Composite nano-propylene pigment and preparation method thereof

A kind of acrylic paint, nanotechnology, applied in the field of pigments, can solve the problems of easy cracking, mildew, fading and other problems of pigments, and achieve the effect of ensuring long-term durability, not easy to mold, and good color

Inactive Publication Date: 2019-01-04
苏州德加画材科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Compared with other pigments, acrylic paint has obvious advantages in terms of firmness, wear resistance, water resistance, and corrosion resistance. Therefore, it is often used in easel paintings and indoor and outdoor murals in the current prior art. However, as time goes by, it still There are problems such as color change, fading, and color instability under high and low temperature environments. Based on this, those skilled in the art have made some improvements, such as Chinese invention patent CN101225250A, which discloses acrylic paint for fine arts containing nano-pigments And the manufacturing method thereof, which specifically includes: the proportion of formula is calculated in parts by mass: take 1-5 parts of nano-pigment, 5-20 parts of pigment powder or 10-20 parts of lithopone, 30-50 parts of polyacrylic acid emulsion, hydroxyethyl 5-10 parts of cellulose, 0.5-5 parts of chitosan, 8-18 parts of hydrated silicon dioxide, 0.2-1 part of sodium benzoate, 0.1-1.0 parts of phenoxyethanol, 2-6 parts of glycerin, 0.2-2 parts of ethanol 5 to 20 parts of distilled water; sprinkle hydroxyethyl cellulose and chitosan into distilled water to make adhesive glue, add sodium benzoate, phenoxyethanol, nano-pigment slurry, polyacrylic acid emulsion, Stir until uniform; then add pigment powder, hydrated silica, lithopone, glycerin and ethanol and stir evenly; grind to a finished product; although this patent achieves pigment weather re

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  • Composite nano-propylene pigment and preparation method thereof
  • Composite nano-propylene pigment and preparation method thereof

Examples

Experimental program
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Example Embodiment

[0027] Example 1

[0028] This embodiment provides a composite nano propylene pigment. The raw material formula includes: 50 parts of acrylate emulsion, 10 parts of nano calcium oxide, 3 parts of nano zinc oxide, 3 parts of nano titanium dioxide, 4 parts of nano calcium carbonate, and polyether modified 0.05 parts of polydimethylsiloxane, 0.05 parts of N-(β-aminoethyl)-γ-aminopropylmethyldimethoxysilane, 0.4 parts of aminopropylamine dioleate, 2 dodecyl alcohol esters Parts, 2 parts of triethanolamine, 2 parts of gum arabic, 1 part of ethylene glycol, 0.5 part of anti-mold fungicide, 20 parts of Phthalocyanine Green G and 2 parts of water.

[0029] The preparation method includes: weighing the above-mentioned raw materials according to the formula ratio, and combining the acrylate emulsion, the nano calcium oxide, the nano zinc oxide, the nano titanium dioxide, the nano calcium carbonate, the water and the Polyether modified polydimethylsiloxane, N-(β-aminoethyl)-γ-aminopropylmeth...

Example Embodiment

[0030] Example 2

[0031] This embodiment provides a composite nano propylene pigment. The raw material formula includes: 45 parts of acrylate emulsion, 10 parts of nano calcium oxide, 4 parts of nano zinc oxide, 4 parts of nano titanium dioxide, 4 parts of nano calcium carbonate, polyether modified 0.05 parts of polydimethylsiloxane, 0.1 parts of N-(β-aminoethyl)-γ-aminopropylmethyldiethoxysilane, 0.55 parts of aminopropylamine dioleate, 3 dodecyl alcohol esters Parts, 2 parts of triethanolamine, 2 parts of gum arabic, 2 parts of ethylene glycol, 0.5 parts of anti-mold fungicide, 20 parts of Phthalocyanine Green G and 3.3 parts of water.

