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Preparation method and application of biodegradable antioxidant fruit and vegetable preservative film

A fruit and vegetable preservation and biodegradation technology, applied in the field of biodegradable food film processing, can solve the problems of reducing the mechanical properties of the fresh-keeping film, low elongation at break, impact on human health, etc. The effect of high performance and production efficiency

Active Publication Date: 2021-12-03
BEIJING TECHNOLOGY AND BUSINESS UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Fruit and vegetable fresh-keeping film is a functional film, which mainly relies on the air permeability of the film to minimize the oxygen concentration, inhibit respiratory consumption and delay the aging of fruits and vegetables. Although the traditional functional fresh-keeping film can play the role of packaging, it is obviously not enough. The preservation needs of the modern market, in the existing research, in order to achieve the purpose of better preservation, some substances that can absorb or inhibit the production of various gases of fruits and vegetables are usually added in the preparation process of the plastic wrap to prevent the effects of ripening and aging Produced, such as tuff, zeolite, quartz stone, hygroscopic agent calcium chloride, etc., but the addition of granular substances will reduce the mechanical properties of the plastic wrap; in addition, in order to prevent food oxidation and microbial contamination, some antibacterial materials will also be added to the film. However, conventionally used synthetic antioxidants (such as tert-butylhydroquinone, butylated hydroxytoluene and butylated hydroxyanisole, propyl gallate) and antibacterial agents (such as sorbic and benzoic acids, benzene Sodium formate) is toxic, carcinogenic and mutagenic, long-term coating on the surface of fruits and vegetables will penetrate into the interior of fruits and vegetables, causing certain impacts on human health; with the enhancement of people's awareness of environmental protection, research has introduced degradable fruit and vegetable films, of which starch ( St) as a kind of renewable, fully biodegradable product, its source is rich, cheap, but the elongation at break is low, so the prior art usually combines starch with thermoplastic degradable plastics (especially butylene adipate) Alcohol ester and butylene terephthalate copolymer, PBAT) composite, using the good ductility and elongation at break of PBAT, and good film-forming properties, etc., to prepare a starch / PBAT composite material, although starch / PBAT composites have great advantages in forming biodegradable films, but there are some limitations in making them competitive materials considering their high permeability to oxygen, water vapor

Method used

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  • Preparation method and application of biodegradable antioxidant fruit and vegetable preservative film
  • Preparation method and application of biodegradable antioxidant fruit and vegetable preservative film
  • Preparation method and application of biodegradable antioxidant fruit and vegetable preservative film

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] Weighed in parts by mass, put 100 parts of starch (St), 35 parts of glycerin, 5 parts of organically modified montmorillonite (OMMT) and 1 part of quercetin (QUE) into a high-speed mixer and mix for 5 minutes to obtain modified Powder; the modified powder and PBAT are mixed according to the mass ratio of 4:6, and then twin-screw melt extrusion granulation is carried out. The temperature from the feeding area to the head area of ​​the twin-screw extruder is 110, 120, 130, 140, 120 and 100°C. Then extrude and blow at 140°C with a film blowing machine to obtain a biodegradable anti-oxidation fruit and vegetable fresh-keeping film, which is denoted as OMMT-5%.

Embodiment 2

[0034] Weighed in parts by mass, put 100 parts of starch (St), 35 parts of glycerin, 10 parts of organically modified montmorillonite (OMMT) and 1 part of quercetin (QUE) into a high-speed mixer and mixed for 5 minutes to obtain a modified Powder: The modified powder and PBAT are mixed according to the mass ratio of 4:6, and then twin-screw melt extrusion granulation is carried out. The temperature of each section of the twin-screw extruder is 140°C. Afterwards, a film blowing machine is used to extrude and blow at 110° C. to obtain a biodegradable anti-oxidation fruit and vegetable fresh-keeping film, which is recorded as OMMT-10%.

Embodiment 3

[0036] Weighed in parts by mass, put 100 parts of starch (St), 35 parts of glycerin, 15 parts of organically modified montmorillonite (OMMT) and 1 part of quercetin (QUE) into a high-speed mixer and mix for 5 minutes to obtain a modified Powder: The modified powder and PBAT are mixed according to the mass ratio of 4:6, and then twin-screw melt extrusion granulation is carried out. The temperature of each section of the twin-screw extruder is 120°C. Afterwards, a film blowing machine is used to extrude and blow at 120°C to obtain a biodegradable anti-oxidation fruit and vegetable fresh-keeping film, which is marked as OMMT-15%.

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Abstract

The invention discloses a preparation method and application of a biodegradable antioxidant fruit and vegetable preservative film, and belongs to the field of biodegradable food film processing. The preparation method of the fruit and vegetable preservative film comprises the following steps: mixing the starch, the glycerol, the organic modified montmorillonite and the quercetin to obtain modified powder, mixing the modified powder with the PBAT, granulating to obtain composite granules, and blow-molding to obtain the biodegradable antioxidant fruit and vegetable preservative film. The fruit and vegetable preservative film prepared by the method takes PBAT and starch as matrix materials, all the raw materials are biodegradable materials, and the waste materials can be treated in manners of composting, soil landfill and the like, so that the fruit and vegetable preservative film is green and environment-friendly, conforms to the concept of sustainable development, and has the advantages of strong mechanical property, high barrier property, good oxidation resistance, good fresh-keeping property, greenness, environmental protection and no toxicity.

Description

technical field [0001] The invention relates to a preparation method and application of a biodegradable anti-oxidation fruit and vegetable fresh-keeping film, belonging to the field of biodegradable food film processing. Background technique [0002] The harvested fruits and vegetables are still undergoing vigorous physiological activities. With the progress of respiration, the temperature of the storage environment of fruits and vegetables increases, which leads to wilting on the surface and reduces the quality of fruits and vegetables. In addition, the ethylene accompanying the ripening of fruits and vegetables will further promote freshness. Fruits are ripe and aging, so according to these physiological characteristics of harvested fruits and vegetables, people often use plastic wrap to wrap them to achieve the purpose of reducing metabolism and preventing corruption and aging. [0003] Fruit and vegetable fresh-keeping film is a functional film, which mainly relies on th...

Claims

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Application Information

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IPC IPC(8): C08J5/18C08L67/02C08L3/02C08K5/053C08K5/1545C08K9/04C08K3/34
CPCC08J5/18C08J2367/02C08J2403/02C08K5/053C08K5/1545C08K9/04C08K3/346
Inventor 张彩丽杨璠翁云宣赵敏
Owner BEIJING TECHNOLOGY AND BUSINESS UNIVERSITY
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