Flame-retardant core material and preparation method thereof
A flame retardant material and core material technology, applied in the field of flame retardant materials, can solve the problems of high energy consumption, environmental pollution, complex process and high price, and achieve the effects of good flame retardant effect, simple preparation process and easy large-scale production.
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Embodiment 1
[0022] A method for preparing an intumescent flame retardant material containing silicon, nitrogen and phosphorus, comprising the steps of:
[0023] (1) Under the protection of an inert gas and at room temperature, the solvent for the reaction is dichloromethane, and chlorosilane and dimethyl phosphonate are reacted to obtain dimethyl silyl phosphonate; the chlorosilane is three Methyl chlorosilane; the molar ratio of said chlorosilane to dimethyl phosphonate is 1: 3.5;
[0024] (2) Under the protection of an inert gas and at 370°C, react the product of step (1) with dimethyl alkylsilylphosphonate and melamine under the action of anhydrous magnesium chloride, and then vacuum dry it after cooling; step (1) The molar ratio of the resulting alkylsilylphosphonic acid dimethyl to melamine is 1:1.1.
[0025] Washing, drying and pulverizing, the flame retardant material is obtained, the degree of polymerization is 750, and the decomposition temperature of 1% thermal weight loss is 2...
Embodiment 2
[0027] A method for preparing an intumescent flame retardant material containing silicon, nitrogen and phosphorus, comprising the steps of:
[0028] (1) Under the protection of an inert gas and at room temperature, the solvent for the reaction is dichloromethane, and chlorosilane and dimethyl phosphonate are reacted to obtain dimethyl silyl phosphonate; the chlorosilane is three Ethyl chlorosilane; the molar ratio of said chlorosilane to dimethyl phosphonate is 1: 3;
[0029] (2) Under the protection of an inert gas at 350°C, react the product of step (1) with dimethyl alkylsilylphosphonate and melamine under the action of anhydrous magnesium chloride, and then vacuum dry after cooling to obtain the product; step (1) The molar ratio of the resulting alkylsilylphosphonic acid dimethyl to melamine is 1:1.1.
[0030] Washing, drying and pulverizing, the flame retardant material is obtained, the degree of polymerization is 990, and the decomposition temperature of 1% thermal weig...
Embodiment 3
[0032] A method for preparing an intumescent flame retardant material containing silicon, nitrogen and phosphorus, comprising the steps of:
[0033] (1) Under the protection of an inert gas and at room temperature, the solvent for the reaction is chloroform, and chlorosilane and dimethyl phosphonate are reacted to obtain dimethyl silyl phosphonate; the chlorosilane is tripropyl Chlorosilane; the molar ratio of said chlorosilane to dimethyl phosphonate is 1:4;
[0034] (2) Under the protection of an inert gas at 350°C, react the product of step (1) with dimethyl alkylsilyl phosphonate and melamine under the action of triphenyl phosphate, and then vacuum dry after cooling to obtain the product; step (1) ) The molar ratio of the resulting alkylsilylphosphonic acid dimethyl ester to melamine is 1: 1.1.
[0035] Washing, drying and pulverizing, the flame retardant material is obtained, the degree of polymerization is 800, and the decomposition temperature of 1% thermal weight loss...
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