IPCPMS) were After pre-contacting at 6°C for 20 minutes, it is continuously fed into a continuous stirred tank prepolymerization reactor for prepolymerization. The flow of triethylaluminum (TEA) entering the prepolymerization reactor is 6.33g / hr, the flow of isopropylcyclopentyldimethoxysilane is 0.3g / hr, the flow of main catalyst i...

Embodiment 1

[0220] The raw material ratio and reaction conditions of the flame retardant, polypropylene composition and expanded beads prepared in this example are listed in Table 3 and Table 4, and Table 4 also lists the performance parameters of the expanded beads. In the table, flame retardant component A is phosphine oxide, flame retardant component B is a transition metal salt, and flame retardant component C is an inorganic flame retardant component.

[0221] (1) Preparation of (halogen-free) flame retardant

[0222] Add 7kg of triphenylphosphine oxide and cobalt formate into ethanol, stir at a rate of 100rpm, and then use microwave to heat the mixture under stirring, with a heating power of 50W, a temperature of 40°C, and a heating time of 4h. The material after microwave heating reaction is carried out supercritical drying, obtains the chelate Co(CHO of the formation of triphenylphosphine oxide and cobalt formate 2 ) 2 (OPPh 3 ) 2 .

[0223] (2) Preparation of (halogen-free) ...

Embodiment 2

[0240] The preparation method of flame retardant, composite flame retardant, carbon nanofiber antistatic agent, flame retardant antistatic polypropylene composition and expanded beads is similar to embodiment 1, and difference is that shown in table 3 and 4 Raw material formulations and reaction conditions. For example, this embodiment uses HMSPP702, and the halogen-free flame retardant formed is the chelate Ni(CHO) formed by trioctylphosphine oxide and nickel formate. 2 ) 2 (OPot 3 ) 2 , the prepared carbon nanofiber antistatic agent contains nickel 3wt%.

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Abstract

The invention mainly provides a flame retardant polypropylene composition, a flame retardant antistatic polypropylene composition, a flame retardant (antistatic) polypropylene foamed bead, and a preparation method and application thereof. Wherein, the flame retardant and antistatic polypropylene foam beads are made of flame retardant materials containing high melt strength polypropylene base resin, flame retardant and antistatic composition, cell nucleating agent and optional antioxidant and other auxiliary agents. The antistatic polypropylene composition is prepared through a foaming process, and the polypropylene base resin includes a propylene homopolymer component and an ethylene-1-butene copolymer component. The molded body prepared from the flame-retardant and antistatic polypropylene foamed beads has good flame-retardant and antistatic properties, excellent mechanical properties, and is widely used.

Description

technical field [0001] The invention relates to the technical field of macromolecules, in particular to a flame-retardant polypropylene composition, a flame-retardant antistatic polypropylene composition and a flame-retardant (antistatic) polypropylene foamed bead. Background technique [0002] Due to its light weight, good mechanical properties, and the use of molding to make products with specific shapes, expanded polypropylene beads (EPP) are a polymer foam material with a wide range of uses. Its development and industrial production have been continuously It is the focus of industry and academia in various countries. Compared with polystyrene series resin foamed bead shaped products, polypropylene foamed molded products obtained by molding polypropylene foamed beads have chemical resistance, high toughness, high heat resistance, good Excellent properties such as compression resilience. However, the current industrialized EPP has disadvantages such as high molding proce...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/12C08L23/08C08K13/04C08K7/06C08K5/00C08K3/22C08J9/18C08J9/228
CPCC08J9/18C08J9/228C08J2323/12C08J2423/08C08J2423/12C08K2201/011C08K2201/017C08L23/12C08L2201/02C08L2201/04C08L2201/22C08L2203/14C08L2205/025C08L2205/03C08L23/0815C08K13/04C08K7/06C08K5/0091C08K2003/2224
Inventor 郭鹏徐耀辉吕明福张师军白弈青邵静波毕福勇宋文波徐萌
Owner CHINA PETROLEUM & CHEM CORP
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