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Water-based inorganic nano-composite silicon resin anticorrosive coating and preparation method thereof

An inorganic nano, anti-corrosion coating technology, applied in anti-corrosion coatings, fire-retardant coatings, conductive coatings, etc., can solve the problems of the huge difficulty in repairing and maintaining damaged coatings, the adverse impact of sustainable social and economic development, and the complex construction process of imported coatings. The effect of improving hardness, excellent corrosion resistance and excellent high and low temperature resistance

Active Publication Date: 2022-02-18
国能投(北京)智慧能源科技有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However traditional organic coatings contain toxic heavy metals such as chromates, lead and zinc
It not only consumes a large amount of non-renewable energy, but also has a serious adverse impact on the sustainable development of social economy
Moreover, heavy-duty anti-corrosion coatings are completely dependent on imports, which are not only expensive but also complex in construction technology, and there is an urgent need for high-quality domestic alternatives; an innovative and breakthrough technology is needed to solve the marine corrosion problems that cannot be truly solved by traditional micro-current and toxic organic coatings. ; Develop water-based coatings that meet the national environmental protection requirements; solve the current complex construction process of imported coatings, especially the difficulty of completing repair and maintenance of damaged coatings on site
Therefore, in the field of corrosion protection, it is still difficult to research on metal surface coatings that are harmless to the environment and have good shielding properties.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] A water-based inorganic nanocomposite silicone resin coating, comprising 60 parts by weight of an epoxy-modified silicone resin with a solid content of 70%, 20 parts by weight of a fluorocarbon elastic emulsion with a solid content of 50%, 25 parts by weight of modified Nano-silica sol, 10 parts by weight of nano-garnet, 5 parts by weight of grinding wheel dust, 1 part by weight of polyethylene wax, 1 part by weight of dodecyl alcohol ester, 0.5 parts by weight of phenyl tri(trimethylsiloxane base) silane, 0.5 parts by weight of sodium perfluorononenyloxybenzene sulfonate, 0.5 parts by weight of hydroxypropyl methylcellulose, and 50 parts by weight of deionized water.

[0028] The preparation method of above-mentioned modified nano silica sol comprises the following steps:

[0029] (1) Mix ethyl orthosilicate and methyl orthosilicate in absolute ethanol according to the mass ratio of 1:2, and the mass of absolute ethanol is 10 times the total mass of ethyl orthosilicate...

Embodiment 2

[0037] A water-based inorganic nanocomposite silicone resin coating, comprising 68 parts by weight of an epoxy-modified silicone resin with a solid content of 75%, 30 parts by weight of a fluorocarbon elastic emulsion with a solid content of 55%, 37 parts by weight of modified Nano-silica sol, 15 parts by weight of nano-garnet, 10 parts by weight of grinding wheel ash, 5 parts by weight of vinylbisstearamide, 5 parts by weight of propylene glycol phenyl ether, 3 parts by weight of methyl tri(trimethylsiloxane Alkyl) silane, 3 parts by weight of sodium di(2-ethylhexyl) sulfosuccinate, 3 parts by weight of hydroxyethyl cellulose, and 58 parts by weight of deionized water.

[0038] The preparation method of above-mentioned modified nano silica sol, comprises the following steps:

[0039] (1) Mix ethyl orthosilicate and methyl orthosilicate in absolute ethanol according to the mass ratio of 1:2.5, and the mass of anhydrous ethanol is 12 times the total mass of ethyl orthosilicate ...

Embodiment 3

[0047] A water-based inorganic nanocomposite silicone resin coating, comprising 75 parts by weight of an epoxy-modified silicone resin with a solid content of 80%, 40 parts by weight of a fluorocarbon elastic emulsion with a solid content of 60%, 50 parts by weight of modified Nano-silica sol, 20 parts by weight of nano-garnet, 15 parts by weight of grinding wheel ash, 10 parts by weight of glyceryl tristearate, 10 parts by weight of ethylene glycol butyl ether, 5 parts by weight of 2,4,7,9 -Tetramethyl-5-decyne-4,7-diol, 5 parts by weight sulfosuccinate-1,4-bis(2,6-dimethylheptyl) sodium salt, 5 parts by weight carboxy Methylcellulose, 65 parts by weight of deionized water.

[0048] The preparation method of above-mentioned modified nano silica sol, comprises the following steps:

[0049] (1) Mix ethyl orthosilicate and methyl orthosilicate in absolute ethanol according to the mass ratio of 1:3, and the mass of absolute ethanol is 15 times the total mass of ethyl orthosilica...

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Abstract

The invention relates to the technical field of coatings, in particular to a water-based inorganic nano-composite silicon resin anticorrosive coating and a preparation method thereof. The coating comprises the following components in parts by weight: 60-75 parts by weight of epoxy modified organic silicon resin, 20-40 parts by weight of fluorocarbon elastic emulsion, 25-50 parts by weight of modified nano silicon dioxide sol, 10-20 parts by weight of nano garnet, 5-15 parts by weight of grinding wheel ash, 1-10 parts by weight of a dispersing agent, 1-10 parts by weight of a coalescing agent, 0.5-5 parts by weight of a defoaming agent, 0.5-5 parts by weight of a flatting agent, 0.5-5 parts by weight of a thickening agent and 50-65 parts by weight of deionized water. The water-based inorganic nano-composite silicon resin coating prepared by the invention is rapidly cured at low temperature, so that the coating not only has higher hardness and adhesive force, but also has excellent corrosion resistance, water resistance, stain resistance, impact resistance, wear resistance, heat resistance and weather resistance; and the coating can be widely applied to corrosion prevention of marine buildings and marine equipment.

Description

technical field [0001] The invention relates to the technical field of coatings, in particular to a water-based inorganic nanocomposite silicone resin anticorrosion coating and a preparation method thereof. Background technique [0002] Covering 70% of the earth's surface, seawater is a highly complex medium that contains almost every element in the periodic table, as well as a wide variety of organisms. Therefore, it is considered the most corrosive natural environment. Marine corrosion is a slow chemical or electrochemical process and is a natural phenomenon. Metallic materials interact with oxygen and water, causing their own inefficiency and destruction. Due to seawater erosion, ships and plant equipment were damaged, and daily life and production suffered serious losses. Although the occurrence of marine corrosion is inevitable, through the study of the corrosion mechanism, effective protection methods can be found, thereby slowing down the speed of marine corrosion ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D183/04C09D127/12C09D5/08C09D5/24C09D7/61
CPCC09D183/04C09D5/08C09D5/24C09D5/18C09D7/61C09D7/70C08K2201/011C08L2201/08C08L2201/04C08L27/12C08K7/26C08K3/30C08K3/34C08K11/005
Inventor 梁轶刘晓东
Owner 国能投(北京)智慧能源科技有限公司
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