[0032] The preparation method includes: weighing the above-mentioned raw materials according to the formula ratio, and combining the acrylate emulsion, the nano calcium oxide, the nano zinc oxide, the nano titanium dioxide, the nano calcium carbonate, the water and the Polyether modified polydimethylsiloxane, N-(β-aminoethyl)-γ-aminopropylmethy...

Example Embodiment

[0033] Example 3

[0034] This embodiment provides a composite nano propylene pigment. The raw material formula includes: 53 parts of acrylate emulsion, 9 parts of nano calcium oxide, 3 parts of nano zinc oxide, 4 parts of nano titanium dioxide, 4 parts of nano calcium carbonate, polyether modified 0.07 parts of polydimethylsiloxane, 0.07 parts of N-(β-aminoethyl)-γ-aminopropylmethyldimethoxysilane, 0.86 parts of aminopropylamine dioleate, 2 dodecyl alcohol esters Parts, 2 parts of triethanolamine, 1 part of gum arabic, 1 part of ethylene glycol, 0.5 parts of anti-mold fungicide, 18 parts of Phthalocyanine Green G and 1.5 parts of water.

[0035] The preparation method includes: weighing the above-mentioned raw materials according to the formula ratio, and combining the acrylate emulsion, the nano calcium oxide, the nano zinc oxide, the nano titanium dioxide, the nano calcium carbonate, the water and the Polyether modified polydimethylsiloxane, N-(β-aminoethyl)-γ-aminopropylmethyl...

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Abstract

The invention discloses composite nano acrylic pigment and a preparation method thereof. The raw materials include an acrylate emulsion, nano calcium oxide, a wetting dispersant, a coalescing agent, athickening agent, a mildew-preventing bactericide, pigment slurry and water, and further includes nano zinc oxide, nano titanium dioxide and nano calcium carbonate. The wetting dispersant comprises an organosilicon compound and aminopropylamine dioleate, wherein each molecule of the organosilicon compound contains a hydrophilic group and at least two hydrophobic groups. The preparation method includes the following steps that the raw materials are weighed according to the proportions in a formula, acrylate emulsion, nano calcium oxide, nano zinc oxide, nano titanium dioxide, nano calcium carbonate, water and the wetting dispersant are mixed and ground, then the coalescing agent, the thickening agent, the mildew-preventing bactericide and the pigment slurry are added, the mixture is stirred and subjected to vacuum deformation, and the composite nano acrylic pigment is obtained. The pigment can be suitable for mural painting in an outdoor environment, and has the advantages of crack resistance, mildew resistance, yellowing resistance, high color retention and the like.

Description

Technical field [0001] The invention belongs to the field of pigments, and in particular relates to the application of acrylic pigments under outdoor high and low temperature alternation and dry and wet alternation phenomena, and particularly relates to a composite nano acrylic pigment and a preparation method thereof. Background technique [0002] Acrylic pigment A type of paint that mainly includes acrylic resin (such as polymethyl methacrylate) and pigments. Compared with other pigments, acrylic paint has obvious advantages in terms of durability, water resistance, and corrosion resistance. Therefore, it is often used in shelf paintings, indoor and outdoor murals in the prior art. However, as time goes by, it is still There are problems such as color discoloration, fading, and color instability under high and low temperature environments. Based on this, those skilled in the art have made some improvements, such as the Chinese invention patent CN101225250A, which discloses a ac...

Claims

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Application Information

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IPC IPC(8): C09D133/04C09D5/14C09D5/06C09D7/61C09D7/63C09D7/65
CPCC08K2003/2206C08K2003/2241C08K2003/2296C08K2003/265C08K2201/003C08K2201/011C08L2201/08C08L2205/03C09D5/06C09D5/14C09D5/18C09D7/61C09D7/63C09D7/65C09D7/67C09D133/04C08L83/12C08L5/00C08K13/02C08K3/22C08K3/26C08K5/103C08K5/17
Inventor 李小福
Owner 苏州德加画材科技有限公司
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