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Water-based UV (ultraviolet) ink-jet ink, preparation method thereof and curing method of ink

An inkjet ink, water-based technology, used in inks, household appliances, applications, etc., can solve the problems of easy migration, increased VOCs emissions, and rapid alcohol volatilization, to reduce VOCs volatilization, avoid small molecule migration, and improve use efficiency. Effect

Inactive Publication Date: 2019-04-05
HONGSAM DIGITAL SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In recent years, there have been many researches on water-based light-curable inks at home and abroad. For example, CN103526570A discloses a preparation method of UV-curable inkjet printing pigment inks. The inkjet printing inks obtained by it are smooth, bright in color, and solid in color The effect is good, but the photoinitiator used in this ink is a small molecule photoinitiator, which is easy to volatilize and migrate during storage, resulting in low photopolymerization efficiency, and the unreacted photoinitiator will also migrate after the ink is illuminated to the surface, causing fouling of the cured film
CN106189512A discloses a water-based UV ink for inkjet printing and a preparation method thereof. The prepared water-based UV inkjet ink is environmentally friendly, has good printing fluency, and ink has good adhesion and abrasion resistance after the substrate is cured. The product is stable in storage, yet, similar to CN103526570A, what it adopts is a small molecule water-based photoinitiator, which is prone to migration, and the water-based photoinitiator is usually expensive and is not suitable for industrial production
CN104927485A discloses a water-based UV ink for inkjet printing and a preparation method thereof. The water-based UV ink has fast curing speed, low curing temperature, short drying time and good quality of printed products, easy cleaning of nozzles, low energy consumption, no irritation and odor odor, does not pollute the environment, but it uses a mixture of water and alcohol as a diluent, alcohol volatilizes quickly, increases the emission of VOCs, poor environmental protection, and easily leads to problems such as unstable ink and easy precipitation of pigments

Method used

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  • Water-based UV (ultraviolet) ink-jet ink, preparation method thereof and curing method of ink
  • Water-based UV (ultraviolet) ink-jet ink, preparation method thereof and curing method of ink
  • Water-based UV (ultraviolet) ink-jet ink, preparation method thereof and curing method of ink

Examples

Experimental program
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Effect test

Embodiment 1

[0028] A water-based UV black inkjet ink, by weight percentage, it is made of the following components: epoxy modified polyurethane acrylate emulsion: 15%, organic fluorine modified polyurethane acrylate emulsion: 3%, photoinitiator GC -410: 2%, photoinitiator PolymericTPO-L: 1%, acryloyl morpholine: 8%, polyethylene glycol (400) acrylate: 7%, propylene glycol: 20%, wetting agent PE-100: 0.5 %, defoamer FS-620: 0.05%, triethanolamine: 1%, fungicide HY-606D-2: 0.1%, water-based nano black paste: 30%, deionized water: the rest; the photoinitiator GC- 410. Photoinitiator PolymericTPO-L, acryloyl morpholine, polyethylene glycol (400) acrylate, wetting agent PE-100, defoamer FS-620 are stirred and mixed according to the weight percentage, and then add ring Oxygen-modified urethane acrylate emulsion, organic fluorine-modified urethane acrylate emulsion, triethanolamine, bactericide HY-606D-2 and deionized water, stirred and mixed evenly, and then filtered to obtain the water-based U...

Embodiment 2

[0031] A water-based UV red inkjet ink, by weight percentage, it is made of the following components: epoxy soybean oil modified polyurethane acrylate emulsion: 8%, silicone modified acrylate emulsion: 3%, photoinitiator GC-409: 3%, photoinitiator Omnipol TX: 1%, acryloyl morpholine: 10%, polyethylene glycol (600) acrylate: 5%, glycerol: 15%, water-based nano red paste: 25% %, wetting agent surfynol 465: 0.1%, wetting agent SD-200: 0.2%, defoamer FS-640: 0.1%, ammonia water: 1%, fungicide HY-606D-2: 0.1%, deionized water : remaining amount; The preparation process of described aqueous UV red ink-jet ink is similar to embodiment 1.

[0032] Wherein, by weight percentage, the water-based nano red paste is made of the following components: pigment red V19: 20%, wetting agent WA-6802: 2.5%, dispersant Tego 655: 20%, defoamer BYK- A506: 2%, triethylamine: 1%, fungicide MIT: 1%, deionized water: the balance; the preparation process of the water-based nano red paste is similar to th...

Embodiment 3

[0034] A water-based UV yellow inkjet ink, by weight percentage, it is made of the following components: fluorine silicon modified urethane acrylate emulsion: 10%, castor oil modified urethane acrylate emulsion: 3%, photoinitiator GC -412: 2%, photoinitiator Omnipol 3TX: 2%, acryloyl morpholine: 12%, ethoxylated trimethylolpropane triacrylate: 3%, polyethylene glycol: 20%, water-based nano yellow paste: 30%, wetting agent SD-200: 1%, defoamer FS-6502: 0.1%, triethylamine: 1%, fungicide HY-606D-2: 0.1%, deionized water: the rest; The preparation process of water-based UV yellow inkjet ink is similar to Example 1.

[0035] Wherein, by weight percentage, the water-based nano yellow paste is made of the following components: pigment yellow 155: 25%, wetting agent surfynol465: 1%, dispersant EFKA4185: 15%, defoamer Tego822: 1%, Triethylamine: 2%, bactericide F-046: 1.5%, deionized water: the balance; the preparation process of the water-based nano yellow paste is similar to that o...

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Abstract

The invention discloses water-based UV (ultraviolet) ink-jet ink which is prepared from, in weight percent, 5-25% of prepolymer dispersion liquid, 0.1-5% of photo-initiators, 1-15% of UV monomers, 1-30% of moisture retention agents, 1-40% of water-based nano-color paste, 0.05-1% of first defoaming agents, 0.1-1% of a first pH(potential of hydrogen) conditioning agents, 0.1-1% of antimicrobial agents, 0.05-1% of wetting agents and the rest deionized water. The invention further discloses a preparation method of the UV ink-jet ink and an application of the ink. According to the water-based UV ink-jet ink, the prepolymer dispersion liquid serves as a main film forming matter, water resistance and abrasion resistance of a curing film are effectively improved, a non-migrating photo-initiator triggers polymerization of a system, small molecule migration is effectively avoided, the self-cleaning property of the curing film is ensured, the water-based UV monomer is less in odor and low in irritation, VOC (volatile organic compound) volatile of the ink is reduced, stability of the ink is ensured, cohesiveness of the film forming matter is improved, so that the abrasion resistance of the curing film is improved.

Description

technical field [0001] The invention relates to an inkjet ink, in particular to a water-based UV inkjet ink, a preparation method and a curing method thereof, and belongs to the technical field of inkjet digital printing. Background technique [0002] The printing industry has undergone many transformations over the past few decades, most notably the introduction of digital printing technology and the new technology of inkjet non-contact printing for a range of different printing applications. The emergence of digital printing has made today's inkjet printing operation simple, with strong controllability, short production cycle, convenient production, good quality and low price, high-precision printing, bright colors and realistic effects, which can fully satisfy users. demand and become a development trend. With the development of new inkjet printing technology, inkjet ink has become an integral part of the printing process. Today, the application field of inkjet printing...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D11/30C09D11/101
CPCC09D11/101C09D11/30
Inventor 王二永李金艳
Owner HONGSAM DIGITAL SCI & TECH
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